Adapting direct filtration to increasing source water dissolved organic carbon using clarification and granular activated carbon

Lindsay E. Anderson, Manda Tchonlla, Martin Earle, Ryan Swinamer, Graham A. Gagnon
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Abstract

Changing source water quality namely through increasing natural organic matter (NOM) concentration challenges surface water treatment, especially direct filtration. We conducted a pilot-scale assessment of various adaptation strategies (e.g., clarification, granular activated carbon [GAC] filtration) for direct filtration facilities under the stress of rising NOM levels. Recognizing that changing source water can impact broader aspects of treatment, we considered the implications of Fe and Mn removal via KMnO4 pre-oxidation. GAC media showed promise as an adaptation strategy, providing ~60% removal of dissolved organic carbon (DOC), and a significant reduction in disinfection by-product formation potential (DBPfp). However, KMnO4 pretreatment showed limited Mn and Fe removal, and filters with GAC media released dissolved Mn at up to ~30% of prefilter levels. These data suggest that using GAC may come with the risk of poor Mn removal performance if Mn is not removed during pretreatment. This work highlights the complexities anticipated under emerging climate pressures and emphasizes the need for comprehensive treatment solutions that consider factors beyond NOM.

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采用澄清和颗粒活性炭,使直接过滤适应增加水源水溶解有机碳
通过增加天然有机物(NOM)浓度来改变水源水质,对地表水处理,特别是直接过滤提出了挑战。在NOM水平上升的压力下,我们对直接过滤设施的各种适应策略(如澄清、颗粒活性炭[GAC]过滤)进行了中试规模评估。认识到水源水的变化会影响处理的更广泛方面,我们考虑了通过KMnO4预氧化去除Fe和Mn的影响。GAC培养基有望成为一种适应策略,可去除约60%的溶解有机碳(DOC),并显著降低消毒副产物形成潜力(DBPfp)。然而,KMnO4预处理显示出有限的Mn和Fe去除,具有GAC介质的过滤器释放的溶解Mn高达预过滤器水平的约30%。这些数据表明,如果在预处理过程中不去除Mn,使用GAC可能会带来Mn去除性能差的风险。这项工作强调了在新出现的气候压力下预期的复杂性,并强调需要考虑NOM以外因素的综合治疗解决方案。
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