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Lithium in drinking water: Review of chemistry, analytical methods, and treatment technologies 饮用水中的锂:化学、分析方法和处理技术综述
Pub Date : 2024-12-17 DOI: 10.1002/aws2.70009
Julie A. Korak, Philip J. Brandhuber, Joseph E. Goodwill

Lithium was included in the fifth Unregulated Contaminants Monitoring Rule, signaling the Environmental Protection Agency's interest in regulating lithium. Many questions regarding occurrence, health effects, and treatability of lithium exist. This review primarily focuses on the relationship between lithium chemistry and treatability. Sampling indicates nationwide lithium occurrence in drinking water. Yet, lithium is not included in the Integrated Risk Information System, reflecting a lack of censuses regarding its health effects. Aqueous lithium is a monovalent cation with size, charge density, and solubility properties that present treatment challenges. Lithium's growing economic value is stimulating new extraction and isolation technologies, but these may not be transferable to drinking water treatment. Currently, reverse osmosis is the only full-scale drinking water treatment technology that can reliably remove significant levels (>50%) of lithium. Focusing future research efforts on electrodialysis and inorganic ion sieves may yield significant gains in effectiveness and readiness for the drinking water industry.

锂被列入第五项不受管制的污染物监测规则,这标志着环境保护局对监管锂的兴趣。关于锂的发生、健康影响和可治疗性存在许多问题。本文主要综述了锂化学与可治疗性之间的关系。抽样显示全国饮用水中存在锂。然而,锂不包括在综合风险信息系统中,这反映了缺乏关于其健康影响的人口普查。含水锂是一种单价阳离子,其大小、电荷密度和溶解度都给处理带来了挑战。锂日益增长的经济价值刺激了新的提取和分离技术,但这些技术可能无法转移到饮用水处理中。目前,反渗透是唯一能够可靠地去除大量(50%)锂的全面饮用水处理技术。将未来的研究重点放在电渗析和无机离子筛上,可能会在饮用水工业的有效性和准备性方面取得重大进展。
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引用次数: 0
A pilot-scale study of potable reuse impacts on surface water treatment 饮用水回用对地表水处理影响的中试研究
Pub Date : 2024-12-04 DOI: 10.1002/aws2.70008
Hari Seshan, Michael J. Adelman, Paige J. Russell, Joseph Quicho, Daniel Daft, Thomas Watson

Interest is growing in direct potable reuse where advanced-treated water and raw water are blended and fed directly to a water treatment plant (WTP). However, the impacts of raw water augmentation on treatability at drinking water treatment plants have not been studied extensively. A pilot-scale treatment system, consisting of coagulation, flocculation, sedimentation, and filtration, was set up at a WTP to treat potential future blends of advanced-treated water and current raw water. The pilot plant was run with blends from 20% to 100% advanced-treated water at a range of filtration rates (2–9 gpm/sf) and coagulant doses. Under all conditions, filterable water was produced, achieving acceptable turbidity removal. Turbidity removal by sedimentation was variable (30%–90%). Filtration performance was more consistent, exceeding 90% turbidity reduction under all conditions and achieving lower headloss accumulation rates at higher advanced-treated water share. These results are optimistic for potable reuse schemes featuring raw water augmentation.

人们对直接饮用水再利用的兴趣日益浓厚,在这种情况下,经过高级处理的水和原水混合后直接送入水处理厂。然而,原水加注对饮用水处理厂可处理性的影响尚未得到广泛的研究。在WTP上建立了一个由混凝、絮凝、沉淀和过滤组成的中试处理系统,以处理未来可能的高级处理水和现有原水的混合物。中试装置在过滤速率(2 - 9gpm /sf)和混凝剂剂量范围内使用了20%至100%的深度处理水。在所有条件下,产生了可过滤的水,达到了可接受的浊度去除。沉淀法去除浊度是可变的(30%-90%)。过滤性能更加一致,在所有条件下浊度降低超过90%,并且在更高的深度处理水份额下实现更低的净水率积累。这些结果对以原水增加为特征的饮用水再利用方案是乐观的。
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引用次数: 0
2015 United States Public Health Service optimal fluoride level adherence and operation among adjusting water systems in 40 states: 2016–2021 2015年美国公共卫生服务在40个州调整水系统中的最佳氟化物水平坚持和运行:2016-2021
Pub Date : 2024-12-02 DOI: 10.1002/aws2.70007
Theresa J. Boehmer, Erin K. Hamilton, Srdjan Lesaja, Bertram Thomas, Lorena Espinoza, Rachel Kaufmann, Chandresh N. Ladva

