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Electronic Waste Treatment Flows in Norway: Investigating recycling rates and embodied emissions 挪威的电子废物处理流程:调查回收率和内含排放量
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18331
Kim Rainer Mattson, Lærke Lindgreen Lauritsen, Johan Berg Pettersen
Norway is one of the countries in Europe generating the most waste from electrical and electronic equipment (WEEE) per capita. Extended producer responsibility schemes are incorporated as part of the national waste policy, with clear goals towards recovery of materials from the waste fraction. Investigating the WEEE flows in Norway, we observe clear improvements needed in the transparency of the sector, and based on the information gathered, we estimate lower recycling of materials than provided through official statistics based on reporting. 68% of WEEE sent to recycling treatments are recycled into reusable material. Accounting for WEEE occurring outside of the treatment system, only 58% is recovered for recycling. We also estimate the CO2-eq emissions of different End-of-Life treatments of WEEE, and the embodied CO2-equivalent emissions of each WEEE category, illustrating 1) what category carry the largest environmental burden with respect to its embedded materials, and 2) the environmental impact of specific treatment options within the system. We show how the recycling rate of precious metals have significant influence over the environmental impact recovery potential of the system. Its not just the amount of material that is recycled that is important, including a proxy for expended emissions effectively illustrates the need for more precise policy implementation to ensure a functional circular economy.
挪威是欧洲人均产生电气和电子设备废物(WEEE)最多的国家之一。生产者延伸责任计划是国家废物政策的一部分,其明确目标是从废物中回收材料。通过调查挪威的废弃电子电气设备(WEEE)流向,我们发现该行业的透明度明显有待提高,而且根据收集到的信息,我们估计材料的回收率低于基于报告的官方统计数据。在送往回收处理的废旧电子电器设备中,68%被回收为可再利用材料。如果将处理系统之外的废弃电子电气设备计算在内,则只有 58% 被回收用于循环利用。我们还估算了废弃电器和电子设备不同报废处理方式的二氧化碳当量排放量,以及每类废弃电器和电子设备的二氧化碳当量内含排放量,从而说明:1)哪类废弃电器和电子设备的内含材料对环境造成的负担最大;2)系统内特定处理方案对环境的影响。我们展示了贵金属的回收率如何对系统的环境影响回收潜力产生重大影响。重要的不仅仅是回收材料的数量,还包括消耗排放的替代物,这有效地说明了需要更精确的政策实施,以确保循环经济的功能。
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引用次数: 0
Comparative life cycle assessment of different recycled concrete aggregates 不同再生混凝土骨料的生命周期比较评估
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18324
Mahsa Doostdar, Janus zum Brock, Annachiara Ceraso, Ariana Carolina Morales Rapallo, Kerstin Kuchta
Concrete is recognized as the second most consumed materials in the whole world. Therefore, applying circular solutions to concrete, like recycling or reusing can guarantee a considerable benefits in terms of environmental impacts. In this paper, a comparative life cycle assessment is done for different recipes of recycled concrete aggregates in comparison to a recipe of virgin concrete aggregate, which are used in a case study called “Musterbude”. The recycling rate of aggregates used in the recipes are 45%, 60%, and 100% and they are supplied from different resources. For environmental impacts calculation, each recipe is defined as a scenario and their impacts are compared to each. The life cycle assessment results show that, despite low performance in water depletion indicator, the recipes with 100% recycled aggregates shows the best performance from environmental point of view.
