ASSESSMENT OF THE DEGREE AND SOURCE OF POLYOLEFIN RECYCLATES CONTAMINATION

IF 1.2 Q4 ENGINEERING, ENVIRONMENTAL Detritus Pub Date : 2021-12-19 DOI:10.31025/2611-4135/2021.15145
A. Alassali, W. Calmano, K. Kuchta
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Abstract

This study has the aim of analysing the degree of contamination of recycled polyolefin purchased from the market by focusing on the content of polycyclic aromatic hydrocarbons (PAHs). Additionally, the impact of the mechanical recycling process on the polyolefin chemical quality was investigated. Results indicated that recycled polyethylene (PE) had higher PAHs concentrations by 10 to 20 folds in comparison to the pristine PE. Similarly, recycled polypropylene (PP) indicated higher PAHs concentrations in comparison to the virgin polypropylene, yet with lower degree of difference. Analysing the 8 indicators assigned by the Regulation EU 1272/2013 amending REACH Annex XVII, all recycled specimens showed concentrations lower than the limit of 0.5 mg kg-1, which indicates that there is no restriction in material’s utilisation. This study functioned as a preliminary assessment to check the suitability of recycled plastics for their further utilisation. Additionally, the study indicates that polyolefin can experience quality deterioration when uncontrolled recycling conditions are applied.
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聚烯烃回收物污染程度及来源评价
本研究的目的是通过关注多环芳烃(PAHs)的含量来分析从市场上购买的回收聚烯烃的污染程度。此外,还研究了机械回收工艺对聚烯烃化学品质量的影响。结果表明,与原始聚乙烯相比,再生聚乙烯(PE)的PAHs浓度高出10-20倍。同样,与原始聚丙烯相比,再生聚丙烯(PP)的PAHs浓度更高,但差异程度较低。通过分析修订REACH附件XVII的欧盟1272/2013号法规指定的8项指标,所有回收样品的浓度均低于0.5 mg kg-1的限值,这表明材料的使用没有限制。这项研究起到了初步评估的作用,以检查回收塑料是否适合进一步利用。此外,研究表明,当采用不受控制的回收条件时,聚烯烃可能会出现质量恶化。
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来源期刊
Detritus
Detritus ENGINEERING, ENVIRONMENTAL-
CiteScore
3.30
自引率
23.50%
发文量
45
审稿时长
15 weeks
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