Nonlinear Shear and Elongational Rheology of Poly(propylene carbonate)

Abstract

Nonlinear shear and elongational rheology of entangled poly(propylene carbonate) (PPC) melts having different molecular weights with relatively narrow molecular weight distribution are examined. In shear measurements, the PPCs exhibit a typical shear thinning behavior with stress overshoot at high shear rates. In the shear rate dependence of the steady-state viscosity, the PPCs do not violate the empirical Cox-Merz rule, which is known to be valid for many other entangled polymer melts. In uniaxial elongational measurements, the viscosity growth functions of the PPCs show a weak deviation from the linear viscoelastic (LVE) envelope to the higher side at the high Weissenberg number Wi d (= ͘ετ d , where ͘ε is the elongation rate and τ d is the characteristic disengagement time). The steady-state viscosity of the PPCs shows an elongational thinning as a function of ͘ε −0.5 within an error. These results are similar to some other polymer melts such as polystyrene (PS). In addition, the normalized elongational viscosity growth functions of PPC and PS with a similar entanglement number Z , are compared. The PPC exhibits a similar viscosity growth curve to the PS at the same Wi d . This result suggests that the degree of the monomeric friction reduction originated from the stretch/orientation of PPC under fast elongational flowmightoccuratthesamelevelasPS.