S. Yu. Lyrshchikov, P. A. Strizhak, S. A. Shevyrev
{"title":"Thermal decomposition of coal and coal-enrichment wastes","authors":"S. Yu. Lyrshchikov, P. A. Strizhak, S. A. Shevyrev","doi":"10.3103/S1068364X16070048","DOIUrl":null,"url":null,"abstract":"<p>The thermokinetic parameters of the thermal decomposition of coal and its processing wastes (filter cake) used in the preparation of coal–water and organic coal–water fuels are determined experimentally by thermogravimetry in an inert atmosphere. The dependence of the thermokinetic parameters of decomposition on the coal’s metamorphic stage is established; the activation energy of decomposition varies from 39.1 kJ/mol (lignite) to 109.4 kJ/mol (anthracite). There is practically no difference between coal and its processing wastes in the thermokinetic parameters of thermal decomposition. The results provide the starting point for an experimental database that may be used in modeling the ignition and combustion of coal and its derivatives: coal–water and organic coal–water fuels.</p>","PeriodicalId":519,"journal":{"name":"Coke and Chemistry","volume":"59 7","pages":"264 - 270"},"PeriodicalIF":0.4000,"publicationDate":"2016-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.3103/S1068364X16070048","citationCount":"9","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coke and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S1068364X16070048","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 9
Abstract
The thermokinetic parameters of the thermal decomposition of coal and its processing wastes (filter cake) used in the preparation of coal–water and organic coal–water fuels are determined experimentally by thermogravimetry in an inert atmosphere. The dependence of the thermokinetic parameters of decomposition on the coal’s metamorphic stage is established; the activation energy of decomposition varies from 39.1 kJ/mol (lignite) to 109.4 kJ/mol (anthracite). There is practically no difference between coal and its processing wastes in the thermokinetic parameters of thermal decomposition. The results provide the starting point for an experimental database that may be used in modeling the ignition and combustion of coal and its derivatives: coal–water and organic coal–water fuels.
期刊介绍:
The journal publishes scientific developments and applications in the field of coal beneficiation and preparation for coking, coking processes, design of coking ovens and equipment, by-product recovery, automation of technological processes, ecology and economics. It also presents indispensable information on the scientific events devoted to thermal rectification, use of smokeless coal as an energy source, and manufacture of different liquid and solid chemical products.