High-pressure Cr3+ R-line luminescence of zoisite and kyanite: a probe of octahedral site distortion

IF 1.2 4区 地球科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Physics and Chemistry of Minerals Pub Date : 2022-08-02 DOI:10.1007/s00269-022-01211-8
Earl F. O’Bannon III, Quentin Williams
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引用次数: 1

Abstract

The Cr3+ luminescence spectra of zoisite and kyanite, two geologically important minerals, were studied up to 40 and 20 GPa, respectively, in various pressure media. Cr3+ substitutes into the octahedral aluminum sites in both minerals and the R-line luminescence is a particularly sensitive site-specific probe of the octahedral Al site. Unlike many previous studies where Cr3+ luminescence was utilized, both these minerals have multiple highly distorted octahedral sites resulting in very large splitting of their R-lines, ~ 300 cm−1 in zoisite and ~ 360 cm−1 in kyanite (for reference, ruby is 29 cm−1). For zoisite, the R-line splitting increases as pressure increases and more than triples from its ambient value by 40 GPa, while the R-line splitting in kyanite from the M1 and M2 sites does not change when compressed in a Ne pressure medium up to 20 GPa. We do not observe evidence of any phase transitions in either zoisite or kyanite across the pressure range of these new luminescence measurements. We present some high-pressure luminescence results where kyanite was known to be bridged between the diamond anvils and show how these spectra illustrate the different effect of uniaxial relative to hydrostatic stress on luminescence spectra.

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黝帘石和蓝晶石的高压Cr3+ r线发光:八面体位畸变的探测
研究了具有重要地质意义的黝帘石和蓝晶石在40 GPa和20 GPa压力下的Cr3+发光光谱。在这两种矿物中,Cr3+取代了八面体铝的位置,而r线发光是一种特别敏感的八面体铝位置特异性探针。与之前许多利用Cr3+发光的研究不同,这两种矿物都有多个高度扭曲的八面体位点,导致它们的r线分裂非常大,在黝帘石中~ 300 cm−1,在蓝晶石中~ 360 cm−1(作为参考,红宝石为29 cm−1)。对于黝帘石,r -线分裂随着压力的增加而增加,比其环境值增加了40 GPa以上,而蓝晶石中M1和M2位点的r -线分裂在Ne压力介质中压缩到20 GPa时没有变化。在这些新的发光测量的压力范围内,我们没有观察到任何黝帘石或蓝晶石相变的证据。我们提出了一些高压发光结果,其中蓝晶石已知是桥接在金刚石砧之间,并展示了这些光谱如何说明单轴相对于静水应力对发光光谱的不同影响。
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来源期刊
Physics and Chemistry of Minerals
Physics and Chemistry of Minerals 地学-材料科学:综合
CiteScore
2.90
自引率
14.30%
发文量
43
审稿时长
3 months
期刊介绍: Physics and Chemistry of Minerals is an international journal devoted to publishing articles and short communications of physical or chemical studies on minerals or solids related to minerals. The aim of the journal is to support competent interdisciplinary work in mineralogy and physics or chemistry. Particular emphasis is placed on applications of modern techniques or new theories and models to interpret atomic structures and physical or chemical properties of minerals. Some subjects of interest are: -Relationships between atomic structure and crystalline state (structures of various states, crystal energies, crystal growth, thermodynamic studies, phase transformations, solid solution, exsolution phenomena, etc.) -General solid state spectroscopy (ultraviolet, visible, infrared, Raman, ESCA, luminescence, X-ray, electron paramagnetic resonance, nuclear magnetic resonance, gamma ray resonance, etc.) -Experimental and theoretical analysis of chemical bonding in minerals (application of crystal field, molecular orbital, band theories, etc.) -Physical properties (magnetic, mechanical, electric, optical, thermodynamic, etc.) -Relations between thermal expansion, compressibility, elastic constants, and fundamental properties of atomic structure, particularly as applied to geophysical problems -Electron microscopy in support of physical and chemical studies -Computational methods in the study of the structure and properties of minerals -Mineral surfaces (experimental methods, structure and properties)
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