Research progress on the synthesis and characterization of ammonia borane and metal nanocatalysts for hydrogen production the hydrolysis of ammonia borane
ZOU Ai-hua , LIN Lu-he , ZHOU Lang , KANG Zhi-bing , CAO Li-hua , HAN Qing-dong
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Abstract
Ammonia borane (AB) is considered to be a promising chemical hydrogen storage material with high hydrogen storage density (19.6%), which can release three molar equivalents of hydrogen through catalytic hydrolysis at room temperature. However, AB releases hydrogen slowly in water, it is necessary to develop highly active metal nanocatalysts to accelerate the process of hydrolysis. This article provides an overview of the synthesis and characterization methods of ammonia borane, the mechanism of hydrolysis and catalytic hydrogen production using the unique dihydrogen key in the ammonia borane structure, and the various factors that affect the hydrogen release performance of AB.
期刊介绍：
Journal of Fuel Chemistry and Technology (Ranliao Huaxue Xuebao) is a Chinese Academy of Sciences(CAS) journal started in 1956, sponsored by the Chinese Chemical Society and the Institute of Coal Chemistry, Chinese Academy of Sciences(CAS). The journal is published bimonthly by Science Press in China and widely distributed in about 20 countries. Journal of Fuel Chemistry and Technology publishes reports of both basic and applied research in the chemistry and chemical engineering of many energy sources, including that involved in the nature, processing and utilization of coal, petroleum, oil shale, natural gas, biomass and synfuels, as well as related subjects of increasing interest such as C1 chemistry, pollutions control and new catalytic materials. Types of publications include original research articles, short communications, research notes and reviews. Both domestic and international contributors are welcome. Manuscripts written in Chinese or English will be accepted. Additional English titles, abstracts and key words should be included in Chinese manuscripts. All manuscripts are subject to critical review by the editorial committee, which is composed of about 10 foreign and 50 Chinese experts in fuel science. Journal of Fuel Chemistry and Technology has been a source of primary research work in fuel chemistry as a Chinese core scientific periodical.
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