{"title":"A review on the chemistry of novel platinum chelates based on azo-azomethine ligands","authors":"Paritosh Mandal, J. L. Pratihar","doi":"10.1515/revic-2022-0027","DOIUrl":null,"url":null,"abstract":"Abstract Numerous platinum group metals (PGMs) complexes contain azo-azomethine-based ligands. Azo-azomethine ligands are N-donor ligands that have extended conjugated π-bonded systems and both azo (–N=N–) and aldimine (–C=N–) functions in their structure. Plenty of platinum (Pt) complexes with azo-imine ligands have been prepared and characterized. Various multidentate azo-imine ligands coordinated with different platinum metal substrates afforded structurally diverse platinum chelates. Nonetheless, many azo-imine-based platinum complexes demonstrated a wide range of biological activities, photo-switchable properties, and redox activities. The review encompasses a general overview of platinum complexes with versatile azo-azomethine ligands, their synthetic protocol, spectroscopic and structural features, chemical reactivity, and multipurpose applications in different areas.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":" ","pages":""},"PeriodicalIF":4.1000,"publicationDate":"2022-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reviews in Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/revic-2022-0027","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Abstract Numerous platinum group metals (PGMs) complexes contain azo-azomethine-based ligands. Azo-azomethine ligands are N-donor ligands that have extended conjugated π-bonded systems and both azo (–N=N–) and aldimine (–C=N–) functions in their structure. Plenty of platinum (Pt) complexes with azo-imine ligands have been prepared and characterized. Various multidentate azo-imine ligands coordinated with different platinum metal substrates afforded structurally diverse platinum chelates. Nonetheless, many azo-imine-based platinum complexes demonstrated a wide range of biological activities, photo-switchable properties, and redox activities. The review encompasses a general overview of platinum complexes with versatile azo-azomethine ligands, their synthetic protocol, spectroscopic and structural features, chemical reactivity, and multipurpose applications in different areas.
期刊介绍：
Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process.
Topics:
-Main group chemistry-
Transition metal chemistry-
Coordination chemistry-
Organometallic chemistry-
Catalysis-
Bioinorganic chemistry-
Supramolecular chemistry-
Ionic liquids
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