混凝土被认为是全球消耗量第二大的材料。因此,对混凝土采用循环解决方案,如回收或再利用,可确保在环境影响方面获得可观的效益。本文针对名为 "Musterbude "的案例研究中使用的不同再生混凝土骨料配方与原生混凝土骨料配方进行了生命周期比较评估。配方中使用的骨料回收率分别为 45%、60% 和 100%,它们来自不同的资源。在计算环境影响时,每种配方都被定义为一种情景,并将其影响与每种情景进行比较。生命周期评估结果表明,尽管水消耗指标表现较低,但从环境角度来看,使用 100% 再生骨料的配方表现最佳。
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引用次数: 0
Food waste collection versus food waste disposers: A case study of a Portuguese city 泔水收集与泔水处理机:葡萄牙城市案例研究
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18326
Pedro Melo Rodrigues, Ricardo Rodrigues, Fátima David, Nuno Melo, Elisabete Soares
The European Union (EU) prioritises sustainable development and aims to achieve climate neutrality by 2050 through investments in green technologies and a legislative climate framework. Waste collection and treatment systems, including biowaste like food waste, protect natural capital and citizens' well-being. Directive 2008/98/EC defines biowaste and sets the stage for exploring alternative solutions. This study focuses on the city of Guarda (Portugal) and analyses the use of disposers for food waste treatment. By comparing storage/collection systems with disposers regarding environmental and economic costs and benefits, the study aims to determine the most effective solution for collecting food waste. The analysis utilises a simulator provided by the Portuguese Fundo Ambiental®. The results show that while operating costs are higher for food waste collection systems, disposers require a more significant initial investment. Nevertheless, the cost-benefit ratio favours disposers, while the net present value analysis suggests that the food waste collection system is more favourable. Additionally, food waste collection systems contribute to higher greenhouse gas (GHG) emissions per tonne of food waste compared to using disposers.
欧洲联盟(欧盟)将可持续发展作为优先事项,并旨在通过投资绿色技术和立法气候框架,到 2050 年实现气候中和。废物收集和处理系统,包括食物垃圾等生物废物,可保护自然资本和公民的福祉。第 2008/98/EC 号指令对生物垃圾进行了定义,并为探索替代解决方案奠定了基础。本研究以葡萄牙瓜尔达市为重点,分析了使用处理器处理食物垃圾的情况。通过比较储存/收集系统与处理机在环境和经济成本及效益方面的差异,该研究旨在确定收集食物垃圾的最有效解决方案。分析使用了葡萄牙 Fundo Ambiental® 提供的模拟器。结果表明,虽然食物垃圾收集系统的运营成本较高,但垃圾处理器需要更多的初始投资。不过,从成本效益比来看,食物垃圾处理器更有优势,而净现值分析表明,食物垃圾收集系统更有优势。此外,与使用处理器相比,泔水收集系统每吨泔水的温室气体排放量更高。
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引用次数: 0
HOSPITAL WASTE – LEGISLATIVE FRAMEWORK AND MANAGEMENT DIFFERENTIATIONS IN AUSTRIA, BELGIUM, GERMANY AND GREECE 医院废物--奥地利、比利时、德国和希腊的立法框架和管理差异
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18325
Susanne N. Mahnik, Marc Hoffmann, N. Fraeyman, Dimitrios Komilis
In this paper, the differences regarding hospital waste management, specifically regarding the legal and technical situation and the definition of hazardous hospital waste in four member states (Austria, Belgium, Germany and Greece) are presented. All countries follow the legal guidelines of the European Union, but the technical situation, especially the possibilities for thermal waste disposal in incineration plants are different. Also, the definition and categories of hazardous medical wastes is different in the aforementioned four EU member states. The annual production amounts of medical waste in selected countries are presented, as well as criteria that lead to their classification as hazardous medical waste.