In 2015, the United States Public Health Service (USPHS) set a target fluoride level for drinking water at 0.7 mg/L to maximize oral health benefits while minimizing any potential harms. Using water fluoridation operational data reported by water systems to the Centers for Disease Control and Prevention (CDC) Water Fluoridation Reporting System (WFRS) during 2016–2021, this study assesses how water systems performed around this target. The authors summarize completeness of data reporting, assess the distribution of monthly average fluoride readings (MAFR) values, and evaluate precision in maintaining fluoride levels. About 69% of adjusting systems provided data, with an average completeness of 63.8% among them. MAFR mean was 0.71 mg/L (SD: 0.20 mg/L), indicating that water systems have primarily adopted the USPHS target. About 76% of MAFRs fell ± 0.1 mg/L around the reporting system point's mean, indicating feasibility in maintaining precision around a target. State programs and water systems could work together to improve data quality and educate operators on best practices.

2015年,美国公共卫生服务局(USPHS)为饮用水设定了0.7毫克/升的氟化物目标水平,以最大限度地提高口腔健康效益,同时尽量减少任何潜在危害。利用2016-2021年期间供水系统向疾病控制与预防中心(CDC)水氟化报告系统(WFRS)报告的水氟化操作数据,本研究评估了供水系统如何围绕这一目标执行。作者总结了数据报告的完整性,评估了月平均氟化物读数(MAFR)值的分布,并评估了维持氟化物水平的精度。约69%的调节系统提供了数据,平均完整性为63.8%。平均MAFR为0.71 mg/L (SD为0.20 mg/L),表明水系统主要采用了USPHS目标。大约76%的MAFRs在报告系统点的平均值附近下降±0.1 mg/L,表明在目标附近保持精度的可行性。国家项目和供水系统可以共同努力,提高数据质量,并教育运营商采取最佳做法。
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引用次数: 0
Drinking water buffer intensity simulator (BIS): Development and practical simulations 饮用水缓冲强度模拟器(BIS):开发和实际模拟
Pub Date : 2024-11-13 DOI: 10.1002/aws2.70006
David G. Wahman, Michael R. Schock, Darren A. Lytle

An established body of research over many decades has identified the importance of both bulk-water and pipe scale surface microenvironment buffering to meet distribution system pH targets and reduce corrosivity toward metallic piping and components. Buffer intensity quantifies the ability of water to resist pH changes, and the greater the buffer intensity, the more resistant the water is to pH changes. To provide a practical tool for exploring buffer intensity, a buffer intensity simulator (BIS) was implemented in open-source R code, incorporating typical chemical species (e.g., carbonate and orthophosphate) that contribute to drinking water buffer intensity along with temperature and ionic strength impacts. The BIS was verified against a parallel spreadsheet implementation and is publicly available at https://github.com/USEPA/BIS. Simulations were conducted to illustrate impacts related to buffer intensity using three practical scenarios: carbonate buffering in drinking waters, temperature impacts, and free ammonia presence from chloramine use and/or source water presence.

数十年来的大量研究表明,要达到配水系统的 pH 值目标并降低对金属管道和部件的腐蚀性,散装水和管道表面微环境缓冲都非常重要。缓冲强度量化了水体抵御 pH 值变化的能力,缓冲强度越大,水体抵御 pH 值变化的能力越强。为了提供一种探索缓冲强度的实用工具,我们用开源 R 代码实现了缓冲强度模拟器 (BIS),其中包含对饮用水缓冲强度有影响的典型化学物质(如碳酸盐和正磷酸盐),以及温度和离子强度的影响。BIS 已通过并行电子表格实施验证,可在 https://github.com/USEPA/BIS 上公开获取。通过三种实际情况进行了模拟,以说明与缓冲强度有关的影响:饮用水中的碳酸盐缓冲、温度影响以及使用氯胺和/或原水中的游离氨。
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引用次数: 0
The role of genus Bacillus in biodegradation of microcystins: Implications for the removal of cyanotoxins from tropical freshwaters 芽孢杆菌属在微囊藻毒素生物降解中的作用:对清除热带淡水中蓝藻毒素的影响
Pub Date : 2024-11-11 DOI: 10.1002/aws2.70005
Madhuni Madhushika Wijesooriya, Kanaji Masakorala, Widana Gamage Shirani Manel Kumari

