Attempts to oxidize sulfides under mechanochemical conditions: synthetic and stereochemical aspects

IF 1.4 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2023-01-01 DOI:10.1080/10426507.2023.2193405
Aneta Wróblewska , Kamil Bugaj , Jakub Łagiewka , Tomasz Girek , Jozsef Rabai , Józef Drabowicz
{"title":"Attempts to oxidize sulfides under mechanochemical conditions: synthetic and stereochemical aspects","authors":"Aneta Wróblewska ,&nbsp;Kamil Bugaj ,&nbsp;Jakub Łagiewka ,&nbsp;Tomasz Girek ,&nbsp;Jozsef Rabai ,&nbsp;Józef Drabowicz","doi":"10.1080/10426507.2023.2193405","DOIUrl":null,"url":null,"abstract":"<div><p>Preliminary experiments devoted to the reaction of model sulfides with several oxidation reagents under mechanochemical conditions are presented. No reaction with sodium metaperiodate and (−)-(8,8-dichlorocamphorylsulfonyl)oxaziridine was observed. An interesting selectivity was observed in the oxidation reaction of aryl trifluoromethyl sulfides with hydrogen peroxide in the presence of tungstic phosphoric acid as a catalyst. Asymmetric induction has been observed during the oxidation of methyl phenyl sulfide to the corresponding sulfoxide carried out in the presence of d-camphorsulfonic acid or beta-cyclodextrin.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"198 6","pages":"Pages 513-516"},"PeriodicalIF":1.4000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650723000394","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Preliminary experiments devoted to the reaction of model sulfides with several oxidation reagents under mechanochemical conditions are presented. No reaction with sodium metaperiodate and (−)-(8,8-dichlorocamphorylsulfonyl)oxaziridine was observed. An interesting selectivity was observed in the oxidation reaction of aryl trifluoromethyl sulfides with hydrogen peroxide in the presence of tungstic phosphoric acid as a catalyst. Asymmetric induction has been observed during the oxidation of methyl phenyl sulfide to the corresponding sulfoxide carried out in the presence of d-camphorsulfonic acid or beta-cyclodextrin.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
尝试在机械化学条件下氧化硫化物:合成和立体化学方面
介绍了在机械化学条件下模型硫化物与几种氧化试剂反应的初步实验。与偏碘酸钠和(−)-(8,8-二氯樟脑磺酰基)恶氮吡啶无反应。在钨磷酸的催化下,芳基三氟甲基硫化物与过氧化氢的氧化反应具有有趣的选择性。在d-樟脑磺酸或β -环糊精存在的情况下,甲基苯基硫化物被氧化为相应的亚砜时,观察到不对称诱导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
2.60
自引率
7.70%
发文量
103
审稿时长
2.1 months
期刊介绍: Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
期刊最新文献
Formation, functionalization and interconversion of sulfur containing functional groups in mechanochemical conditions A novel [4 + 2] cycloaddition reaction involving Lawesson’s reagent. Structure and specific fragmentations of a new cyclic 1,2-thiaphosphinane-4-one In situ formation of the electrophilic phenylselenenyl sulfate triggered by light A theoretical investigation of the competition between σ- and π-holes on the stability of the complexes resulting from the interaction between the COCl2 and OCY molecules (Y = S, Se, and Te) Topological characterization of PETAA and bismuth(III) iodide: Flair drug carriers and therapeutic agents
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1