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Neural network modeling methods for predicting the air parameters in the city of Tuzla 预测图兹拉市空气参数的神经网络建模方法
Pub Date : 2020-06-17 DOI: 10.7251/jepm2001029a
D. Agić́, H. Makic, G. Tadic, M. Gligoric, S. Agic
According to the report of the World Health Organization, the city of Tuzla is the second in the world, and the first in Europe in terms of the number of diseases caused by air pollution. Tuzla Canton since 2003 has continuous air monitoring. Concentrations of individual pollutants exceed hourly, daily and annual limit values. In this paper, based on the existing results of air monitoring and meteorological data, using statistical methods and neural network modeling methods, unique and reliable models for predicting the concentration of NO2 in the air for the City of Tuzla have been developed. The results obtained using these models can be used in strategic decision-making processes and activities related to air quality control and management. This paper, on the example of the City of Tuzla, showed that using existing air monitoring data, concentrations of pollutants can be predicted for a longer period of time, using artificial intelligence methods. Reliable models with a high correlation coefficient can be obtained. In the case of a short or long interruption of the measurement of pollutant concentrations for the City of Tuzla with the help of models, which are the result of this work, it is possible to predict the concentrations of pollutants and plan to take measures based on them.
根据世界卫生组织的报告,就空气污染引起的疾病数量而言,图兹拉市在世界上排名第二,在欧洲排名第一。图兹拉州自2003年开始进行连续空气监测。个别污染物的浓度超过小时、日和年限制值。本文在现有大气监测成果和气象资料的基础上,运用统计方法和神经网络建模方法,建立了图兹拉市大气NO2浓度预测的独特、可靠的模型。使用这些模型获得的结果可用于与空气质量控制和管理有关的战略决策过程和活动。本文以图兹拉市为例,表明利用现有的空气监测数据,利用人工智能方法可以预测更长的时间内污染物的浓度。可以得到具有高相关系数的可靠模型。在利用这项工作的结果模型对图兹拉市的污染物浓度进行测量的情况下,如果有短期或长期的中断,就有可能预测污染物的浓度,并根据这些浓度计划采取措施。
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引用次数: 0
Effects of drilling parameters on TI-6Al-4V alloy using different coolants 不同冷却液对TI-6Al-4V合金钻孔参数的影响
Pub Date : 2020-06-17 DOI: 10.7251/jepm2001025b
Roopsandeep Bammidi, P. Rao, K. Prasad
The formulation or application of coolants plays a critical role in machining to bring out the best finished products. In this scientific article, the study focused on the effects of coolants and machining parameters of Ti-6Al-4V are investigated with consideration of their performances by using drilling operation. The design of ex- periments (DOE) was considered and the performance of machining was measured with respect to cutting temperatures and surface responses. The final results put forward that the excellent surface finish and minimal cutting temperatures are ob- tained by application of power metcut s plus when compared with pure water. The factors that impact the surface roughness of Ti-6Al-4V are coolant and feed rate. The coolant also helps in the machining process by reducing temperature at the cutting zone.
冷却剂的配方或应用在机械加工中起着关键作用,以生产出最佳的成品。在这篇科学的文章中,重点研究了冷却剂和加工参数对Ti-6Al-4V的影响,并考虑到它们的性能。考虑了实验设计(DOE),并测量了加工性能与切削温度和表面响应的关系。最后的结果表明,与纯水相比,使用power metcut s plus可以获得良好的表面光洁度和最低的切削温度。影响Ti-6Al-4V表面粗糙度的因素有冷却液和进料速率。冷却液还通过降低切削区的温度来帮助加工过程。
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引用次数: 0
3D model of a Monolithic Honeycomb Adsorber for Electric Swing Adsorption for Carbon Dioxide Capture 用于二氧化碳电摆动吸附的整体式蜂窝吸附器的三维模型
Pub Date : 2020-06-17 DOI: 10.7251/jepm2001001d
Ivaná Đukic, Marija Ječmenica Dučić, N. Nikačević, M. Petkovska
The goal of this work was to develop a 3D model of Electric Swing Adsorption pro- cess for carbon dioxide capture from effluent gasses from power plants. Detailed 3D model of the composite honeycomb monolithic adsorber was developed for a sin- gle monolith channel and can be used to simulate and represent different physical properties: velocity, concentration and temperature. The advantage of this model is the fact that all physical properties and results can be presented visually in the 3D domain. COMSOL Multiphysics software was used for solving partial differential equations and simulations of adsorption and electrothermal desorption processes. Some simulation results are presented in this work. The results obtained from 3D simulations will be used for the adsorber model reduction to the 1D model which will be used for modeling and optimization of the whole ESA cycle due to its sim- plicity and computational demands. Simulation and optimization runs based on the 1D model will be performed in g-Proms software.
