Laser scattering, optical constants and connection to other material performances (Kerr constant, mobility/diffusion coefficient/electrophoresis and depolarization)

M. Sreckovic, A. Tistchenko, Sanja Jevtić, B. Kaludjerovic, S. Pelemiš, Katarina Zarubica, V. Zarubica
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Abstract

Scattering of optical photons from the view of parallel methods related to absorption, scattering, fluorescence, reflection with inclusion of the polarization states of laser beams from experiment and theory give many possibilities for obtaining indirect data on material, processes, and dynamics. As a method with minimal perturbations, if low power beams are involved, certain type of data is provided. In fundamental dependences of various material properties, many phenomenological and basic laws are covered. Several coupled variables, primarily with the processes of scattering, pointing out further possibilities for linking the obtained theoretical or experimental results were presented. By including simulations, this associates with biological environments / variables for properties equivalent to defined tissues, cells, and characteristics. Along with selected formalisms including Stokes vectors and scattering matrices, a biological cell as an object can be monitored in time and influence of various environments could be predicted. Connecting Kerr’s effect with depolarization and scattering makes the complete description of molecule possible. Angular scattering observation with experimental possibilities gives the fastest practical data. This enables interpretation of E. coli with the application of Stokes vector formalisms. A relatively small number of material constants for many simulation cases could give draft estimation, but the experiment depends on the measuring devices and samples. The necessary symmetries showing the size of the scattering centers are analyzed, with the scattering data for some liquids (known / less known). From measured data, depolarization could be calculated, and with refractive index (molar refraction) connection with Kerr effect/ birefringence for selected solutions and behavior of molecules could be monitored. From the experimental Rayleigh factors, cross section (apparent/ effective) and attenuation coefficients for pure liquids were calculated. An approach for the correct assessment of the measurement uncertainty in the process of calibration of polyethylene samples was used.
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激光散射、光学常数和与其他材料性能的联系(克尔常数、迁移率/扩散系数/电泳和去极化)
从与吸收、散射、荧光、反射相关的平行方法的角度来看,光学光子的散射,包括实验和理论中激光束的偏振态,为获得材料、过程和动力学的间接数据提供了许多可能性。作为一种具有最小扰动的方法,如果涉及低功率波束,则提供特定类型的数据。在各种材料性质的基本依赖关系中,涵盖了许多现象学和基本定律。几个耦合变量,主要是散射过程,指出了将所获得的理论或实验结果联系起来的进一步可能性。通过包括模拟,这与生物环境/变量的特性等效于定义的组织、细胞和特征。除了包括斯托克斯矢量和散射矩阵在内的选定形式外,还可以实时监测作为对象的生物细胞,并预测各种环境的影响。将克尔效应与去极化和散射联系起来,使得对分子的完整描述成为可能。具有实验可能性的角散射观测提供了最快的实际数据。这使得能够应用斯托克斯矢量形式主义来解释大肠杆菌。对于许多模拟情况,相对少量的材料常数可以给出草案估计,但实验取决于测量设备和样品。分析了显示散射中心大小的必要对称性,以及一些液体(已知/未知)的散射数据。根据测量数据,可以计算去极化,并通过折射率(摩尔折射率)与所选溶液的克尔效应/双折射的联系,可以监测分子的行为。根据实验瑞利因子,计算了纯液体的横截面(表观/有效)和衰减系数。在聚乙烯样品的校准过程中,使用了一种正确评估测量不确定度的方法。
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