Effects of various additives on the crumb rubber integrated geopolymer concrete

Abstract

The use of scrap tyres in construction materials has been promoted to curb the environmental exploitation caused by the open disposal of non-biodegradable waste rubber. Tyre grinds as aggregates in geopolymer concrete (GPC) would increase its sustainability value by reducing the consumption of natural aggregates. Although there is limited literature addressing the damage to GPC characteristics caused by rubber aggregates, this investigation was designed to determine the extent of possible side effects of using crumb rubber (CR) in GPC. Additionally, this investigation aims to address any resulting reduction in strength and durability using additives such as cement and fibres. Geopolymer specimens with CR replacement of fine aggregates by volume (0, 5, 10 and 15%) showed a compressive strength reduction of up to 17% when tested according to ASTM standards. Substituting the total binder by weight with Ordinary Portland cement (OPC) (0%, 5%, 10%, 15%, and 20%) improved the microstructural integrity of the rubberised geopolymer mix with the highest percentage of OPC. Despite producing new and additional binding products (CSH and CASH gels), the GPC surface readily disintegrated under acid exposure. Optimum glass fibres (GF) reinforcement (0.30%) effectively disrupted the GPC pore network, consequently reducing the acid permeability of the matrix. Further addition of steel fibres (SF) enhanced the GPC specimen's compressive and flexural strength. To analyse the cumulative effect of these additives on GPC microstructure, supporting tests such as scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy were carried out. Although these additives enhanced the overall performance of rubberised geopolymer, it might somewhat reduce its green aspect.