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Surfactant Optimization for PFAS Removal in Site Groundwater Using Colloidal Gas Aphrons (CGAs) 胶体气aphron (CGAs)去除现场地下水中PFAS的表面活性剂优化
IF 1.8 Pub Date : 2026-01-20 DOI: 10.1002/aws2.70048
Poonam R. Kulkarni, Hassan Javed, Nicholas W. Johnson, John A. Connor, Jessica Alanis, William Vines, Hanadi Rifai, Charles J. Newell

Colloidal gas aphrons (CGAs) have proven successful in separating both long- and short-chain PFAS from water; however, little information is available on the impact of surfactants used for aphron generation. This study assesses the use of five cationic surfactant-generated CGAs in batch experiments to remove PFAS from two site groundwaters. The results found that lauric arginate ethyl ester (LAE), a food-grade surfactant used to generate CGAs, had the best performance, removing over 80% of PFAAs in a single stage. Removal rates were consistent between high- and low-concentration waters, indicating its versatility. The addition of a second stage of treatment improved PFAS removal, particularly for short-chain PFAS, as the first stage predominantly removed long-chain PFAS due to their greater presence in the initial water. Higher salinity and saponins reduced the removal rates due to competitive sorption. Overall, the success of a food-grade surfactant for CGA generation is significant in terms of water treatment.

胶体气aphrons (CGAs)已被证明可以成功地从水中分离长链和短链PFAS;然而,关于表面活性剂对aphron生成的影响的信息很少。本研究评估了在批量实验中使用五种阳离子表面活性剂生成的CGAs来去除两个站点地下水中的PFAS。结果表明,用于生成CGAs的食品级表面活性剂月桂精氨酸乙酯(LAE)的去除率最高,单段可达80%以上。高浓度和低浓度水体的去除率一致,表明其通用性。添加第二阶段的处理改善了PFAS的去除,特别是对于短链PFAS,因为第一阶段主要去除长链PFAS,因为它们在初始水中存在更多。较高的盐度和皂甙降低了由于竞争吸附的去除率。总的来说,食品级表面活性剂在水处理方面的成功是显著的。
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引用次数: 0
Drinking Water Biofiltration Performance With Varying Ozone and Hydraulic Operations 不同臭氧和水力操作下的饮用水生物过滤性能
IF 1.8 Pub Date : 2025-12-25 DOI: 10.1002/aws2.70047
Kara Cunningham, Amanda Minke, Ramola Vaidya, Christina Alito, Carolyn Hannoch, Eric Rogers, Jessica Edwards-Brandt, Gerardo Castaneda, Anurag Mantha, Mary Jo Kirisits, Emily Garner, Bradley Schmitz

This study produced a comprehensive drinking water ozone-biofiltration evaluation by assessing performance at a newly commissioned facility with varying hydraulic and ozonation operations. In brief, 30 water quality, operational, and biological parameters were collected at 11 locations throughout the treatment train at least every other week for an entire year. Seasonal and environmental variation seemed to influence treatment performance more than operational changes (i.e., ozone or hydraulic re-rating). However, media adenosine triphosphate (ATP), an indicator of biomass, was sensitive to hydraulic variability. Organic carbon was identified as a reliable performance metric, particularly when total organic carbon (TOC) and dissolved organic carbon (DOC) shared a strong linear relationship. Carboxylic acid removal also served as a useful long-term monitoring tool for assessing ozone-biofilter performance. This study establishes a critical benchmark for capturing the effects of intermittent ozonation, variable hydraulic loading, and seasonal transitions that utilities can utilize to better understand ozone-biofiltration processes in drinking water treatment systems.