The proliferation of harmful cyanobacterial blooms poses a threat to the ecosystem and human health. Microcystins (MCs) are the most frequently detected cyanotoxin released by cyanobacteria, including Microcystis sp. Our study aimed to isolate potential MC-degrading bacteria in Sri Lankan freshwater and determine their possible MC-degradation pathways. Twenty-two morphologically distinct bacterial strains from 13 freshwater bodies were isolated following the enrichment assay. MC-biodegradation assays further confirmed the MC-degradation potential of 21 strains, with Bacillus being the predominant genus. The strain Bacillus altitudinis BL1, isolated from Beira Lake, showed the highest efficiency in Microcystis sp. cell lysis (80%) and MC-degradation (87%). PCR assay results confirmed the absence of mlrABCD genes in all strains, indicating the presence of uncharacterized alternative MC-degradation mechanisms that require further exploration. The dual functions of Microcystis sp. cell lysis and MC-degradation in 21 strains support developing efficient bacteria-mediated strategies to remediate microcystins and eradicate Microcystis-blooms in tropical freshwaters.

有害蓝藻水华的扩散对生态系统和人类健康构成威胁。微囊藻毒素(MC)是蓝藻(包括微囊藻)释放的最常见的蓝藻毒素。通过富集试验,我们从 13 个淡水水体中分离出了 22 株形态各异的细菌。二氯甲烷生物降解试验进一步证实了 21 株菌株的二氯甲烷降解潜力,其中芽孢杆菌是主要的菌属。从贝拉湖分离出的菌株 Bacillus altitudinis BL1 对微囊藻细胞裂解(80%)和 MC 降解(87%)的效率最高。PCR 检测结果证实,所有菌株中都没有 mlrABCD 基因,这表明存在尚未定性的替代 MC 降解机制,需要进一步探索。21 株微囊藻细胞裂解和 MC 降解的双重功能支持开发高效的细菌介导策略,以修复微囊藻毒素并根除热带淡水中的微囊藻。
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引用次数: 0
Chlorine conversion impact on activated carbon block filters: Water quality and nitrification risk in chloraminated water 氯转化对活性炭块过滤器的影响:氯化水的水质和硝化风险
Pub Date : 2024-10-27 DOI: 10.1002/aws2.70003
Horace Jakpa, Katherine Alfredo

The effectiveness of a periodic free chlorine conversion period (FClP) as a nitrification mitigation measure has been scrutinized in chloraminated distribution systems, and knowledge about the response of activated carbon block (ACB) point-of-use (POU) filters to this practice is unknown. In this study, three similar filters were monitored bracketing three successive FClPs in the laboratory, aimed at studying the response of ACB POU filters to FClP and the occurrence of nitrification. Results indicate that stagnating filters fostered biofilm growth and increased nitrite concentration (2.5 mg/L-N) above the EPA maximum contaminant level (MCL). Despite FClP being effective at mitigating nitrification and reducing nitrite concentration far below EPA MCL, this was only temporary. Filters that were microbially seeded before an FClP event re-nitrified immediately after chloramination resumed. Successive FClPs induced a microbial community change and failed at controlling nitrification, resulting in elevated nitrite and microbial exposure.

