Activated carbon paper as ethylene adsorber

IF 0.9 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Nordic Pulp & Paper Research Journal Pub Date : 2022-12-13 DOI:10.1515/npprj-2022-0082
Qanytah, Khaswar Syamsu, F. Fahma, G. Pari, Indrie Ambarsari
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Abstract

Abstract The use of activated carbon with KMnO4 activators incorporated on the paper matrix is carried out in this research. Three methods of activated carbon incorporation on paper are carried out to evaluate the paper’s physical parameters and adsorption ability to ethylene. The paper’s physical parameters include grammage, bursting strength, Ring Crush Test (RCT), moisture content, water absorption (Cobb60), and paper microstructures using SEM. Evaluation of the performance of activated carbon paper nanopores as ethylene adsorbent is conducted using GC. The treatment of activated carbon nanopores on non-wood paper causes grammage to increase, but RCT and paper bursting strength decrease. The incorporation of nanopore-activated carbon by the mixing method has produced papers with activated carbon particles spread evenly inside the pulp fibers of the paper. Activated carbon paper with the best adsorption capacity is bamboo+KMnO4&mixing with an adsorption capacity of 1,348 ppm and ethylene amount of 88.58 %. Concentration equilibrium is reached in the 25th minute. The non-linear pseudo-first-order absorbent kinetics model is an appropriate model to describe the equilibrium capacity of ethylene entrant (qe) by nanopore-activated carbon paper with the equation: qt = 1.35734 ( 1 − exp − 0.15312 t ) \mathrm{qt}=1.35734\hspace{0.1667em}(1-{\exp ^{-0.15312\hspace{0.1667em}\mathrm{t}}}) , with R 2 = 0.9981 {\mathrm{R}^{2}}=0.9981 .
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活性炭纸作为乙烯吸附器
摘要:本研究采用在纸基体上掺入KMnO4活化剂的活性炭。采用三种方法对活性炭在纸上的吸附性能进行了评价。纸张的物理参数包括克重、破裂强度、环压试验(RCT)、含水率、吸水率(Cobb60)和扫描电镜下的纸张微观结构。采用气相色谱法对活性炭纸纳米孔作为乙烯吸附剂的性能进行了评价。活性炭纳米孔处理使非木纸的克重增加,但使纸的抗折强度和抗折强度降低。通过混合法掺入纳米孔活性炭,使活性炭颗粒均匀地分布在纸的纸浆纤维内。吸附量最大的活性炭纸为竹材+ kmno4 +混合,吸附量为1348 ppm,乙烯用量为88.58%。25分钟达到浓度平衡。非线性伪一阶吸附动力学模型是描述纳米孔活性炭纸吸附乙烯平衡容量的合适模型,方程为:qt =1.35734(1−exp−0.15312 t) \ mathm {qt}=1.35734\hspace{0.1667em}(1-{\exp ^{-0.15312\hspace{0.1667em}\ mathm {t}}}), r2 =0.9981 {\ mathm {R}^{2}}=0.9981。
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来源期刊
Nordic Pulp & Paper Research Journal
Nordic Pulp & Paper Research Journal 工程技术-材料科学:纸与木材
CiteScore
2.50
自引率
16.70%
发文量
62
审稿时长
1 months
期刊介绍: Nordic Pulp & Paper Research Journal (NPPRJ) is a peer-reviewed, international scientific journal covering to-date science and technology research in the areas of wood-based biomass: Pulp and paper: products and processes Wood constituents: characterization and nanotechnologies Bio-refining, recovery and energy issues Utilization of side-streams from pulping processes Novel fibre-based, sustainable and smart materials. The editors and the publisher are committed to high quality standards and rapid handling of the peer review and publication processes. Topics Cutting-edge topics such as, but not limited to, the following: Biorefining, energy issues Wood fibre characterization and nanotechnology Side-streams and new products from wood pulping processes Mechanical pulping Chemical pulping, recovery and bleaching Paper technology Paper chemistry and physics Coating Paper-ink-interactions Recycling Environmental issues.
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