本研究通过评估新投入使用的不同水力和臭氧化操作设施的性能,对饮用水臭氧-生物过滤进行了全面的评估。简而言之,在整个处理过程中,至少每隔一周在11个地点收集30个水质、操作和生物参数,持续一整年。季节和环境变化似乎比操作变化(即臭氧或水力重新分级)更能影响处理效果。然而,作为生物量指标的培养基三磷酸腺苷(ATP)对水力变化非常敏感。有机碳被认为是一个可靠的性能指标,特别是当总有机碳(TOC)和溶解有机碳(DOC)具有很强的线性关系时。羧酸去除也作为评估臭氧生物过滤器性能的有用的长期监测工具。本研究为捕捉间歇性臭氧化、可变水力负荷和季节转换的影响建立了一个关键基准,公用事业公司可以利用这些基准更好地了解饮用水处理系统中的臭氧-生物过滤过程。
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引用次数: 0
Combined UV LED and Chlorine for Synergistic Drinking Water Disinfection and Assessment of Disinfection By-Product Formation UV LED与氯离子协同饮用水消毒及消毒副产物形成评价
IF 1.8 Pub Date : 2025-12-11 DOI: 10.1002/aws2.70046
Jin Li, Sean MacIsaac, Xuedongzi Jiang, Lindsay E. Anderson, Kyle D. Rauch, Taylor Prest, Ryan Swinamer, Amina K. Stoddart, Graham A. Gagnon

This study provides a comprehensive evaluation of the effectiveness of 280 nm UV LEDs in enhancing chlorine disinfection in natural water sources. The results of this work indicate sequential treatments (UV-chlorine and chlorine-UV) further enhanced the disinfection efficiency of T1 in natural waters, especially at higher UV doses, such as 40 mJ cm−2. The log reduction value for the chlorine-UV sequence reached 6.65, slightly higher than the 6.29 for the UV-chlorine sequence, suggesting that sequencing influences disinfection efficacy at higher fluences. UV LED-enhanced chlorine disinfection did not significantly alter concentrations of THMs and HAAs. Overall, the findings of this study open new avenues for the application of UV LEDs in drinking water disinfection, demonstrating their potential as an alternative to traditional disinfection methods. Future research should further explore the effects of UV-chlorine combined treatments under different water quality conditions to optimize disinfection processes and provide theoretical support for innovation in water treatment technologies.

本研究全面评价了280 nm UV led在天然水源中加强氯消毒的有效性。这项工作的结果表明,顺序处理(UV-氯和氯-UV)进一步提高了T1在天然水中的消毒效率,特别是在较高的紫外线剂量下,如40 mJ cm - 2。氯-紫外序列的对数还原值为6.65,略高于紫外-氯序列的6.29,表明序列对消毒效果的影响程度更高。紫外led增强氯消毒没有显著改变THMs和HAAs的浓度。总的来说,这项研究的发现为UV led在饮用水消毒中的应用开辟了新的途径,展示了它们作为传统消毒方法的替代品的潜力。未来的研究应进一步探索不同水质条件下uv -氯联合处理的效果,优化消毒工艺,为水处理技术创新提供理论支持。
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引用次数: 0
Orthophosphate and Residence Time Impacts in Chloraminated Model Distribution Systems 氯胺化模型配电系统中正磷酸盐和停留时间的影响
IF 1.8 Pub Date : 2025-12-09 DOI: 10.1002/aws2.70045
Mahmoud H. Badawy, Vedika Bakshi, Sigrid Peldszus, Robin M. Slawson, Peter M. Huck

The combined effects of orthophosphate addition and residence time on chloramine stability, biofilm development, and nitrification potential in drinking water distribution systems (DWDSs) remain unexplored. Most previous studies examined orthophosphate dose under fixed residence time conditions, leaving a gap in understanding how water age modifies these impacts. This study evaluated the effects of orthophosphate and residence time (6/12 days) on monochloramine decay, biofilm growth, and nitrification potential using bench-scale systems. At the 12-day residence time, chloramine decay, biofilm growth, and nitrite accumulation were significantly greater, with orthophosphate amplifying these effects. Biofilm metabolic activity initially increased with orthophosphate before converging with the control, while bulk water metabolic activity remained higher. Genetic profiling revealed microbial community shifts under extended residence time and orthophosphate. These findings demonstrate that orthophosphate, when combined with longer residence times, can accelerate microbial activity and nitrification, highlighting the need to manage both factors to safeguard water quality.

