The conformational behavior and structure of monosubstituted 1,3,5-trisilacyclohexanes—Part III: 1-Methyl-1,3,5-trisilacyclohexane

IF 1.9 4区 化学 Q2 CHEMISTRY, ORGANIC Journal of Physical Organic Chemistry Pub Date : 2023-05-04 DOI:10.1002/poc.4514
Liubov E. Kuzmina, Sergey A. Shlykov, Ingvar Arnason, Nanna R. Jonsdottir
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Abstract

1-Methyl-1,3,5-trisilacyclohexane was synthesized and its structure and conformational properties have been determined by gas-phase electron diffraction (GED) and quantum chemical (QC) calculations. The molecule may exist in two forms differing from each other by the substituent's position. QC results show that the equatorial conformer is predicted to be slightly more stable than the axial conformer; note that one method (M06-2X) with basis set 6-311G** shows an equal amount of Ax and Eq conformers: ratio (Ax/Eq) = (30–50):(70–50)% (depending on the method and basis set). From the GED data, the molar fractions of the conformers were found to be Ax:Eq = 54(10):46(10) at 280(5) K. A temperature-dependent Raman experiment resulted in an Ax:Eq ratio of 58(4):42(4). Conformational properties are compared in series of analogous 1-X-1-(hetero)cyclohexanes.

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单取代1,3,5-三硅环己烷的构象行为和结构——第三部分:1-甲基-1,3,5-三硅环己烷
合成了1-甲基-1,3,5-三硅环己烷,并通过气相电子衍射(GED)和量子化学(QC)计算测定了其结构和构象。分子可以以两种形式存在,这两种形式因取代基的位置而彼此不同。QC结果表明,赤道构象预测比轴向构象略稳定;请注意,基集为6-311G**的一种方法(M06-2X)显示了相等数量的Ax和Eq一致性:比率(Ax/Eq) = (30-50):(70-50)%(取决于方法和基准集)。根据GED数据,发现构象异构体的摩尔分数为Ax:Eq = 54(10):46(10)在280(5)K下。依赖于温度的拉曼实验导致Ax:Eq比为58(4):42(4)。比较了一系列类似的1-X-1-(杂)环己烷的构象性质。
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来源期刊
CiteScore
3.60
自引率
11.10%
发文量
161
审稿时长
2.3 months
期刊介绍: The Journal of Physical Organic Chemistry is the foremost international journal devoted to the relationship between molecular structure and chemical reactivity in organic systems. It publishes Research Articles, Reviews and Mini Reviews based on research striving to understand the principles governing chemical structures in relation to activity and transformation with physical and mathematical rigor, using results derived from experimental and computational methods. Physical Organic Chemistry is a central and fundamental field with multiple applications in fields such as molecular recognition, supramolecular chemistry, catalysis, photochemistry, biological and material sciences, nanotechnology and surface science.
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