Tarannum Jahan, Brijesh Lekhak, A. K. Verma, A. Dubey, T. Bhattacharya
{"title":"Preparation of phenol-formaldehyde resin modified with phenol-rich pine needle pyrolysis oil and assessment of bonding strength","authors":"Tarannum Jahan, Brijesh Lekhak, A. K. Verma, A. Dubey, T. Bhattacharya","doi":"10.1080/20426445.2022.2061254","DOIUrl":null,"url":null,"abstract":"ABSTRACT The pine needles bio-oil was partially replaced with phenol-formaldehyde (PF) resin at a rate of up to 40% by weight. The wood adhesive characteristics of a newly produced bio-oil phenol-formaldehyde (BOPF) resin with 10% bio-oil replacements was found to be comparable to those of pure PF resin with similar shear strength. DSC revealed that the curing temperature of 20 wt-% BOPF resin decreased from 95 to 60°C. Thermal degradation of BOPF resins was somewhat lower than that of pure PF resin, according to TGA and DTG data, and was similar in 10 and 20 wt-% BOPF resins. The presence of methylene bridges between phenols shown by FTIR analysis indicated that the wood adhesive had a good quality. According to SEM examination, the 10 and 20% BOPF resins showed a flat microstructure comparable to the pure PF resin.","PeriodicalId":14414,"journal":{"name":"International Wood Products Journal","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2022-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Wood Products Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/20426445.2022.2061254","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, PAPER & WOOD","Score":null,"Total":0}
引用次数: 1
Abstract
ABSTRACT The pine needles bio-oil was partially replaced with phenol-formaldehyde (PF) resin at a rate of up to 40% by weight. The wood adhesive characteristics of a newly produced bio-oil phenol-formaldehyde (BOPF) resin with 10% bio-oil replacements was found to be comparable to those of pure PF resin with similar shear strength. DSC revealed that the curing temperature of 20 wt-% BOPF resin decreased from 95 to 60°C. Thermal degradation of BOPF resins was somewhat lower than that of pure PF resin, according to TGA and DTG data, and was similar in 10 and 20 wt-% BOPF resins. The presence of methylene bridges between phenols shown by FTIR analysis indicated that the wood adhesive had a good quality. According to SEM examination, the 10 and 20% BOPF resins showed a flat microstructure comparable to the pure PF resin.
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