正磷酸盐添加和停留时间对饮用水分配系统(DWDSs)中氯胺稳定性、生物膜发育和硝化潜力的综合影响尚不清楚。大多数先前的研究检查了固定停留时间条件下的正磷酸盐剂量,在理解水年龄如何改变这些影响方面留下了空白。本研究评估了正磷酸盐和停留时间(6/12天)对单氯胺衰变、生物膜生长和硝化潜力的影响。在12 d的停留时间内,氯胺衰变、生物膜生长和亚硝酸盐积累显著增加,而正磷酸盐则放大了这些影响。生物膜代谢活性最初随着正磷酸盐的增加而增加,然后与对照趋同,而散装水代谢活性仍然较高。遗传图谱显示微生物群落在延长停留时间和正磷酸盐作用下发生变化。这些发现表明,正磷酸盐与较长的停留时间相结合,可以加速微生物活性和硝化作用,突出了管理这两个因素以保障水质的必要性。
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引用次数: 0
Climate Change Impacts and Adaptation for Water Distribution Systems: Physical, Hydraulic, and Water Quality Integrity 气候变化对配水系统的影响和适应:物理、水力和水质完整性
IF 1.8 Pub Date : 2025-12-04 DOI: 10.1002/aws2.70044
Juneseok Lee, Elizabeth Murphy, Fatemeh Hatam, Michele Prevost

Water distribution systems (WDS) are critical infrastructures essential for human well-being and economic prosperity. However, climate change (CC) is increasingly causing variational environmental stress and natural disasters that threaten the integrity of these systems. Without resilient and sustainable WDS, societies will struggle to function effectively. This review article examines the impact of CC on the integrity of WDS, focusing on physical, hydraulic, and water quality aspects. It presents a synthesis of recently published peer-reviewed journal articles that address these dimensions, while acknowledging their synergistic interrelationships. The paper presents adaptation strategies and highlights utility case studies aimed at strengthening the resilience of WDS against the impacts of CC.

供水系统(WDS)是人类福祉和经济繁荣的关键基础设施。然而,气候变化(CC)越来越多地引起变化的环境压力和自然灾害,威胁到这些系统的完整性。没有弹性和可持续的白龙会,社会将难以有效运作。本文从物理、水力和水质三个方面探讨了CC对WDS完整性的影响。它介绍了最近发表的同行评审期刊文章的综合,这些文章涉及这些方面,同时承认它们的协同相互关系。本文提出了适应策略,并重点介绍了旨在加强WDS抵御气候变化影响的能力的公用事业案例研究。
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引用次数: 0
Asbestos Cement Pipes in Water Distribution Systems: Health Risks, Regulations, and Management 配水系统中的石棉水泥管道:健康风险、法规和管理
IF 1.8 Pub Date : 2025-11-18 DOI: 10.1002/aws2.70043
Johannes Gérson Janzen

This review introduces a novel risk-based management framework for asbestos cement (AC) pipes in drinking water systems, emphasizing maintenance practices and occupational health risks while harmonizing global regulatory and utility practices. Inhalation risks are well established, but WHO guidance indicates negligible risks from ingestion, not warranting regulatory limits. The framework addresses gaps in fiber release monitoring, standardizing protocols to minimize occupational exposure. AC pipes, deployed since the 1920s, persist in many systems despite phase outs. The study highlights deficiencies in fiber release under varying water corrosivity, advocating management of aging infrastructure through GIS tracking, non-destructive testing (NDT), and phased replacement, informed by case studies from Australia and New Zealand. Airborne exposure underscores the need for standardized protocols. Public engagement and evidence-based decisions are essential where immediate replacement is not mandated. This global synthesis integrates regulatory guidance, utility practices, and health data into an actionable framework.