本文介绍了四个成员国(奥地利、比利时、德国和希腊)在医院废物管理方面的差异,特别是在法律和技术方面的差异,以及对医院危险废物的定义。所有国家都遵循欧盟的法律准则,但技术状况,特别是在焚烧厂进行热废物处置的可能性有所不同。此外,上述四个欧盟成员国对有害医疗废物的定义和类别也不尽相同。本文介绍了部分国家的医疗废物年产量,以及将其归类为危险医疗废物的标准。
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引用次数: 0
EVALUATION OF DUST EMISSION RATE FROM LANDFILL MINING ACTIVITIES 垃圾填埋场采矿活动的粉尘排放率评估
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18328
Mohammed Zari, Richard Smith, Rebecca Ferrari
Mining operations are one of the most significant sources of particulate emissions in the atmosphere. Landfill mining (LFM) process activities, including excavation, screening, shredding, and equipment handling, have the potential to emit particulate matter into the environment as short-term episodic emissions during operational periods. Previous investigations show that LFM activities can potentially cause human health and environmental impacts through exposure of these emissions. This paper evaluates the dust emission rate of such activities to understand factors responsible for higher emissions rate and determine where any pressure points exist in order to mitigate risk. Nine empirical formulas were adopted from surface mining activities, including point, line, and area sources of activity. Parameters identified in the equations were adjusted to LFM application conditions. From emission results, it is observed that point source activities were the major sources of emission. The study area was divided into multiple phases and one phase cumulative for the maximum/average/minimum point sources emissions over the lifetime of the landfill mining operation calculated in this study are approximately 5.04 tonnes (t) / 3.23 (t) / 1.61 (t), respectively. However, the one phase cumulative for the maximum/average/minimum line sources emissions over the lifetime of the landfill mining operation are approximately 100.8 (kg/m) / 40.32 (kg/m) / 20.16 (kg/m), respectively. Mitigation measures to control high emission rate of LFM related activity, such as utilising tankers or bowsers to spray water around the LFM area, to control airborne emissions, should be considered. The results of this research are expected to inform air dispersion modelling for environmental impact assessment studies of air pollution.
采矿作业是大气中微粒排放的最主要来源之一。垃圾填埋场采矿(LFM)过程活动,包括挖掘、筛选、粉碎和设备处理,都有可能在作业期间以短期偶发排放的形式向环境中排放颗粒物。以往的调查显示,低频炉处理活动可能会通过接触这些排放物对人类健康和环境造成影响。本文对此类活动的粉尘排放率进行了评估,以了解造成较高排放率的因素,并确定存在哪些压力点,从而降低风险。本文采用了地表采矿活动中的九个经验公式,包括点、线和区域活动源。根据 LFM 的应用条件对公式中确定的参数进行了调整。从排放结果来看,点源活动是主要的排放源。研究区域被划分为多个阶段,本研究计算出的垃圾填埋场采矿作业生命周期内最大/平均/最小点源排放量的单阶段累积值分别约为 5.04 吨(t)/3.23 吨(t)/1.61 吨(t)。然而,在堆填區開採期內,最大/平均/最小線源排放量的一階段累積值分別約為 100.8 (kg/m) / 40.32 (kg/m) / 20.16 (kg/m)。应考虑采取缓解措施,控制垃圾填埋场采矿相关活动的高排放率,例如利用水罐车或水车在垃圾填埋场采矿区周围喷水,以控制空气中的排放物。这项研究的结果有望为空气污染环境影响评估研究的空气扩散模型提供参考。
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引用次数: 0
WASTE EGGSHELLS AS CATALYSTS: AN ENVIRONMENTALLY-FRIENDLY APPROACH 废蛋壳作为催化剂:一种环保方法
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18323
Ateeq Rahman, Hilaria Hakwenye, V. Uahengo
Sustainability is crucial for the survival of mankind, ecosystem for the development of society. There have been huge amount of waste have been dumped which creates pollutions. Hence, from Green chemistry perspective it is a protocol to design heterogeneous catalysts which can yield products from waste products with minimization of wastes pollution with environmentally friendly heterogeneous catalytic process for the developed environmentally friendly products with longevity. Such green synthesized heterogeneous catalysts will replace the existing homogeneous process to heterogeneous catalysts being developed from waste materials. This abstract highlight key aspects on the preparation of heterogeneous catalysts derived from waste materials such as egg shell, rice husk for synthesis of Ag Nanoparticles developed, which can applied for biomass conversions, to environmental remediation, heterogeneous catalysts for organic transformations. These egg shell CaO catalysts are characterized using analytical techniques, such as: X-ray diffraction (XRD), Fourier-transform infrared (FT-IR), Thermogravimetric-Differential Thermal Analyzer (TG-DTA), Scanning electron microscope (SEM), Brunauer-Emmett-Teller (BET) surface area, which gives its complete picture of its structure, porosity, morphology, thermal stability, reusability, and activity of catalysts. Hence heterogeneous catalysts developed from egg shell wastes and medical plants will become increasingly popular since two decades. Since, the egg shell waste is developed into egg shell CaO catalysts for cleaner, reusable, eco-friendly catalysts for economic growth for Namibia and other developing and underdeveloped countries.
