Jiaqi Tao , Linling Xu , Haoshan Jin , Yansong Gu , Jintang Zhou , Zhengjun Yao , Xuewei Tao , Ping Chen , Dinghui Wang , Zhong Li , Hongjing Wu
{"title":"Selective coding dielectric genes based on proton tailoring to improve microwave absorption of MOFs","authors":"Jiaqi Tao , Linling Xu , Haoshan Jin , Yansong Gu , Jintang Zhou , Zhengjun Yao , Xuewei Tao , Ping Chen , Dinghui Wang , Zhong Li , Hongjing Wu","doi":"10.1016/j.apmate.2022.100091","DOIUrl":null,"url":null,"abstract":"<div><p>Regulating dielectric genes of hollow metal-organic frameworks is a milestone project for microwave absorption (MA). However, there is still a bottleneck in deciphering the contribution of various dielectric genes, making it hard to expand the MA potential from selective encoding gene sequences. Herein, a custom-made proton tailoring strategy is used to build a controllable cavity, and meticulously designed thermodynamic regulation promotes the rearrangement of carbon atoms from disorder to order, thus enhancing the characteristics of charge transfer. Meanwhile, the defect-configuration transformation from heteroatom to vacancy and geometric configuration of hollow structure increase the polarization-related dielectric genes. Therefore, MA performance is enhanced towards broadband absorption (6.6 GHz, 1.78 mm) and high-efficiency loss (−62.5 dB), making samples suitable for complex open electromagnetic environments. This work realizes the tradeoff between dielectric gene sequences and provides a profound insight into the functions and sources of various microwave loss mechanisms.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"38","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Powder Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772834X22000744","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 38
Abstract
Regulating dielectric genes of hollow metal-organic frameworks is a milestone project for microwave absorption (MA). However, there is still a bottleneck in deciphering the contribution of various dielectric genes, making it hard to expand the MA potential from selective encoding gene sequences. Herein, a custom-made proton tailoring strategy is used to build a controllable cavity, and meticulously designed thermodynamic regulation promotes the rearrangement of carbon atoms from disorder to order, thus enhancing the characteristics of charge transfer. Meanwhile, the defect-configuration transformation from heteroatom to vacancy and geometric configuration of hollow structure increase the polarization-related dielectric genes. Therefore, MA performance is enhanced towards broadband absorption (6.6 GHz, 1.78 mm) and high-efficiency loss (−62.5 dB), making samples suitable for complex open electromagnetic environments. This work realizes the tradeoff between dielectric gene sequences and provides a profound insight into the functions and sources of various microwave loss mechanisms.