在氯化配水系统中,定期的游离氯转换期(FClP)作为硝化缓解措施的有效性已经得到了仔细的研究,但活性炭块(ACB)使用点(POU)过滤器对这种做法的反应尚不清楚。在这项研究中,在实验室中对三个类似的过滤器进行了监测,以研究活性炭块 POU 过滤器对氟氯化钾的反应以及硝化作用的发生。结果表明,停滞的过滤器促进了生物膜的生长,亚硝酸盐浓度(2.5 mg/L-N)增加,超过了美国环保署(EPA)规定的最高污染物浓度(MCL)。尽管 FClP 能有效缓解硝化作用并将亚硝酸盐浓度降至远低于 EPA MCL,但这只是暂时的。在恢复氯化过程之前已播下微生物种子的过滤器,在氯化过程恢复后会立即重新硝化。连续的氟氯化碳事件导致微生物群落发生变化,无法控制硝化作用,从而导致亚硝酸盐和微生物暴露量升高。
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引用次数: 0
Estimating the impact of the proposed Lead and Copper Rule Improvements 估算铅铜规则改进提案的影响
Pub Date : 2024-10-17 DOI: 10.1002/aws2.70004
Carleigh C. Samson, Sheldon V. Masters, Christian Ley Mathews, Chad J. Seidel

Lead in drinking water can lead to serious health effects, including neurodevelopmental issues and heart disease. In December 2023, the U.S. Environmental Protection Agency (EPA) proposed the Lead and Copper Rule Improvements (LCRI), which lower the Lead and Copper Rule's (LCR's) lead action level (AL) from 15 parts per billion (ppb) to 10 ppb and require both first- and fifth-liter sampling and 90th percentile compliance calculations based on the highest lead levels at sites with lead service lines. A methodology for estimating the likelihood a system will have an AL exceedance (ALE) under the LCRI was developed using Michigan LCR compliance data and applied to national LCR compliance data. Findings were compared to EPA's estimates, indicating EPA may have underestimated the percent of smaller systems (serving $$ le $$ 3300) with ALEs and overestimated the percent of larger systems (serving > 10,000), thus underestimating costs and overestimating the benefits of this rulemaking.

饮用水中的铅可导致严重的健康影响,包括神经发育问题和心脏病。2023 年 12 月,美国环保署 (EPA) 提出了铅铜法规改进方案 (LCRI),将铅铜法规 (LCR) 的铅行动水平 (AL) 从十亿分之十五 (ppb) 降低到十亿分之十,并要求根据含铅服务管线现场的最高铅含量进行第一升和第五升采样和第 90 百分位数达标计算。利用密歇根州的 LCR 达标数据,并将其应用于全国的 LCR 达标数据,制定了一种方法来估算系统在 LCRI 下出现 AL 超标 (ALE) 的可能性。研究结果与 EPA 的估计进行了比较,表明 EPA 可能低估了较小系统(服务 ≤ $le $3300)中出现 ALE 的百分比,高估了较大系统(服务 > 10,000)中出现 ALE 的百分比,从而低估了成本,高估了该规则制定的效益。
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引用次数: 0
The use of lead isotopes for determining sources of lead in drinking water 利用铅同位素确定饮用水中铅的来源
Pub Date : 2024-10-14 DOI: 10.1002/aws2.70002
David A. Cornwell, George Kamenov, Nancy E. McTigue

A series of paired samples were analyzed to determine if high-precision lead isotopic fingerprinting could help identify the source of lead in plumbing materials and drinking water. Samples were obtained of plumbing materials (lead service lines, copper pipe with lead solder, galvanized materials, and brass fixtures) from water utilities across the United States. Lead samples were taken from the material itself, from scales, and in some cases from associated water. The lead samples were analyzed to determine the ratios of the four stable lead isotopes present. The results enabled the identification of relationships between various components and further aided in the identification of the source of lead found in water and in pipe scales. Isotopic fingerprinting, as demonstrated in this study, could be used to determine if a galvanized line is a galvanized line requiring replacement (GRR) under the Lead and Copper Rule Improvements (USEPA, 2023).

对一系列配对样本进行了分析,以确定高精度铅同位素指纹图谱是否有助于确定冷热水管道材料和饮用水中的铅来源。研究人员从美国各地的自来水公司获取了管道材料样本(含铅供水管道、含铅焊料的铜管、镀锌材料和黄铜固定装置)。铅样本取自材料本身、鳞片,有时也取自相关的水。对铅样本进行了分析,以确定存在的四种稳定铅同位素的比率。分析结果有助于确定各种成分之间的关系,并进一步帮助确定在水和管道鳞片中发现的铅的来源。本研究中展示的同位素指纹识别技术可用于确定镀锌管道是否属于《铅铜规则改进》(USEPA,2023 年)中要求更换的镀锌管道 (GRR)。
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引用次数: 0
Repeated conventional flushing to improve water quality in a full-scale distribution system 重复常规冲洗以改善全规模输水系统的水质
Pub Date : 2024-10-10 DOI: 10.1002/aws2.70001
Matthew Vedrin, Joseph N. S. Eisenberg, Sarah Page, Rebecca Lahr, Brian Steglitz, Rebecca Hardin, Lutgarde Raskin

