Voltammetric Determination of Dopamine in the Presence of Caffeine Using a Modified Glassy Carbon Electrode

Maryam Ebrahimi,  Hadi Beitollahi
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Abstract

In this work, an electrochemical sensor based on CuO nanoflowers modified glassy carbon electrode (GCE) was developed for the voltammetric determination of dopamine. The CuO nanoflowers modified GCE showed good catalytic ability for the determination of dopamine. The differential pulse voltammetry investigation showed a linear relation between the dopamine current and its concentration within the range of 0.1–800.0 μM, with a limit of detection of 0.03 ± 0.001 μM. Also, the modified electrode was used for the simultaneous determination of dopamine and caffeine. Both dopamine and caffeine exhibited non-overlapping voltammetric peaks at 235 and 1390 mV, respectively, using CuO nanoflowers/GCE. Finally, the analytical performance of the developed sensor was evaluated for the analysis of dopamine and caffeine in real samples, which showed satisfactory results.

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修饰玻碳电极在咖啡因存在下伏安法测定多巴胺
摘要——本工作开发了一种基于CuO纳米花修饰玻碳电极(GCE)的电化学传感器,用于多巴胺的伏安测定。CuO纳米花修饰GCE对多巴胺的测定显示出良好的催化能力。微分脉冲伏安法研究表明,多巴胺电流与其浓度在0.1–800.0μM范围内呈线性关系,检测限为0.03±0.001μM。同时,将修饰电极用于多巴胺和咖啡因的同时测定。使用CuO纳米花/GCE,多巴胺和咖啡因分别在235和1390 mV处显示出不重叠的伏安峰。最后,对所开发的传感器的分析性能进行了评估,用于真实样品中多巴胺和咖啡因的分析,结果令人满意。
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来源期刊
Surface Engineering and Applied Electrochemistry
Surface Engineering and Applied Electrochemistry Engineering-Industrial and Manufacturing Engineering
CiteScore
1.60
自引率
22.20%
发文量
54
期刊介绍: Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.
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