Features of the defect-impurity composition of diamonds from the northern Istok and Mayat placers (Yakutia) according to EPR, IR, and luminescence data

IF 1.2 4区 地球科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Physics and Chemistry of Minerals Pub Date : 2022-12-16 DOI:10.1007/s00269-022-01227-0
V. A. Nadolinny, O. P. Yurjeva, M. I. Rakhmanova, A. Yu. Komarovskikh, V. S. Shatsky
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引用次数: 1

Abstract

Diamonds from placers in the northern provinces of the Siberian Platform attract attention not only due to the unsolved problem of their sources but also due to the variety of properties they exhibit. In this work, electron paramagnetic resonance (EPR), infrared (IR), and photoluminescence (PL) methods were used to study cuboid diamonds from Istok (25 diamonds of Ib-IaA type) and dodecahedron diamonds from Mayat (21 diamonds of IaAB type) placers. The main impurity defects in the crystals studied are nitrogen, nitrogen-titanium, and oxygen-containing centers. The total amount of nitrogen in the form of C (P1 in EPR nomenclature), A, and B centers ranges from 34 to 903 ppm. For 19 out of 25 crystals from the Istok placer, the N3 titanium-related center is observed in the EPR spectra, but only one optical system with zero-phonon line (ZPL) at 635.7 nm is detected in the PL spectra in most cases. It can be assumed that the absence of an accompanying system with ZPL at 440.3 nm is due to its quenching by other centers in these crystals. For 12 out of 21 crystals from the Mayat placer, photoluminescence of oxygen-containing centers in the region of 600–800 nm in the form of a series of equidistant bands with an interval of ~ 31 meV was revealed. A comparison of the EPR and PL data has shown that this red broad band is not correlated with titanium-nitrogen paramagnetic centers OK1 and N3. Thus, the results obtained for diamond crystals from the Istok and Mayat placers show no connection between the N3 and OK1 paramagnetic centers and band in the 600–800 nm region, which questions the presence of oxygen in the structure of the N3 and OK1 centers. The nickel-nitrogen centers were found in crystals from the Mayat placer testifying about the peridotitic paragenesis of these diamonds.

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根据EPR, IR和发光数据分析北部Istok和Mayat砂矿(雅库特)钻石的缺陷-杂质组成特征
来自西伯利亚地台北部省份的砂矿的钻石吸引了人们的注意,不仅是因为它们的来源问题尚未解决,而且还因为它们表现出的各种特性。本文采用电子顺磁共振(EPR)、红外(IR)和光致发光(PL)等方法研究了来自Istok砂矿的长方体钻石(25颗Ib-IaA型钻石)和来自Mayat砂矿的十二面体钻石(21颗IaAB型钻石)。所研究的晶体中主要的杂质缺陷是氮、氮钛和含氧中心。以C (EPR命名法中的P1)、A和B中心形式存在的氮总量在34 - 903 ppm之间。在Istok砂矿的25个晶体中,有19个在EPR光谱中观察到N3钛相关中心,但在大多数情况下,在PL光谱中只检测到一个在635.7 nm处具有零声子线(ZPL)的光学系统。可以认为,在440.3 nm处没有伴随ZPL的体系是由于ZPL被晶体中的其他中心猝灭所致。在玛雅特砂矿的21个晶体中,有12个晶体在600 ~ 800 nm区域以一系列间隔为~ 31 meV的等距带的形式出现了含氧中心的光致发光。EPR和PL数据的比较表明,该红色宽带与钛-氮顺磁中心OK1和N3无关。因此,从Istok和Mayat砂矿中获得的金刚石晶体的结果表明,在600-800 nm区域内,N3和OK1顺磁中心和带之间没有联系,这就质疑了N3和OK1中心结构中是否存在氧。在玛雅特砂矿的晶体中发现了镍氮中心,证明了这些钻石的橄榄岩共生。
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来源期刊
Physics and Chemistry of Minerals
Physics and Chemistry of Minerals 地学-材料科学:综合
CiteScore
2.90
自引率
14.30%
发文量
43
审稿时长
3 months
期刊介绍: Physics and Chemistry of Minerals is an international journal devoted to publishing articles and short communications of physical or chemical studies on minerals or solids related to minerals. The aim of the journal is to support competent interdisciplinary work in mineralogy and physics or chemistry. Particular emphasis is placed on applications of modern techniques or new theories and models to interpret atomic structures and physical or chemical properties of minerals. Some subjects of interest are: -Relationships between atomic structure and crystalline state (structures of various states, crystal energies, crystal growth, thermodynamic studies, phase transformations, solid solution, exsolution phenomena, etc.) -General solid state spectroscopy (ultraviolet, visible, infrared, Raman, ESCA, luminescence, X-ray, electron paramagnetic resonance, nuclear magnetic resonance, gamma ray resonance, etc.) -Experimental and theoretical analysis of chemical bonding in minerals (application of crystal field, molecular orbital, band theories, etc.) -Physical properties (magnetic, mechanical, electric, optical, thermodynamic, etc.) -Relations between thermal expansion, compressibility, elastic constants, and fundamental properties of atomic structure, particularly as applied to geophysical problems -Electron microscopy in support of physical and chemical studies -Computational methods in the study of the structure and properties of minerals -Mineral surfaces (experimental methods, structure and properties)
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