可持续性对于人类的生存和社会发展的生态系统至关重要。大量废物的倾倒造成了污染。因此,从绿色化学的角度来看,设计异相催化剂是一项协议,它可以从废品中产生产品,并通过环境友好型异相催化过程最大限度地减少废物污染,从而开发出环境友好型的长寿命产品。这种绿色合成的异相催化剂将取代现有的均相工艺,成为从废料中开发的异相催化剂。本摘要重点介绍了从蛋壳、稻壳等废弃材料中提取的异相催化剂的制备关键环节,这些催化剂可用于生物质转化、环境修复、有机转化的异相催化剂。这些蛋壳氧化钙催化剂采用分析技术进行表征,如X 射线衍射 (XRD)、傅立叶变换红外 (FT-IR)、热重-差热分析仪 (TG-DTA)、扫描电子显微镜 (SEM)、Brunauer-Emmett-Teller (BET) 表面积等分析技术对这些蛋壳氧化钙催化剂进行了表征,从而全面了解了催化剂的结构、孔隙率、形态、热稳定性、可重复使用性和活性。因此,二十年来,从蛋壳废料和医疗植物中开发的异相催化剂将越来越受欢迎。将蛋壳废料开发成蛋壳氧化钙催化剂,可为纳米比亚及其他发展中国家和欠发达国家的经济增长提供更清洁、可重复使用、生态友好的催化剂。
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引用次数: 0
Citrus waste fibres for natural cosmetic and bioplastic packaging 用于天然化妆品和生物塑料包装的柑橘废纤维
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18330
Vesna Žepič Bogataj, Peter Fajs, C. Penalva, Georgios Tsatsos
In this work new biocomposite materials from wasted citrus peels has been validated for a value-added packaging and novel cosmetic products. Specifically, extracted natural fibres and dehydrated pulp from citrus fruit were combined with polylactic acid and other additives as materials for the production of bio-based packaging jars and cosmetic products. For the composition of the packaging an orange powder (dehydrated wastes) was found to be the best performing, while orange comminute, which results from milling the orange peel, was most suitable for composition of the cosmetic formulations. Polylactic acid was compounded with citrus fibres by up to 25 wt.% by twin screw extrusion and processed via injection moulding, one of the most widespread processing technologies for producing rigid packaging containers. Composites were characterized, defining their mechanical, morphological and thermal properties. Validation of packaging thermostability performance was performed by Heat deflection temperature in compliance to ISO75 and VICAT softening temperature in accordance with ISO306. Compatibility tests of packaging demonstrators with newly formulated cosmetic products has been investigated as well. An accelerated compatibility test of the cosmetic jars with water and oil-based simulants was performed at ambient temperature, -5 °C, and at 45 °C. The results indicated that new cosmetic packaging are not consistent with water-based cosmetic formulations but are compatible with products based on natural oils. While the price of these products is generally higher than those using conventional plastics, they are competitive for premium cosmetic brands.
