Polypyrrole-coated electrospun polystyrene-Fe (III) composite fibres

Muaathe A. Ibraheem, Frederik J. Davis, N. Spencer, J. Mckendrick
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Abstract

Polypyrrole (Ppy) was synthesized via a chemical oxidization method with FeCl3.6H2O (FCHH) on electrospun polystyrene fibres ESPSF. The spinning process was achieved using Electrospinning for three solutions of polystyrene PS including 3, 5, and 9 % wt/v of FCHH in dimethyl formamide (DMF). The fibres diameters were monitored by scanning electron microscope SEM before and after coating, and it was found that the best results were achieved at low concentrations of FCHH. The Ppy coating was applied under four exposure periods (90, 150, 200, and 270 minutes) at 22C; Fibre diameter and coating quality are directly related in the study. The technique suggests a potential route towards producing conducting fibres with micro/nanoscale dimensions using Electrospinning followed by vapor chemical polymerization of pyrrole.
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聚吡咯涂层静电纺聚苯乙烯-铁(III)复合纤维
采用FeCl3.6H2O(FCHH)化学氧化法在静电纺丝聚苯乙烯纤维ESPSF上合成了聚吡咯(Ppy)。使用静电纺丝对聚苯乙烯PS的三种溶液(包括在二甲基甲酰胺(DMF)中的3%wt/v、5%wt/v和9%wt/v的FCHH)实现纺丝过程。在涂布前后通过扫描电子显微镜SEM监测纤维直径,发现在低浓度的FCHH下获得了最佳结果。在22C下,在四个暴露期(90、150、200和270分钟)下施加Ppy涂层;纤维直径与涂层质量直接相关。该技术为使用静电纺丝和吡咯的气相化学聚合生产微米/纳米尺寸的导电纤维提供了一条潜在的途径。
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来源期刊
CiteScore
0.50
自引率
0.00%
发文量
23
审稿时长
12 weeks
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