这项工作的目标是开发一个电动摇摆吸附过程的3D模型,用于从发电厂的废气中捕获二氧化碳。针对单体通道,建立了复合材料蜂窝整体吸附器的详细三维模型,可用于模拟和表示不同的物理特性:速度、浓度和温度。该模型的优点在于,所有物理特性和结果都可以在3D域中可视化呈现。COMSOL Multiphysics软件用于求解偏微分方程和模拟吸附和电热解吸过程。本文给出了一些仿真结果。从3D模拟中获得的结果将用于将吸附器模型简化为1D模型,由于其复杂性和计算需求,1D模型将用于整个ESA循环的建模和优化。基于一维模型的模拟和优化运行将在g-Proms软件中进行。
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引用次数: 0
Cloud Point Extraction as a Method for Preconcentration of Metal Ions 云点萃取作为金属离子富集的方法
Pub Date : 2020-06-17 DOI: 10.7251/jepm2002044h
N. Hasić, E. Horozić
Cloud point extraction (CPE) is an attractive technique that reduces solvent con- sumption and exposure, disposal costs, and process time. This method has an im- portant practical application and is used to separate and concentrate the analyte as a step before its determination, and after the formation of a poorly water-soluble complex. Use of nonionic surfactants as ”green solvents” which represent an effec- tive alternative to toxic organic solvents (in classical extraction), along with other advantages, such as low cost and low flammability, makes this method attractive and worth further research and optimization. This paper presents a detailed de- scription of the principles, procedure, advantages, disadvantages and application of CPE.
浊点萃取(CPE)是一种有吸引力的技术,可以减少溶剂消耗和暴露、处理成本和工艺时间。该方法具有重要的实际应用,用于在测定前和形成水溶性差的络合物后分离和浓缩分析物。使用非离子表面活性剂作为“绿色溶剂”,代表了有毒有机溶剂的有效替代品(在经典萃取中),以及其他优点,如低成本和低易燃性,使该方法具有吸引力,值得进一步研究和优化。本文详细介绍了CPE的原理、程序、优点、缺点和应用。
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引用次数: 0
Quality testing of industrially produced essential oil of white pine (Pinus sylvestris L.) from the Republic of Srpska 塞族共和国工业生产的白松精油的质量测试
Pub Date : 2020-06-17 DOI: 10.7251/jepm2002036b
Vesna Gojković Cvjetković, Z. Marjanovic-Balaban, M. Kapović-Solomun, L. Stanojević, J. Stanojević, V. Kalaba
The quality of the essential oil obtained from white pine wood greenery from the territory of the Republic of Srpska was analyzed by examining the chemical composi- tion and antimicrobial activity of samples produced by the hydro-distillation process in industrial production conditions. The chemical composition of the essential oil was analyzed by GC/MS and GC/FID analysis. The antimicrobial activity of the ob- tained white pine oil was investigated for its possible use as an antimicrobial agent. The obtained results prove the presence of 37 components in the analyzed sam- ple, which represents 98.5% of the total components present. The most common are monoterpene hydrocarbons, followed by sesquiterpene hydrocarbons, much less represented are monoterpenes containing oxygen and aromatic compounds, while aliphatic esters are found only in traces. Antimicrobial activity was examined using the disk diffusion method. The results showed large zones of inhibition, both for the tested oil sample and for all eight analyzed bacterial strains (from 12.00 ± 0.00 to 17.33 ± 1.15mm), as well as for the fungal strain. The chemical composition and antimicrobial action of essential white pine oiled from plant material originating from the territory of the Republic of Srpska indicates its significant phytomedical potential.
