Shape and Satellite Studies of Highly Charged Ions X-ray Spectra Using Bayesian Methods

IF 1.7 Q3 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL Atoms Pub Date : 2023-04-01 DOI:10.3390/atoms11040064
M. Trassinelli
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引用次数: 0

Abstract

High-accuracy spectroscopy commonly requires dedicated investigation into the choice of spectral line modelling to avoid the introduction of unwanted systematic errors. For such a kind of problem, the analysis of χ2 and likelihood are normally implemented to choose among models. However, these standard practices are affected by several problems and, in the first place, they are useless if there is no clear indication in favour of a specific model. Such issues are solved by Bayesian statistics, in the context of which a probability can be assigned to different hypotheses, i.e., models, from the analysis of the same set of data. Model probabilities are obtained from the integration of the likelihood function over the model parameter space with the evaluation of the so-called Bayesian evidence. Here, some practical applications are presented within the context of the analysis of recent high-accuracy X-ray spectroscopy data of highly charged uranium ion transitions. The method to determine the most plausible profile is discussed in detail. The study of the possible presence of satellite peaks is also presented.
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用贝叶斯方法研究高电荷离子x射线光谱的形状和卫星
高精度光谱学通常需要对谱线建模的选择进行专门的研究,以避免引入不必要的系统误差。对于这类问题,通常执行χ2和似然的分析来在模型之间进行选择。然而,这些标准做法受到几个问题的影响,首先,如果没有明确的迹象支持某一特定模式,它们就毫无用处。这些问题通过贝叶斯统计来解决,在贝叶斯统计的背景下,可以根据对同一组数据的分析将概率分配给不同的假设,即模型。模型概率是通过对模型参数空间上的似然函数与所谓贝叶斯证据的评估进行积分而获得的。在这里,在分析最近高电荷铀离子跃迁的高精度X射线光谱数据的背景下,介绍了一些实际应用。详细讨论了确定最合理剖面的方法。还介绍了卫星峰值可能存在的研究。
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来源期刊
Atoms
Atoms Physics and Astronomy-Nuclear and High Energy Physics
CiteScore
2.70
自引率
22.20%
发文量
128
审稿时长
8 weeks
期刊介绍: Atoms (ISSN 2218-2004) is an international and cross-disciplinary scholarly journal of scientific studies related to all aspects of the atom. It publishes reviews, regular research papers, and communications; there is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental and/or methodical details must be provided for research articles. There are, in addition, unique features of this journal: -manuscripts regarding research proposals and research ideas will be particularly welcomed. -computed data, program listings, and files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Scopes: -experimental and theoretical atomic, molecular, and nuclear physics, chemical physics -the study of atoms, molecules, nuclei and their interactions and constituents (protons, neutrons, and electrons) -quantum theory, applications and foundations -microparticles, clusters -exotic systems (muons, quarks, anti-matter) -atomic, molecular, and nuclear spectroscopy and collisions -nuclear energy (fusion and fission), radioactive decay -nuclear magnetic resonance (NMR) and electron spin resonance (ESR), hyperfine interactions -orbitals, valence and bonding behavior -atomic and molecular properties (energy levels, radiative properties, magnetic moments, collisional data) and photon interactions
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