Development of Reaction Kinetics Model for the Production of Synthesis Gas from Dry Methane Reforming

A. Inayat, M.F.A Ahmad, M. Raza, C. Ghenai, S. Naqvi, M. Ayoub
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Abstract

The energy supply systems dependent on fossils and municipal solid waste (MSW) materials are primarily responsible for releasing greenhouse (GHG) gases and their related environmental hazards. The increasing amount of methane (CH4) and carbon dioxide (CO2) is the scientific community's main concern in this context. Reduction in the emission amount of both gases combined with the conversion technologies that would convert these total threat gases (CO2 and CH4) into valuable feedstocks will significantly lower their hazardous impact on climate change. The conversion technique known as dry methane reforming (DMR) utilizes CO2 and CH4 to produce a combustible gas mixture (CO+H2), popularly known as synthesis gas/or syngas. Therefore, this research study aims to explore and enlighten the characteristics of the DMR mechanism. The conversion behaviour of CO2 and CH4 was studied with modelling and simulation of the DMR process using MATLAB. The results showed that inlet gas flow has a significant impact on the reactions. In contrast, the inlet molar composition ratio of the reactions was found to have no substantial effect on the mechanism of DMR. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
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干甲烷重整制合成气反应动力学模型的建立
依赖化石和城市固体废物(MSW)材料的能源供应系统主要负责释放温室气体及其相关环境危害。甲烷(CH4)和二氧化碳(CO2)的数量不断增加是科学界在这方面的主要关注点。减少这两种气体的排放量,再加上将这些总威胁气体(CO2和CH4)转化为有价值原料的转化技术,将大大降低其对气候变化的危险影响。被称为干甲烷重整(DMR)的转化技术利用CO2和CH4产生可燃气体混合物(CO+H2),通常被称为合成气/或合成气。因此,本研究旨在探索和启发DMR机制的特点。利用MATLAB对DMR过程进行建模和模拟,研究了CO2和CH4的转化行为。结果表明,进气流量对反应有显著影响。相反,发现反应的入口摩尔组成比对DMR的机理没有实质性影响。版权所有©2021作者所有,BCREC集团出版。这是CC BY-SA许可证下的开放访问文章(https://creativecommons.org/licenses/by-sa/4.0)。
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来源期刊
CiteScore
3.20
自引率
6.70%
发文量
52
审稿时长
12 weeks
期刊介绍: Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in chemical reaction engineering, catalysis science and engineering, catalyst preparation method and characterization, novel innovation of chemical reactor, kinetic studies, etc. are particularly welcome. However, articles concerned on general chemical engineering process are not covered and out of scope of this journal
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