Effect of boron on the microstructural evolution and wear resistance of high-hardness Fe-based alloy coatings prepared by laser cladding

IF 5.3 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS Surface & Coatings Technology Pub Date : 2023-04-15 DOI:10.1016/j.surfcoat.2023.129342
Qian Li , Ya Long Zhang , Liang Zhang , Qian Wang , Zhuo Zhao , Dong Xu Chen , Hui Jin , Yi Yong Wang , Jun Wei Zhang
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引用次数: 4

Abstract

One of the primary failure modes of 45 steel is severe surface wear, which significantly raises its application cost. In order to improve the wear resistance, high-hardness Fe-based alloy coatings with varying boron contents were prepared on 45 steel substrates by preplaced-powder laser cladding in this study. The effect of boron content on the phase composition and microstructural evolution of the coatings were systematically studied. The proportion, morphology, and distribution characteristics of boride phases in the coatings were discussed in detail. The results demonstrated that the Fe-based alloy coatings with different boron contents were composed of α-Fe, Cr7C3, and Fe2B phases. The boron content had a significant influence on the morphology and proportion of the boride phases. With the increase of boron content, the proportion of boride phases gradually increased and the morphology transition was reticular → cluster-shape → long strip-shape → plate-shape. The composition analysis revealed that the boride was Cr-rich Fe2B phase and the content of Cr in the borides increased with the boron content of the coating. The addition of boron could effectively improve the hardness and wear resistance of the Fe-based coatings, which could be attributed to the boride hard phases in the microstructures. The coating with 6.0 wt% B exhibited the highest microhardness and least amount of wear loss. The wear mechanism of the coating with different boron contents was also discussed.

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硼对激光熔覆高硬度铁基合金涂层组织演变和耐磨性的影响
45钢的主要失效模式之一是严重的表面磨损,这大大提高了其应用成本。为了提高耐磨性,本研究采用粉末激光熔覆技术在45钢基体上制备了不同硼含量的高硬度铁基合金涂层。系统地研究了硼含量对涂层相组成和微观结构演变的影响。详细讨论了涂层中硼化物相的比例、形态和分布特征。结果表明,不同硼含量的铁基合金镀层由α-Fe、Cr7C3和Fe2B相组成。硼含量对硼化物相的形态和比例有显著影响。随着硼含量的增加,硼化物相的比例逐渐增加,形态转变为网状→簇状→长条形→板状。成分分析表明,硼化物为富Cr的Fe2B相,硼化物中Cr的含量随着涂层中硼含量的增加而增加。硼的加入可以有效地提高铁基涂层的硬度和耐磨性,这可能归因于微观结构中的硼化物硬相。B含量为6.0wt%的涂层具有最高的显微硬度和最小的磨损量。讨论了不同硼含量涂层的磨损机理。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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