Leonardo Evaristo, Rafael Silveira, Matheus Tissot, Gisele Hippler, Benjamin Moulton, Silvio Buchner
{"title":"Effect of high pressure in barium disilicate glass investigated by DTA and Raman spectroscopy","authors":"Leonardo Evaristo, Rafael Silveira, Matheus Tissot, Gisele Hippler, Benjamin Moulton, Silvio Buchner","doi":"10.1111/ijag.16606","DOIUrl":null,"url":null,"abstract":"<p>This work aimed to explore the effect of high pressures at room temperature on the vibrational modes and the thermal properties and stability of barium disilicate glass (BaO-2SiO<sub>2</sub>) (BS2). The BS2 was prepared through the conventional melting route at atmospheric pressure. After being submitted to different pressure values (2.5 GPa, 4.0 GPa, and 7.7 GPa) and room temperature, the samples were characterized ex situ by Raman spectroscopy and differential thermal analysis. With this, it is possible to see that the pressure modifies the Raman vibrational modes of the glass, in the region associated with the Si-O-Si symmetrical bending modes. The Si-O symmetrical stretching vibrational modes (Q<sup>n</sup>) remain unchanged, however there are changes on values of glass transition and decrease crystallization temperature, as well as the parameters of thermal stability of the glass.</p>","PeriodicalId":13850,"journal":{"name":"International Journal of Applied Glass Science","volume":"14 2","pages":"240-246"},"PeriodicalIF":2.1000,"publicationDate":"2022-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Glass Science","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/ijag.16606","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 1
Abstract
This work aimed to explore the effect of high pressures at room temperature on the vibrational modes and the thermal properties and stability of barium disilicate glass (BaO-2SiO2) (BS2). The BS2 was prepared through the conventional melting route at atmospheric pressure. After being submitted to different pressure values (2.5 GPa, 4.0 GPa, and 7.7 GPa) and room temperature, the samples were characterized ex situ by Raman spectroscopy and differential thermal analysis. With this, it is possible to see that the pressure modifies the Raman vibrational modes of the glass, in the region associated with the Si-O-Si symmetrical bending modes. The Si-O symmetrical stretching vibrational modes (Qn) remain unchanged, however there are changes on values of glass transition and decrease crystallization temperature, as well as the parameters of thermal stability of the glass.
期刊介绍：
The International Journal of Applied Glass Science (IJAGS) endeavors to be an indispensable source of information dealing with the application of glass science and engineering across the entire materials spectrum. Through the solicitation, editing, and publishing of cutting-edge peer-reviewed papers, IJAGS will be a highly respected and enduring chronicle of major advances in applied glass science throughout this century. It will be of critical value to the work of scientists, engineers, educators, students, and organizations involved in the research, manufacture and utilization of the material glass. Guided by an International Advisory Board, IJAGS will focus on topical issue themes that broadly encompass the advanced description, application, modeling, manufacture, and experimental investigation of glass.
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