本文介绍了一种新的基于风险的饮用水系统石棉水泥(AC)管道管理框架,强调维护实践和职业健康风险,同时协调全球监管和公用事业实践。吸入风险是公认的,但世卫组织的指导表明,摄入的风险可以忽略不计,不需要制定监管限制。该框架解决了光纤释放监测方面的差距,标准化协议以最大限度地减少职业暴露。自20世纪20年代开始使用的交流管道,尽管已逐步淘汰,但仍在许多系统中使用。该研究强调了不同水腐蚀性下纤维释放的不足,并通过澳大利亚和新西兰的案例研究,倡导通过GIS跟踪、无损检测(NDT)和分阶段更换来管理老化的基础设施。空气传播暴露强调了标准化协议的必要性。在没有强制要求立即更换的情况下,公众参与和基于证据的决策至关重要。这一全球综合将监管指导、公用事业实践和健康数据整合到一个可操作的框架中。
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引用次数: 0
Interface of Weather and Climate: The Great Midwest Flood of 2008 天气和气候的界面:2008年中西部大洪水
IF 1.8 Pub Date : 2025-10-23 DOI: 10.1002/aws2.70041
Russell L. Cuhel, Carmen Aguilar

Ten days of continuous torrential rain pushed warm late Spring runoff in deltaic patterns far into Lake Michigan over two subsequent months. Repeated expeditions on the RV Neeskay documented shallow lenses of plankton-enriched water spreading across the surface at 1 km (0.6 mi) per day for months, reaching halfway across the lake, and often running against prevailing currents. Floating cohesively near the surface, a trail of strong, river-harbor-originating biological productivity long outlasted chemical evidence of stormwater efflux in depleted coastal and offshore regions. Only sinking algal populations descended into cooler midwater depths. Previously depauperated siliceous protein- and lipid-rich diatom algae were strongly favored, suggesting a change in water chemistry not readily detected in standard water quality measurements. Initial community outgrowth in near-surface water was evident through turbidity and enhanced biomass as a wave of growth moved offshore, trailed by resurgence of midwater diatom community blooms. Anomalously high surface chloride moved past 25 km 30 days after peak flow. Conductivity is a valuable tool for detection of riverine and harbor water intrusion, as runoff-fed rivers have higher dissolved salts than receiving waters. Endurance of impact indicated that sources far from intakes could pose water quality risks for stable substances. Seasonal temperatures controlled river–lake interactions as Spring runoff warmed by surfaces was buoyant on cool lakewater. Nearshore water treatment intakes thus lay well below the initial surface lens outflows, but biological products would have impinged on them during subsequent sinking. Operational recommendations for predictive event assessment by water producers are provided.

连续十天的暴雨在随后的两个月里将温暖的春末三角洲径流推入密歇根湖。在RV Neeskay上的多次探险记录了富含浮游生物的浅水透镜,它们以每天1公里(0.6英里)的速度在湖面上扩散,持续了几个月,达到了湖的一半,并且经常逆流而行。在枯竭的沿海和近海地区,一条强大的、源自河流港口的生物生产力的踪迹,紧密地漂浮在水面上,其存在时间远远超过了暴雨溢出的化学证据。只有下沉的藻类种群才会下降到较冷的中水深处。先前贫硅蛋白和富含脂质的硅藻受到强烈青睐,这表明在标准水质测量中不易检测到水化学的变化。在近地表水中,随着一波生长浪潮向近海移动,通过浊度和生物量的增加可以明显地看出群落的最初生长,随后是水体中硅藻群落的重现。异常高的地表氯化物在峰值后30天移动超过25公里。电导率是检测河流和港口水入侵的一个有价值的工具,因为径流河流比接收水具有更高的溶解盐。冲击的持久性表明,远离入口的来源可能对稳定物质构成水质风险。季节温度控制着河流与湖泊的相互作用,因为被表面加热的春季径流在凉爽的湖水上漂浮。因此,近岸水处理的入口远低于最初的表面透镜流出物,但在随后的下沉过程中,生物制品会撞击它们。为水生产商提供预测事件评估的操作建议。
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引用次数: 0
Estimating Ion Exchange Resin Intraparticle Diffusion Coefficients: Method Development and Nitrate Application 离子交换树脂颗粒内扩散系数的估算:方法发展及硝酸盐的应用
IF 1.8 Pub Date : 2025-10-16 DOI: 10.1002/aws2.70042
Samantha J. Smith, Brooke N. Gray, Esther W. Hughes, Levi M. Haupert, Isabella L. Bass, Eric J. Kleiner, Ben J. Burkhart, Sophia G. Pedigo, Jackson D. Quinn, Gulizhaer Abulikemu, Jonathan G. Pressman, George A. Sorial, David G. Wahman

