Effect of TiO2 particle and pore size on DSSC efficiency

IF 3.6 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials for Renewable and Sustainable Energy Pub Date : 2020-06-08 DOI:10.1007/s40243-020-00173-7
V. A. González-Verjan, B. Trujillo-Navarrete, Rosa María Félix-Navarro, J. N. Díaz de León, J. M. Romo-Herrera, J. C. Calva-Yáñez, J. M. Hernández-Lizalde, E. A. Reynoso-Soto
{"title":"Effect of TiO2 particle and pore size on DSSC efficiency","authors":"V. A. González-Verjan,&nbsp;B. Trujillo-Navarrete,&nbsp;Rosa María Félix-Navarro,&nbsp;J. N. Díaz de León,&nbsp;J. M. Romo-Herrera,&nbsp;J. C. Calva-Yáñez,&nbsp;J. M. Hernández-Lizalde,&nbsp;E. A. Reynoso-Soto","doi":"10.1007/s40243-020-00173-7","DOIUrl":null,"url":null,"abstract":"<p>In this work, we report the preparation of TiO<sub>2</sub> nanoparticles with a high surface area, from 120 to 168 m<sup>2</sup>?g<sup>?1</sup> by the hydrothermal-microemulsion route and hydrothermal temperature effect over particle size, porosity, and photovoltaic parameter. The TiO<sub>2</sub> samples were characterized by Raman, BET, TEM, SEM-FE, I–V curves, and EIS. The increase of hydrothermal temperature correlates with particle and pore size. Although when the synthesis temperature was 250?°C, the surface area presents an unexpected decrease of c.a. 28%. TiO<sub>2</sub> samples were employed as thin-film photo-anodes for dye-sensitized solar cell (DSSC) solar cells. Photovoltaic results showed that the sample prepared at 250?°C presented the more suitable textural properties for the DSSC application. The prepared TiO<sub>2</sub> materials with a particle size of 6.93?±?0.59?nm and anatase crystalline phase favor electron transport and diffusion of electrolyte species, which directly impact in solar cell efficiency.</p>","PeriodicalId":692,"journal":{"name":"Materials for Renewable and Sustainable Energy","volume":null,"pages":null},"PeriodicalIF":3.6000,"publicationDate":"2020-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s40243-020-00173-7","citationCount":"20","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials for Renewable and Sustainable Energy","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1007/s40243-020-00173-7","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 20

Abstract

In this work, we report the preparation of TiO2 nanoparticles with a high surface area, from 120 to 168 m2?g?1 by the hydrothermal-microemulsion route and hydrothermal temperature effect over particle size, porosity, and photovoltaic parameter. The TiO2 samples were characterized by Raman, BET, TEM, SEM-FE, I–V curves, and EIS. The increase of hydrothermal temperature correlates with particle and pore size. Although when the synthesis temperature was 250?°C, the surface area presents an unexpected decrease of c.a. 28%. TiO2 samples were employed as thin-film photo-anodes for dye-sensitized solar cell (DSSC) solar cells. Photovoltaic results showed that the sample prepared at 250?°C presented the more suitable textural properties for the DSSC application. The prepared TiO2 materials with a particle size of 6.93?±?0.59?nm and anatase crystalline phase favor electron transport and diffusion of electrolyte species, which directly impact in solar cell efficiency.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
TiO2颗粒和孔径对DSSC效率的影响
在这项工作中,我们报道了高表面积TiO2纳米粒子的制备,从120到168 m2?g?1 .通过热液-微乳液途径和热液温度对颗粒尺寸、孔隙度和光伏参数的影响。采用Raman、BET、TEM、SEM-FE、I-V曲线和EIS对TiO2样品进行了表征。热液温度的升高与颗粒和孔隙大小有关。虽然当合成温度为250?°C时,表面积意外地减少了约28%。采用TiO2样品作为染料敏化太阳能电池(DSSC)的薄膜光阳极。光伏结果表明,制备的样品在250?°C表现出更适合DSSC应用的织构性能。制备的TiO2材料粒径为6.93±0.59?纳米和锐钛矿晶相有利于电解质物质的电子传递和扩散,直接影响太阳能电池的效率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Materials for Renewable and Sustainable Energy
Materials for Renewable and Sustainable Energy MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
7.90
自引率
2.20%
发文量
8
审稿时长
13 weeks
期刊介绍: Energy is the single most valuable resource for human activity and the basis for all human progress. Materials play a key role in enabling technologies that can offer promising solutions to achieve renewable and sustainable energy pathways for the future. Materials for Renewable and Sustainable Energy has been established to be the world''s foremost interdisciplinary forum for publication of research on all aspects of the study of materials for the deployment of renewable and sustainable energy technologies. The journal covers experimental and theoretical aspects of materials and prototype devices for sustainable energy conversion, storage, and saving, together with materials needed for renewable fuel production. It publishes reviews, original research articles, rapid communications, and perspectives. All manuscripts are peer-reviewed for scientific quality. Topics include: 1. MATERIALS for renewable energy storage and conversion: Batteries, Supercapacitors, Fuel cells, Hydrogen storage, and Photovoltaics and solar cells. 2. MATERIALS for renewable and sustainable fuel production: Hydrogen production and fuel generation from renewables (catalysis), Solar-driven reactions to hydrogen and fuels from renewables (photocatalysis), Biofuels, and Carbon dioxide sequestration and conversion. 3. MATERIALS for energy saving: Thermoelectrics, Novel illumination sources for efficient lighting, and Energy saving in buildings. 4. MATERIALS modeling and theoretical aspects. 5. Advanced characterization techniques of MATERIALS Materials for Renewable and Sustainable Energy is committed to upholding the integrity of the scientific record. As a member of the Committee on Publication Ethics (COPE) the journal will follow the COPE guidelines on how to deal with potential acts of misconduct. Authors should refrain from misrepresenting research results which could damage the trust in the journal and ultimately the entire scientific endeavor. Maintaining integrity of the research and its presentation can be achieved by following the rules of good scientific practice as detailed here: https://www.springer.com/us/editorial-policies
期刊最新文献
Effect of scandium concentration on the performances of cantilever based AlN unimorph piezoelectric energy harvester with silicon nitride substrate Enhanced electrochemical validation of metal organic frameworks-derived TiO2/Fe-TiO2 as an active electrode for supercapacitors The photothermal properties of hydrogel nanocomposite embedded with ZnO/CuO based on PVA/GA/activated carbon for solar-driven interfacial evaporation Formulation and development of composite materials for thermally driven and storage-integrated cooling technologies: a review Novel Nafion nanocomposite membranes embedded with TiO2-decorated MWCNTs for high-temperature/low relative humidity fuel cell systems
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1