Menthol-Based (Deep) Eutectic Solvents: A Review on Properties and Application in Extraction

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chemical record Pub Date : 2023-10-20 DOI:10.1002/tcr.202300267

Marharyta Cherniakova, Dr. Victoria Varchenko, Dr. Konstantin Belikov

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Abstract

In the last 10 years the interest in deep eutectic solvents (DESs) as a new class of green solvents has considerably increased. The emergence of numerous of hydrophobic DESs has stimulated intensive research into their application in extraction technologies, including sample preparation. As the properties of such systems are highly dependent on the properties of their components (hydrogen bond donors and acceptors) and can be finely tuned, DESs can be successfully used for the extraction of both metal ions and organic substances, including biomolecules. Despite the rapidly increasing number of publications on the use of DESs as an extraction medium, including review articles, information on the extraction properties of DESs in terms of their chemical composition has not yet been summarized. This review covers available literature data on the physicochemical properties of menthol-based eutectic solvents and the results of their practical application as an extraction medium. Also, the appropriateness of using the term “DES” for all mixtures with melting points lower than the melting points of their components is discussed.

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薄荷醇基（深层）共晶溶剂：性质及其在萃取中的应用综述。

在最近10 多年来，人们对深共晶溶剂（DESs）作为一类新的绿色溶剂的兴趣大大增加。大量疏水性DESs的出现促使人们深入研究其在提取技术中的应用，包括样品制备。由于这种系统的性质高度依赖于其组分（氢键供体和受体）的性质，并且可以进行微调，因此DESs可以成功地用于提取金属离子和有机物质，包括生物分子。尽管关于使用DESs作为提取介质的出版物（包括综述文章）数量迅速增加，但关于DESs的化学成分提取特性的信息尚未汇总。本文综述了薄荷醇基共晶溶剂的物理化学性质及其作为提取介质的实际应用结果。此外，还讨论了将“DES”一词用于熔点低于其组分熔点的所有混合物的适当性。

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来源期刊

Chemical record 化学-化学综合

CiteScore

11.00

自引率

3.00%

发文量

188

审稿时长

>12 weeks

期刊介绍： The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.