The conformational behavior and structure of monosubstituted 1,3,5-trisilacyclohexanes—Part III: 1-Methyl-1,3,5-trisilacyclohexane

IF 1.9 4区 化学 Q2 CHEMISTRY, ORGANIC Journal of Physical Organic Chemistry Pub Date : 2023-05-04 DOI:10.1002/poc.4514
Liubov E. Kuzmina, Sergey A. Shlykov, Ingvar Arnason, Nanna R. Jonsdottir
{"title":"The conformational behavior and structure of monosubstituted 1,3,5-trisilacyclohexanes—Part III: 1-Methyl-1,3,5-trisilacyclohexane","authors":"Liubov E. Kuzmina,&nbsp;Sergey A. Shlykov,&nbsp;Ingvar Arnason,&nbsp;Nanna R. Jonsdottir","doi":"10.1002/poc.4514","DOIUrl":null,"url":null,"abstract":"<p>1-Methyl-1,3,5-trisilacyclohexane was synthesized and its structure and conformational properties have been determined by gas-phase electron diffraction (GED) and quantum chemical (QC) calculations. The molecule may exist in two forms differing from each other by the substituent's position. QC results show that the equatorial conformer is predicted to be slightly more stable than the axial conformer; note that one method (M06-2X) with basis set 6-311G** shows an equal amount of Ax and Eq conformers: ratio (Ax/Eq) = (30–50):(70–50)% (depending on the method and basis set). From the GED data, the molar fractions of the conformers were found to be Ax:Eq = 54(10):46(10) at 280(5) K. A temperature-dependent Raman experiment resulted in an Ax:Eq ratio of 58(4):42(4). Conformational properties are compared in series of analogous 1-X-1-(hetero)cyclohexanes.</p>","PeriodicalId":16829,"journal":{"name":"Journal of Physical Organic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.9000,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Physical Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/poc.4514","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0

Abstract

1-Methyl-1,3,5-trisilacyclohexane was synthesized and its structure and conformational properties have been determined by gas-phase electron diffraction (GED) and quantum chemical (QC) calculations. The molecule may exist in two forms differing from each other by the substituent's position. QC results show that the equatorial conformer is predicted to be slightly more stable than the axial conformer; note that one method (M06-2X) with basis set 6-311G** shows an equal amount of Ax and Eq conformers: ratio (Ax/Eq) = (30–50):(70–50)% (depending on the method and basis set). From the GED data, the molar fractions of the conformers were found to be Ax:Eq = 54(10):46(10) at 280(5) K. A temperature-dependent Raman experiment resulted in an Ax:Eq ratio of 58(4):42(4). Conformational properties are compared in series of analogous 1-X-1-(hetero)cyclohexanes.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
单取代1,3,5-三硅环己烷的构象行为和结构——第三部分:1-甲基-1,3,5-三硅环己烷
合成了1-甲基-1,3,5-三硅环己烷,并通过气相电子衍射(GED)和量子化学(QC)计算测定了其结构和构象。分子可以以两种形式存在,这两种形式因取代基的位置而彼此不同。QC结果表明,赤道构象预测比轴向构象略稳定;请注意,基集为6-311G**的一种方法(M06-2X)显示了相等数量的Ax和Eq一致性:比率(Ax/Eq) = (30-50):(70-50)%(取决于方法和基准集)。根据GED数据,发现构象异构体的摩尔分数为Ax:Eq = 54(10):46(10)在280(5)K下。依赖于温度的拉曼实验导致Ax:Eq比为58(4):42(4)。比较了一系列类似的1-X-1-(杂)环己烷的构象性质。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
3.60
自引率
11.10%
发文量
161
审稿时长
2.3 months
期刊介绍: The Journal of Physical Organic Chemistry is the foremost international journal devoted to the relationship between molecular structure and chemical reactivity in organic systems. It publishes Research Articles, Reviews and Mini Reviews based on research striving to understand the principles governing chemical structures in relation to activity and transformation with physical and mathematical rigor, using results derived from experimental and computational methods. Physical Organic Chemistry is a central and fundamental field with multiple applications in fields such as molecular recognition, supramolecular chemistry, catalysis, photochemistry, biological and material sciences, nanotechnology and surface science.
期刊最新文献
Issue Information Cover Image Cover Image Issue Information Enhanced Hyperpolarizabilities Through p‐Phenylene Bridges: Computational Studies on Metamerism and Functional Molecular Properties of Pyridinium–Dicyanomethanide‐Based Zwitterions
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1