通过检查工业生产条件下加氢蒸馏工艺生产的样品的化学成分和抗菌活性,分析了从塞族共和国境内的白松木绿色植物中获得的精油的质量。采用GC/MS和GC/FID分析方法对其化学成分进行了分析。研究了所得白松油的抗菌活性,以探讨其作为抗菌剂的可能用途。所获得的结果证明分析样品中存在37种成分,占总成分的98.5%。最常见的是单萜烯烃,其次是倍半萜烃,含氧和芳香化合物的单萜烯代表性要小得多,而脂族酯只存在于微量中。采用纸片扩散法检测抗菌活性。结果显示,测试的油样品和所有八种分析的菌株(从12.00±0.00到17.33±1.15mm)以及真菌菌株都有大的抑制区。从原产于塞族共和国领土的植物材料中提炼的精油白松的化学成分和抗菌作用表明了其巨大的植物医学潜力。
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引用次数: 0
Simulation of a single-stage evaporator system integrated with a mechanical vapor compressor for concentrating the electrolytic system KNO3 – H2O 与机械蒸汽压缩机集成的单级蒸发器系统的模拟,用于浓缩电解系统KNO3–H2O
Pub Date : 2020-06-17 DOI: 10.7251/jepm2002050k
Ervin Karić, Rejha Alić
A simulation of a single-stage evaporator system integrated with a mechanical com- pressor for a case study (concentrating the electrolytic system KNO3 – H2O) was performed. A mathematical model of the subsystem of a single-stage evaporator, a mechanical compressor, and superheated steam seeding is presented. Microsoft Excel with VBA (Visual Basic for Application) was used to solve the mathematical model. The model was solved by an iterative method where the values of the in- let stream temperature and the salt concentration in the concentrated stream at the evaporator outlet were assumed. The process parameters of the system have been determined. Since the goal of any industrial process is to minimize costs and maximize products, the impact of mean temperature difference changes on satu- ration water consumption and molar salt content in the concentrated stream was presented. 106.92 kg/h of freshwater are required to obtain 18% by weight of salt in a concentrated stream, while 432.30 kg/h of fresh water are required to obtain 25% by weight of salt in a concentrated stream. Consumption of heating steam ranged from 1760.31 to 4473.4 kg/h depending on the average temperature dif- ference. By increasing the temperature differences from 10 to 25 ◦C, the amount of transferred upper lines increases from 1025 to 2750 kW, which is an advantage of increasing the mean temperature difference. The disadvantage of the larger tem- perature difference is the increase in the power of the mechanical compressor from 97.02 to 384.12 kW.
对与机械压缩机集成的单级蒸发器系统进行了模拟,以进行案例研究(浓缩电解系统KNO3–H2O)。建立了单级蒸发器、机械压缩机和过热蒸汽播种子系统的数学模型。使用Microsoft Excel和VBA(Visual Basic for Application)对数学模型进行求解。该模型通过迭代方法求解,其中假设蒸发器出口处浓流中的入流温度和盐浓度的值。系统的工艺参数已经确定。由于任何工业过程的目标都是最小化成本和最大化产品,因此介绍了平均温差变化对饱和水消耗和浓物流中摩尔盐含量的影响。需要106.92千克/小时的淡水才能在浓缩流中获得18%重量的盐,而需要432.30千克/小时淡水才能在浓流中获得25%重量的盐。加热蒸汽消耗量在1760.31至4473.4 kg/h之间,具体取决于平均温差。通过将温差从10增加到25◦C、 传输的上层线路的量从1025kW增加到2750kW,这是增加平均温差的优点。温差较大的缺点是机械压缩机的功率从97.02增加到384.12 kW。
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引用次数: 0
Packaging materials and articles for food: legislation and codes of good manufacturing practice 食品包装材料和制品:良好生产规范的立法和规范
Pub Date : 2020-06-17 DOI: 10.7251/jepm2001015k
A. P. Kujundziski, D. Chamovska
The basic objectives of food packaging materials are to provide safety and to pre- vent physical damage of the product, to retain or improve sensory characteristics, to offer a pleasing appearance, to be functional, to facilitate distribution, to give dimensional stability, but also to be compatible with the requirements regulated by the law. Consumers’ demands for an extended shelf life of the product, as well as increased competition in the packaging industry, foster the need for continuous growth and application of innovative solutions for food packaging. While the tradi- tional packaging acts as a passive barrier toward atmospheric effects, the innovative packaging systems offer “active” interactions with the foodstuff, providing increased shelf life and improved quality of the product. The selection of the appropriate pack- aging material is influenced by many factors, and, among many packaging materi- als offered on the market, polymer materials and articles have a significant place. On the other hand, some interactions occur between the plastics and the food in contact. The migration of the low-molecular-weight components from the polymer packaging to the packed food is emphasized when the so-called active and intelli- gent systems are used. Therefore, all the issues related to the packaging materials for food and the substances used as part of the packaging systems, are elaborated in the directives and regulations of the materials and articles intended to come in contact with the food.