在这项工作中,从废弃柑橘皮中提取的新型生物复合材料已被验证可用于生产增值包装和新型化妆品。具体来说,从柑橘类水果中提取的天然纤维和脱水果肉与聚乳酸和其他添加剂相结合,作为生产生物基包装罐和化妆品的材料。研究发现,橘子粉(脱水废料)的性能最佳,而碾磨橘子皮后得到的橘子碎屑最适合用于化妆品配方。通过双螺杆挤压法将聚乳酸与柑橘纤维进行复合,复合比例最高可达 25%,然后通过注射成型法进行加工,注射成型法是生产硬质包装容器最常用的加工技术之一。对复合材料进行了表征,确定了其机械、形态和热性能。根据 ISO75 标准和 ISO306 标准,通过热变形温度和 VICAT 软化温度验证了包装的热稳定性能。此外,还研究了包装演示器与新配制的化妆品的兼容性测试。在环境温度、-5 °C 和 45 °C 下,对化妆品罐与水基和油基模拟物进行了加速兼容性测试。结果表明,新型化妆品包装与水基化妆品配方不一致,但与天然油基产品兼容。虽然这些产品的价格普遍高于使用传统塑料的产品,但对于高档化妆品品牌来说,它们还是具有竞争力的。
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引用次数: 0
WASTE MANAGEMENT WITHIN EUROPEAN UNION: MUST THE DISCOURSE CHANGE? 欧盟内部的废物管理:话语权必须改变吗?
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18332
Oskar Johannson
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引用次数: 0
LIFE CYCLE ASSESSMENT OF SCENARIOS FOR END-OF-LIFE MANAGEMENT OF LITHIUM-ION BATTERIES FROM SMARTPHONES AND LAPTOPS 智能手机和笔记本电脑锂离子电池报废管理方案的生命周期评估
IF 1.7 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-31 DOI: 10.31025/2611-4135/2023.18329
Ana Mariele Domingues, Ricardo Gabbay de Souza, A. R. Ometto, Sandro Donnini Mancini, Flavia Carla dos Santos Martins Padoan, Jose Rocha Andrade da Silva
Recycling lithium-ion batteries (LIBs) is a solution to minimise the environmental problems caused by the consumption of natural resources and the generation of hazardous waste. This paper aims to assess the potential environmental impacts and benefits of four scenarios for recycling LIBs from smartphones and laptops using Life Cycle Assessment (LCA). The methodological approach followed four steps: i) scenario modelling representing the current and future situations of LIBs End-of-Life (EoL) management from smartphones and laptops; ii) estimating smartphones, laptops and respective LIBs waste generation; iii) mapping representative recycling options; and iv) assessment of potential environmental impacts using LCA with 16 ILCD midpoint categories. The results revealed that hydrometallurgical recycling in Brazil could be less harmful than pyrohydrometallurgical recycling in Europe in 12 impact categories. The benefits of recycling are mainly of Co and Ni recovery. Results of scenarios indicate that the more optimistic scenario, which includes expanding Reverse Logistics to 50% of collection, internal recycling to 75%, and reducing of LIBs waste sent to landfills in 44%, had the best environmental performance in all 13 impacts categories. For the Climate change category, scenario 4 presents net environmental benefits of -1.83E+05 kgCO2eq while scenarios 1, 2 and 3 do not present a net environmental benefit. Scenarios assessment shows that more significant environmental benefits are achieved when the formal collection rate is increased, and the less impactful technology option makes the recovery of materials. These results can help decision-makers promote the management and recycling more sustainable of LIBs waste.
