Recent advances in electrochemical nitrate removal technology in water

Q4 Chemistry 中国科学(化学) Pub Date : 2023-07-01 DOI:10.1360/ssc-2023-0081
Jianjun Zhou, Fanrong Pan, Yunqing Zhu, Chuanyi Wang, Jincai Zhao
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Abstract

: Nitrate pollution has become a key environmental concern in China and World. The accumulation of nitrate in the water environment poses a great danger to human health, and it is important to develop technologies for efficient nitrate removal from water. Electrochemical nitrate reduction technology has outstanding advantages and wide application prospects because of its ability to selectively convert nitrate to N 2 and thus reduce the total nitrogen concentration in water. During the electrochemical nitrate reduction reaction, the catalytic performance of catalysts determines the reaction rate and product selectivity, and the design and development of efficient catalysts are key in the field of nitrate reduction and are developing rapidly, but there is still a lack of review reports on the design and synthesis strategies of novel catalysts. In this paper, the latest research progress of electrocatalytic nitrate reduction catalysts and high-performance reaction systems are summarized, and the mechanism of electrocatalytic nitrate reduction and the synthesis strategy of high efficiency electrocatalysts are discussed with the latest research examples. Furthermore, the design of electrochemical denitrification systems is discussed in terms of the selection of cathode materials, the synergistic electrocatalytic reaction of cathodes and anodes, and the design of reactors, aiming to promote the nitrate electroreduction technology from ″laboratory″ to ″practical application″. Finally, the future direction and research focus of electrochemical nitrate removal from water bodies are discussed from the perspective of engineering practice.
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电化学去除水中硝酸盐技术的最新进展
硝酸盐污染已成为中国乃至世界关注的重要环境问题。水环境中硝酸盐的积累严重危害人类健康,开发高效去除水中硝酸盐的技术具有重要意义。电化学硝酸还原技术能够选择性地将硝酸盐转化为n2,从而降低水中总氮浓度,具有突出的优势和广阔的应用前景。在硝酸电化学还原反应中,催化剂的催化性能决定了反应速率和产物选择性,高效催化剂的设计与开发是硝酸还原领域的关键,发展迅速,但目前还缺乏新型催化剂的设计与合成策略的综述报道。本文综述了电催化硝酸还原催化剂和高性能反应体系的最新研究进展,并结合最新研究实例探讨了电催化硝酸还原的机理和高效电催化剂的合成策略。并从正极材料的选择、正极与负极协同电催化反应、反应器的设计等方面对电化学脱氮系统的设计进行了探讨,旨在将硝酸盐电还原技术从″实验室″推进到″实际应用″。最后,从工程实践的角度探讨了电化学去除水体硝酸盐的未来发展方向和研究重点。
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来源期刊
中国科学(化学)
中国科学(化学) Materials Science-Materials Chemistry
CiteScore
1.20
自引率
0.00%
发文量
6112
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