An investigation on the use algae-based material for the production of reusable bioplastic bags: A Mauritian case study

M.Y.Z.K. Kadell, D.S. Callychurn
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Abstract

The Government of Mauritius has come up with new regulations in an attempt to ban the use of petroleum based plastics bags so as to protect the environment. Hence it is important to find substitute materials to achieve this goal set by the government. Interestingly though, Mauritius being an island with a large Exclusive Economic Zone (EEZ), there is an abundancy of seaweeds, which is an interesting avenue to explore. The unexploited seaweed in the waters surrounding Mauritius remains a remarkably potential raw material for the manufacture of an alternative to petro-plastics, especially polypropylene non-woven bags, in the form of reusable and fully biodegradable bioplastic bags. This research attempts to investigate the use of algae, mainly Gracilaria Salicornia and Ulva lactuca as a potential; raw material for the production of reusable bioplastic bags through Taguchi optimisation method for the culling of optimum constituent wt.%. For the preparation of the biofilm to be solution casted, cassava starch, algae powder, glycerol and acetic acid were selected as controllable factors. The Taguchi L9 orthogonal array experimental design plan was considered for carrying out the experiments. The responses analysed were the tensile strength, water absorption, biodegradation and water vapour permeability. A maximum tensile strength and degradation of 7.325 MPa and 91.32% respectively were achieved from Taguchi optimal conditions. A maximum water absorption and minimum water vapour permeability of 60.3 % and 3.0181 g/h.m2 respectively were evaluated from the experiments. Contribution of factors to the responses were determined through analysis of variance. Furthermore, regression models and contour plots were developed for predicting the best combination which was determined to be 8 % (w/v) starch, 3 % (w/v) algae, 1 % (w/v) glycerol and 8 % (w/v) acetic. An Ulva lactuca blend was experimented to act as substitute for cassava starch, achieving a tensile strength and water absorption of 3.578 MPa and 175.0 % respectively. Compared to other materials, used for bag production, available on the market, the mechanical properties of the developed algae-based material showed its potential as a replacement with some having much higher tensile strength confirming its successful usage.

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关于使用藻类材料生产可重复使用的生物塑料袋的调查:毛里求斯的案例研究
毛里求斯政府制定了新的法规,试图禁止使用石油塑料袋,以保护环境。因此,寻找替代材料来实现政府设定的目标是很重要的。然而,有趣的是,毛里求斯是一个拥有大型专属经济区(EEZ)的岛屿,那里有丰富的海藻,这是一条有趣的探索之路。毛里求斯周围水域中未开发的海藻仍然是制造石油塑料替代品的一种非常有潜力的原材料,尤其是聚丙烯无纺袋,其形式是可重复使用和完全可生物降解的生物塑料袋。本研究试图探讨藻类的利用,主要是以龙须菜和羊茅为潜力;通过田口优化法筛选最佳成分wt.%生产可重复使用的生物塑料袋的原料。对于待溶液浇铸的生物膜的制备,选择木薯淀粉、藻类粉末、甘油和乙酸作为可控因素。实验采用田口L9正交阵列实验设计方案。分析的响应包括抗拉强度、吸水性、生物降解性和水蒸气渗透性。田口优化条件下的最大抗拉强度和降解率分别为7.325MPa和91.32%。从实验中评估出最大吸水率和最小水蒸气渗透率分别为60.3%和3.0181 g/h.m2。通过方差分析确定各因素对反应的贡献。此外,还开发了回归模型和等高线图来预测最佳组合,该组合被确定为8%(w/v)淀粉、3%(w/v)藻类、1%(w/v。试验用Ulva-lactuca共混物代替木薯淀粉,拉伸强度和吸水率分别达到3.578MPa和175.0%。与市场上用于袋生产的其他材料相比,开发的藻类基材料的机械性能显示出其作为替代品的潜力,其中一些材料具有高得多的抗拉强度,证实了其成功使用。
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