Formic acid as renewable reagent and product in biomass upgrading

Mahdi Achour , Débora Álvarez-Hernández , Estela Ruiz-López , Cristina Megías-Sayago , Fatima Ammari , Svetlana Ivanova , Miguel Ángel Centeno
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Abstract

The problems associated with the use of molecular hydrogen (transportation, storage and high cost) have pushed scientists to the pursuit of efficient hydrogen donors, able to reduce chemical bonds in the presence of catalysts through catalytic transfer hydrogenation (CTH) reactions. In this sense, formic acid stands up as one of the most important and safest chemical molecules for H2 generation under mild conditions. It can be obtained from biomass through different catalytic transformations and used as well to upgrade biomass to platform chemicals. This review summarizes the recently published studies dealing with formic acid production from biomass (using glucose as representing molecule) along with its use in hydrogen involved reactions of different groups of platform chemicals upgrading.

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甲酸作为生物质改性中的可再生试剂和产品
与分子氢的使用相关的问题(运输、储存和高成本)促使科学家追求高效的氢供体,能够在催化剂存在的情况下通过催化转移氢化(CTH)反应减少化学键。从这个意义上说,甲酸是在温和条件下产生H2最重要、最安全的化学分子之一。它可以通过不同的催化转化从生物质中获得,也可以用于将生物质升级为平台化学品。这篇综述总结了最近发表的关于生物质(使用葡萄糖作为代表分子)生产甲酸的研究,以及它在不同平台化学品升级的氢相关反应中的应用。
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