食品包装材料的基本目标是提供安全性和防止产品的物理损坏,保持或改善感官特性,提供令人愉悦的外观,具有功能性,便于分销,具有尺寸稳定性,但也符合法律规定的要求。消费者对延长产品保质期的需求,以及包装行业竞争的加剧,促进了对食品包装创新解决方案的持续增长和应用的需求。而传统的包装作为一个被动的屏障对大气的影响,创新的包装系统提供“主动”的相互作用与食品,提供延长的保质期和提高产品的质量。选择合适的包装老化材料受多种因素的影响,在市场上提供的众多包装材料中,高分子材料和制品占有重要的地位。另一方面,塑料和接触的食物之间会发生一些相互作用。当使用所谓的主动和智能系统时,强调了低分子量组分从聚合物包装到包装食品的迁移。因此,与食品包装材料和作为包装系统一部分使用的物质相关的所有问题都在与食品接触的材料和物品的指令和法规中进行了详细说明。
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引用次数: 0
HOW DOES CRYOGENIC FREEZING AFFECT THE CALORIMETRIC PROPERTIES OF LIQUID EGG PRODUCTS? 低温冷冻如何影响液态蛋制品的量热特性?
Pub Date : 2019-11-12 DOI: 10.7251/jepm1901001h
Hidas Karina Ilona, I. C. Nyulas-Zeke, L. Friedrich, Anna Visy, Judit Csonka, C. Németh
Eggs are widely utilized because of their high nutrient value, coagulating, foaming, emulsifying and sometimes even colouring or flavouring facilities in food manufacturing. Production of processed egg products shows an increasing trend. Frozen products belong to first processing, their shelf life can increase up to 1 year. By freezing, a large reduction in microbial loss can be achieved. But different undesirable processes can occur. The effect of freezing on animal cells is highly dependent on freezing parameters. It has a different effect on egg subtituents. Egg yolk undergoes a gelation process while proteins can denaturate. In our study pasteurized liquid egg products (liquid egg white, liquid egg yolk and liquid whole egg) were frozen by dripping into liquid nitrogen. After that, a 14-day frozen storage experiment was carried out at -18°C. Before freezing and on the 1th, 7th and 14th days of storage experiment pH, dry matter content, colour and calorimetric properties (denaturation temperatures and enthalpy of denaturation) with differential scanning calorimetry were tested. For statistical analysis, one-way ANOVA (α = 0.05) was employed. In our experiment, we found no significant change in calorimetric properties of liquid egg white after freezing, but significant decreasing of enthalpy and denaturation temperatures of liquid egg yolk and liquid whole egg was identified. In contrast, frozen storage had a decreasing effect in all these products. Freezing caused a clearly visible colour change in LEW, a visible change in colour of LWE and a very clearly visible change in colour of LEY. In case of LEW and LEY changes increased to clearly visible 14 days. In conclusion, our results show that frozen storage had a greater effect on liquid egg products properties than freezing in liquid nitrogen.
鸡蛋因其营养价值高、凝结、发泡、乳化,有时甚至在食品制造中具有着色或调味设施而被广泛使用。加工蛋类产品的产量呈增长趋势。冷冻产品属于首次加工,其保质期可延长至1年。通过冷冻,可以大大减少微生物的损失。但是可能会出现不同的不希望的过程。冷冻对动物细胞的影响在很大程度上取决于冷冻参数。它对鸡蛋的潜台词有不同的影响。蛋黄经历一个凝胶化过程,而蛋白质可以变性。在我们的研究中,巴氏灭菌的液态蛋制品(液态蛋清、液态蛋黄和液态全蛋)通过滴入液氮中冷冻。之后,在-18°C下进行为期14天的冷冻储存实验。在冷冻前和储存实验的第1、7和14天,用差示扫描量热法测试pH、干物质含量、颜色和量热性质(变性温度和变性焓)。统计分析采用单因素方差分析(α=0.05)。在我们的实验中,我们发现冷冻后液体蛋清的量热性质没有显著变化,但液体蛋黄和液体全蛋的焓和变性温度显著降低。相比之下,冷冻储存对所有这些产品都有减少作用。冰冻导致LEW的颜色发生明显变化,LWE的颜色发生可见变化,LEY的颜色发生非常明显的变化。在LEW和LEY的情况下,变化增加到清晰可见的14天。总之,我们的研究结果表明,冷冻储存对液态蛋制品性能的影响比在液氮中冷冻更大。
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引用次数: 0
Using structural equation model to estimate nitrate pollution in the Melen Watershed of the Turkey 用结构方程模型估算土耳其梅伦流域硝酸盐污染
Pub Date : 2019-11-12 DOI: 10.7251/jepm1901031a
M. E. Akıner
In this study, Bayesian technique was applied in order toestimate export coefficients for the Melen Watershed.Furthermore, instead of calculating the contributions ofsubwatersheds individually, the whole watershed was consideredfor the estimation of the total load at the outlet of the MelenWatershed using the calculated nitrate export coefficient. TheBayesian approach has the goal of combining prior knowledgewith data to optimally use both sources of information. Success ofthe Bayesian approach is directly proportional to sufficiency ofdata for acquiring the prior information about estimands.Bayesian analysis was conducted through Structural EquationModel (SEM) using AMOS software and posterior informationabout land use based export coefficients was obtained throughMarkov Chain Monte Carlo (MCMC) method. Estimated land usebased nitrate export coefficients are in kg/km2/day unit. Inaddition, monthly river retention value of nitrogen in allsubwatersheds of the Melen Watershed were estimated. Thisinformation was used in order to predict nitrate exportcoefficients appropriately. This study is aimed to be an importantprecedent for other basins that are determined as in priority interms of pollution by The Ministry of Forest and Water Works ofTurkey.
