Extraction and physicochemical characterization of cashew nut-shell liquid in metal forming

O. Sekunowo, G. U. Uduh
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Abstract

ABSTRACT: Effective lubrication during metal working is critical to mitigating undesirable tool wear and poor surface finish of formed components. This paper investigated the physicochemical characteristics of cashew nut-shell-liquid (CNSL) with a view of determining its suitability for the development of an eco-friendly lubricant used in metal forming. The cashew nut shell oil (CNSO) was extracted by soxhlet method and characterised to determine its physicochemical properties including density, free fatty acid (FFA), and viscosity. In addition, the saponification value, iodine value, pH, flash point and friction coefficient were determined using relevant analytical tools. The results showed that CNSL yield from soxhlet solvent extraction is 45.6%, which is adjudged to be relatively substantial with regard to other extraction processes. Furthermore, the CNSL exhibited critical lubrication characteristics in terms of density (0.94 g/cm3), moisture content (3.96%), acid value (11.32 mg.KOH/g), FFA (3.7%), ester value (127.92 mg.KOH/g), saponification value (139.24 mg.KOH/g), pH value (4.61), iodine value (40.21 gI2/100 g), viscosity at 100 oC (14.12 Pa.s), friction coefficient (0.001) and flash point of 286.63 oC. Given these outcomes in comparison with commercial Chevron soluble oil, it is concluded that CNSL is suitable for use as a viable metal forming lubrication fluid.
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金属成型腰果果壳液的提取及理化性质研究
摘要:金属加工过程中有效的润滑是减少刀具磨损和成形零件表面光洁度差的关键。本文研究了腰果壳液体(CNSL)的物理化学特性,以确定其是否适合开发用于金属成形的环保型润滑剂。采用索氏法提取腰果壳油(CNSO),测定其理化性质,包括密度、游离脂肪酸(FFA)和粘度。利用相关分析工具测定了皂化值、碘值、pH、闪点和摩擦系数。结果表明,索氏溶剂萃取的CNSL得率为45.6%,相对于其他提取工艺而言是比较可观的。此外,CNSL在密度(0.94 g/cm3)、含水量(3.96%)、酸值(11.32 mg.KOH/g)、FFA(3.7%)、酯值(127.92 mg.KOH/g)、酯化值(139.24 mg.KOH/g)、pH值(4.61)、碘值(40.21 gI2/100 g)、100℃粘度(14.12 Pa.s)、摩擦系数(0.001)和闪点(286.63 oC)等方面均表现出临界润滑特性。将这些结果与商业雪佛龙可溶性油进行比较,得出CNSL适合作为可行的金属成型润滑液的结论。
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来源期刊
Nigerian Journal of Technological Development
Nigerian Journal of Technological Development Engineering-Engineering (miscellaneous)
CiteScore
1.00
自引率
0.00%
发文量
40
审稿时长
24 weeks
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