One of the primary ways utilities prevent and address water quality concerns in distribution systems is via regular hydrant flushing, yet rigorous research to evaluate the impact of full-scale flushing programs is limited. This study employed time-series and correlation analyses to evaluate the efficacy of a utility's five-month repeated conventional flushing program to reduce nitrification and improve disinfectant residual concentrations in the distribution system. Short-term water quality improvements during flushes were common across the 16 locations flushed, but lasting improvements were inconsistent as demonstrated by continued nitrification and heterogeneous water quality changes. Flushing frequencies and flow rates may need to be tailored to individual sites, even when similar water quality challenges exist. Water quality monitoring data and related analyses helped to prioritize flush sites, maximize efficiency during and between flushes, and inform decisions to implement additional interventions.

公用事业公司预防和解决输水系统水质问题的主要方法之一是定期冲洗消防栓,但评估全面冲洗计划影响的严格研究却很有限。本研究采用时间序列和相关性分析来评估公用事业公司为期五个月的重复常规冲洗计划对减少硝化和改善输水系统中消毒剂残留浓度的效果。在冲洗过程中,16 个冲洗点的水质普遍得到短期改善,但持续的硝化和水质的不同变化表明,水质的持久改善并不一致。即使存在类似的水质挑战,冲洗频率和流速也可能需要根据各个地点的具体情况进行调整。水质监测数据和相关分析有助于确定冲洗地点的优先次序,最大限度地提高冲洗期间和两次冲洗之间的效率,并为实施其他干预措施的决策提供信息。
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引用次数: 0
Rejection of low-molecular weight neutral organics is highly sensitive to reverse osmosis system design and operation 低分子量中性有机物的去除对反渗透系统的设计和运行非常敏感
Pub Date : 2024-09-30 DOI: 10.1002/aws2.70000
Kerry J. Howe, Jose P. Hernandez-Quintero, Carson O. Lee

A computational model was developed to investigate the significance of system design and operating conditions on the rejection of neutral, low-MW organics by reverse osmosis for potable reuse. The model demonstrated that the decrease in local rejection as net driving pressure decreases is substantially greater for moderately rejected compounds than for highly rejected compounds. At recovery values less than 70%, the local permeate concentration can exceed the pressure vessel feed concentration for moderately rejected compounds. System-level rejection of moderately rejected compounds is likewise substantially more sensitive to operating conditions than highly rejected compounds. The findings highlight a drawback of relying on rejection results from bench-scale testing that operates at low recovery, which invariably has higher rejection than full-scale systems operating at similar pressure. The analysis demonstrates a trade-off in which the low-pressure, high-recovery operation desired for potable reuse systems can be detrimental to the removal of low-MW neutral organics. The removal of low-MW neutral organics can be improved if organics rejection is explicitly evaluated during the design process.

开发了一个计算模型,以研究系统设计和运行条件对饮用水回用反渗透法剔除中性、低 MW 有机物的影响。该模型表明,随着净驱动压力的降低,中度截留化合物的局部截留下降幅度要远远大于高度截留化合物。在回收率低于 70% 的情况下,对于中度剔除的化合物,本地渗透物的浓度可能会超过压力容器的进料浓度。同样,中度剔除化合物的系统级剔除对操作条件的敏感度也远高于高度剔除化合物。这些发现凸显了依赖于在低回收率下运行的台架试验的排斥结果的缺点,因为在低回收率下运行的台架试验的排斥率总是高于在类似压力下运行的全规模系统。分析表明,饮用水回用系统所需的低压、高回收率运行可能不利于去除低兆瓦级的中性有机物。如果在设计过程中对有机物去除进行明确评估,则可提高去除低兆瓦级中性有机物的能力。
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引用次数: 0
期刊
AWWA water science
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