在本研究中,贝叶斯技术用于估计梅伦流域的出口系数。此外,使用计算的硝酸盐出口系数来估计MelenWatershed出口的总负荷时,考虑了整个流域,而不是单独计算子流域的贡献。贝叶斯方法的目标是将先验知识与数据相结合,以最佳地使用两个信息源。贝叶斯方法的成功与获取估计的先验信息的数据充分性成正比。利用AMOS软件通过结构方程模型(SEM)进行贝叶斯分析,通过马尔可夫链蒙特卡罗(MCMC)方法获得基于土地利用的出口系数后验信息。基于土地利用的硝酸盐出口系数以千克/平方公里/天为单位。此外,还估算了梅伦流域各子流域氮的月河流滞留值。利用这些信息对硝酸盐出口系数进行了预测。本研究旨在为土耳其森林和水工部确定的其他优先污染流域提供重要的先例。
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引用次数: 0
Removing Products of Thermal Degradation from Edible Oils by Zeolite and by Clinoptilolite - Comparison of Results 沸石与斜沸石去除食用油热降解产物的比较
Pub Date : 2019-11-12 DOI: 10.7251/jepm1901024d
S. Dobrnjac, L. Vasiljević, S. Blagojević, M. Gligoric, Z. Obrenović, Vesna Cvijetinović, D. Tosković
When edible oils are heated above 150°C, they undergo thermo-oxidative changes depending on a variety of factors, such as temperature, heating time, type of oil, etc. These changes cause a series of chemical reactions (hydrolysis, oxidation, polymerization, etc.) resulting in the formation of free fatty acids, an increase in the peroxide number and the acid number, a change of color and a decrease in the iodine number. This study investigates changes of the content of free fatty acids, the acid number, and the peroxide number in edible sunflower oil when heating at the temperature range from 110°C to 190°C for 30 minutes, as well as after the adsorption by a natural and a synthetic adsorbent (clinoptilolite and zeolite 4A). The results of the research show that these adsorbents are effective in removing the products of chemical reactions occurring in thermal degradation, which is particularly evident after the adsorption of oil heated at 190°C. Somewhat better results were achieved after the adsorption using clinoptilolite, with a 72 % reduction in the content of free fatty acids, 83 % reduction in the acid number, and 43 % reduction in the peroxide number. After the adsorption by zeolite 4A, the content of free fatty acids was reduced by 65%, the acid number by 76 %, and the peroxide number by 39 %. The results obtained open the possibilities of further research aiming at discovering the adsorbents which would be most suitable for the regeneration of used edible oils, after which they could be applied safely for different purposes.
当食用油被加热到150℃以上时,根据温度、加热时间、油的种类等多种因素,它们会发生热氧化变化。这些变化引起一系列的化学反应(水解、氧化、聚合等),导致游离脂肪酸的形成,过氧化值和酸值增加,颜色改变,碘值降低。本研究考察了食用葵花籽油在110℃~ 190℃温度范围内加热30分钟,以及天然吸附剂和合成吸附剂(斜沸石和4A沸石)吸附后,游离脂肪酸含量、酸值和过氧化氢值的变化。研究结果表明,这些吸附剂对热降解过程中发生的化学反应产物有较好的去除效果,对加热190℃的油吸附效果尤其明显。斜发沸石吸附后效果稍好,游离脂肪酸含量降低72%,酸数降低83%,过氧化物数降低43%。经4A沸石吸附后,游离脂肪酸含量降低65%,酸值降低76%,过氧化物值降低39%。研究结果为进一步研究发现最适合食用油再生的吸附剂提供了可能,之后它们可以安全地应用于不同的用途。
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引用次数: 0
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Journal of Engineering Processing Management
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