Towards Extraordinary Catalysts for Aromatization of Biomass and Low-Cost C5 Streams

IF 2.1 4区化学 Q3 CHEMISTRY, PHYSICAL Catalysis Surveys from Asia Pub Date : 2022-07-20 DOI:10.1007/s10563-022-09364-w

Ahmad Galadima, Ahmad Masudi, Oki Muraza

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引用次数: 3

Abstract

The production of aromatics with fuel properties from either biomass resources or low-cost refinery streams such as C5 is an important industrial interest. However, the strategic design of reliable catalysts with commercial compatibilities remained a challenge. Several investigations were carried out in this direction. This review accordingly presents a comprehensive analysis of the literature on the catalysis-based strategies adopted for aromatization of the feeds. Valorization of furans and allied oxygenates derived from biomass into aromatics was initially covered. The review examined strategies for C5 streams aromatization, co-upgrading of furans with hydrocarbons and methanol and discussed how biomass-derived bio-oils could be valorized into aromatics. In addition to discussion on the influence of catalytic textural, acidity and topological properties, the paper provided substantial updates on the associated reaction mechanisms. A perspective for further investigations in aromatization was also provided.

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面向生物质芳构化和低成本C5流的特殊催化剂

从生物质资源或低成本的炼油流(如C5)中生产具有燃料特性的芳烃是一个重要的工业兴趣。然而，具有商业相容性的可靠催化剂的战略设计仍然是一个挑战。在这方面进行了几项调查。这篇综述相应地提出了一个综合分析的文献上的催化为基础的策略采用的芳香化饲料。最初涵盖了从生物质中提取的呋喃和相关含氧化合物转化为芳烃的增值。综述了C5流芳构化、呋喃与烃类和甲醇共升级的策略，并讨论了生物质衍生生物油如何转化为芳烃。除了讨论了催化结构、酸度和拓扑性质的影响外，本文还对相关的反应机理进行了大量的更新。并对芳构化的进一步研究提出了展望。

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来源期刊

Catalysis Surveys from Asia 化学-物理化学

CiteScore

4.80

自引率

0.00%

发文量

审稿时长

>12 weeks

期刊介绍： Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.