C. Charalambous, Shanshan Xu, Sheng Ding, Sarayute Chansai, E. Asuquo, Antonio Torres Lopez, Christopher M. A. Parlett, J. Gilmour, Arthur A. Garforth, C. Hardacre
{"title":"Non-thermal plasma activated CO2 hydrogenation over K- and La- promoted layered-double hydroxide supported Ni catalysts","authors":"C. Charalambous, Shanshan Xu, Sheng Ding, Sarayute Chansai, E. Asuquo, Antonio Torres Lopez, Christopher M. A. Parlett, J. Gilmour, Arthur A. Garforth, C. Hardacre","doi":"10.3389/fceng.2022.1027167","DOIUrl":null,"url":null,"abstract":"The catalytic conversion of CO2 to CH4 and CO over nickel particles supported on layered-double hydroxide (MgAl) with different metal promoters was investigated under non-thermal plasma (NTP) conditions. It has been shown that lanthanum-promoted Ni catalysts significantly enhanced the CO2 conversion in comparison to the 10Ni/MgAl catalyst (33.4% vs. 89.3%). In comparison, for the potassium-promoted catalysts, CO2 conversion is similar to that of 10Ni/MgAl but the CO selectivity increased significantly (35.7% vs. 62.0%). The introduction of La and K to Ni catalysts increased the Ni dispersion and improved the reducibility of Ni species, thus affecting CO2 conversion and product selectivity. In situ DRIFTS showed similar reaction pathways for La- and K- promoted catalysts with Ni catalysts. However, the La and K promoters significantly improved the formation of formate species on the Ni surface, facilitating CO2 conversion to useful products.","PeriodicalId":73073,"journal":{"name":"Frontiers in chemical engineering","volume":" ","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2022-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers in chemical engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3389/fceng.2022.1027167","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"BIOTECHNOLOGY & APPLIED MICROBIOLOGY","Score":null,"Total":0}
引用次数: 2
Abstract
The catalytic conversion of CO2 to CH4 and CO over nickel particles supported on layered-double hydroxide (MgAl) with different metal promoters was investigated under non-thermal plasma (NTP) conditions. It has been shown that lanthanum-promoted Ni catalysts significantly enhanced the CO2 conversion in comparison to the 10Ni/MgAl catalyst (33.4% vs. 89.3%). In comparison, for the potassium-promoted catalysts, CO2 conversion is similar to that of 10Ni/MgAl but the CO selectivity increased significantly (35.7% vs. 62.0%). The introduction of La and K to Ni catalysts increased the Ni dispersion and improved the reducibility of Ni species, thus affecting CO2 conversion and product selectivity. In situ DRIFTS showed similar reaction pathways for La- and K- promoted catalysts with Ni catalysts. However, the La and K promoters significantly improved the formation of formate species on the Ni surface, facilitating CO2 conversion to useful products.