Orthogonal Experimental Research the Gangue in Gallium Extraction Conditions

Tian Aijie, Tian Aimin, Kong Lingliang, Liu Zhenxue
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Abstract

After mining for many years, the coal gangue piles up, not only occupies a large amount of land, but also causes serious pollution. Therefore, the treatment and utilization of coal gangue has become an important topic for coal mining and environmental protection departments. The inorganic components of coal gangue are mainly SiO2 and Al2O3, followed by Fe2O3, generally accounting for 75%~80% of all components. Organic components are mainly composed of Carbon, Hydrogen, Oxygen, Nitrogen and organic Sulfur, accounting for 20%~25% of all components of oal gangue. In addition, the gangue also contains a small amount of Gallium, Alum, Germanium and other rare earth elements. In recent years, the research of extracting Gallium from other raw materials has developed rapidly. In order to make full use of the waste of resources, turning waste into treasure, improve the economic and social benefits, the paper adopted orthogonal experiment to explore the the gangue gallium extraction conditions. The experiments take the high-temperature acid leaching method of orthogonal experimental design experimental conditions. Acid concentration, ignition temperature, ignition time, the acid leaching temperature, leaching time and other factors on the extraction rate of gallium. After a large number of scientific comparison of the experimental conditions, to get the better conditions of the extraction of gallium that acid concentration 6mol / L, the ignition temperature of 600°C, the ignition time 0.5h, acid leaching temperature of 100°C, leaching time for 6 h. The extraction rate of 95%, provide a viable experimental conditions for the gangue gallium extraction.
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脉石中镓提取条件的正交试验研究
经过多年的开采,煤矸石堆积,不仅占用了大量的土地,而且造成了严重的污染。因此,煤矸石的处理和利用已成为煤矿和环保部门的一个重要课题。煤矸石的无机成分主要为SiO2和Al2O3,其次为Fe2O3,一般占所有成分的75%~80%。有机组分主要由碳、氢、氧、氮和有机硫组成,占煤矸石所有组分的20%~25%。此外,脉石中还含有少量的镓、铝、锗等稀土元素。近年来,从其他原料中提取镓的研究发展迅速。为了充分利用资源浪费,变废为宝,提高经济效益和社会效益,采用正交试验法对脉石镓的提取条件进行了探讨。实验采用高温酸浸法正交实验设计实验条件。酸浓度、灼烧温度、灼烧时间、酸浸温度、浸出时间等因素对镓的提取率有影响。通过对实验条件的大量科学比较,得出了较佳的提取镓的条件:酸浓度6mol/L,点火温度600°C,点火时间0.5h,酸浸温度100°C,浸出时间6h,提取率95%,为脉石镓的提取提供了可行的实验条件。
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CiteScore
3.50
自引率
0.00%
发文量
6
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