回收锂离子电池(LIBs)是一种解决方案,可最大限度地减少因消耗自然资源和产生有害废物而造成的环境问题。本文旨在采用生命周期评估(LCA)方法,评估回收智能手机和笔记本电脑锂离子电池的四种方案对环境的潜在影响和益处。该方法分为四个步骤:i) 模拟智能手机和笔记本电脑锂电池寿命终期(EoL)管理的当前和未来情况;ii) 估算智能手机、笔记本电脑和相应锂电池的废物产生量;iii) 绘制具有代表性的回收方案图;iv) 使用 16 个 ILCD 中点类别的生命周期评估来评估潜在的环境影响。结果显示,在 12 个影响类别中,巴西的湿法冶金回收可能比欧洲的火法冶金回收危害更小。回收利用的益处主要在于钴和镍的回收。各种方案的结果表明,较为乐观的方案(包括将反向物流的收集量扩大到 50%,内部回收利用率达到 75%,将送往垃圾填埋场的惰性金属废料减少 44%)在所有 13 个影响类别中的环境绩效最佳。在气候变化类别中,方案 4 产生的环境净效益为 -1.83E+05 kgCO2eq,而方案 1、2 和 3 没有产生环境净效益。方案评估表明,如果提高正式收集率,并采用影响较小的技术方案进行材料回收,则可实现更显著的环境效益。这些结果可以帮助决策者促进更可持续的惰性气体废物管理和回收。
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引用次数: 0
HYDROTHERMAL CARBONIZATION OF SEWAGE SLUDGE – AN EFFECTIVE APPROACH TO TREAT AND MANAGE SEWAGE SLUDGE IN RURAL AREAS OF GERMANY? 污水污泥的水热碳化-德国农村污水污泥处理和管理的有效方法?
Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-09-30 DOI: 10.31025/2611-4135/2023.18308
Tommy Ender, Vicky Shettigondahalli Ekanthalu, Michael Nelles
As the result of new regulation from the German Sewage Sludge Ordinance (AbfKlärV 2017) and the future obligation to recover phosphorus, thermal treatment (mono-incineration) has become increasingly popular, whereas land-based utilization has decreased. Germany has produced 1.71 million metric tons (DM) of sewage sludge in the year 2021. Sewage sludge contains important nutrients such as phosphorus but also heavy metals and organic pollutants making the direct utilization of sewage sludge in agriculture controversial. Rural areas in particular have benefited from land-based sewage sludge utilization however the future ban on direct land-based utilization is forcing them to find alternative solutions for sewage sludge treatment and management. Hydrothermal carbonization (HTC) has developed considerably over the last 15 years and offers a viable alternative for the utilization of municipal and industrial organic waste such as sewage sludge. The process takes place in an aqueous environment without the need for pre-drying sewage sludge and thereby facilitating direct processing. HTC is especially suitable in combination with the recovery of nutrients like phosphorus. Technologies to recover this essential resource are important because phosphorus is an element that cannot be substituted and is therefore essential. HTC could make a significant contribution to sewage sludge management in combination with phosphorus recovery. However, the technology has yet to establish itself as a sewage sludge valorization process (2023) and is not yet a recognized state-of-the-art. Nevertheless, the HTC technology could gain greater relevance in the future, especially as an alternative valorization pathway for sewage sludge in rural areas of Germany.
由于德国《污水污泥条例》(AbfKlärV 2017)的新规定以及未来回收磷的义务,热处理(单一焚烧)越来越受欢迎,而土地利用则有所减少。德国在2021年生产了171万吨的污水污泥。污水污泥中含有磷等重要营养物质,但也含有重金属和有机污染物,这使得污水污泥在农业上的直接利用存在争议。农村地区尤其受益于土地污泥利用,但未来禁止直接土地利用迫使他们寻找污水污泥处理和管理的替代解决方案。水热炭化(HTC)在过去15年中取得了长足的发展,为城市和工业有机废物(如污水污泥)的利用提供了一种可行的替代方案。该工艺在水环境中进行,不需要预干燥污水污泥,从而便于直接处理。HTC特别适合与磷等营养物质的回收结合使用。回收这一重要资源的技术很重要,因为磷是一种不可替代的元素,因此是必不可少的。HTC与磷回收相结合,可以为污水污泥管理做出重大贡献。然而,该技术尚未成为污水污泥增值过程(2023年),尚未成为公认的最先进技术。尽管如此,HTC技术在未来可能会获得更大的相关性,特别是作为德国农村地区污水污泥的另一种增值途径。
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引用次数: 0
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