Gel-type anion exchange (AEX) resin performance is impacted by internal mass transfer, which is represented by the solid-phase intraparticle diffusion coefficient (Ds). Importantly, Ds values are required inputs to ion exchange treatment process models but are rarely reported. Previous experiments using gel-type AEX resins exhibited external mass transfer control, preventing Ds estimation for several anions, including perfluoroalkyl substances. To reduce external mass transfer resistance and allow Ds estimation, a stainless-steel centrifugal stirrer device was standardized and validated with nitrate (model anion). Initially, experiments were conducted across mixing speeds (750–1750 rpm) to balance (1) maximizing external mass transfer and (2) preventing flow disturbances. Subsequently, experiments used an optimized speed to estimate nitrate Ds at multiple initial concentrations on three gel-type AEX resins. The developed methodology was useful for determining nitrate Ds and should enable improved Ds estimates for other contaminants, including perfluoroalkyl substances, needed for ion exchange treatment process models.

凝胶型阴离子交换(AEX)树脂的性能受到内部传质的影响,内部传质由固相颗粒内扩散系数(Ds)表示。重要的是,Ds值是离子交换处理过程模型所需的输入,但很少报道。先前使用凝胶型AEX树脂的实验显示出外部传质控制,阻止了对包括全氟烷基物质在内的几种阴离子的Ds估计。为了减小外部传质阻力并允许Ds的估算,对不锈钢离心搅拌装置进行了标准化和硝酸盐(模型阴离子)验证。最初,实验在不同的混合速度(750-1750 rpm)下进行,以平衡(1)最大化外部传质和(2)防止流动干扰。随后,实验使用优化的速度来估计三种凝胶型AEX树脂在不同初始浓度下的硝酸盐Ds。所开发的方法可用于确定硝酸盐中的Ds,并可改进对离子交换处理过程模型所需的其他污染物(包括全氟烷基物质)的Ds估计。
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引用次数: 0
Correction to “Estimating the Relationship Between Water Utility Workforce Quality and Water Utility Performance” 更正“估计水务公司员工素质与水务公司业绩的关系”
IF 1.8 Pub Date : 2025-10-05 DOI: 10.1002/aws2.70040

Saywitz, R. R. 2025. “Estimating the Relationship Between Water Utility Workforce Quality and Water Utility Performance.” AWWA Water Science 7, no. 5: e70032. https://doi.org/10.1002/aws2.70032.

The word “compliance” in the second to last sentence of the abstract should be “violations.”

The corrected abstract is presented below.

ABSTRACT

Workforce quality has been a major concern in the water utility sector for decades. While previous research presumes that workforce quality plays an important role in water utility performance, no research to date has explored this relationship empirically. This study represents a first attempt at quantifying the relationship between workforce quality and performance using a dataset containing water utilities in Texas serving over 500 customers, data on Safe Drinking Water Act (SDWA) violations, and water utility operator classes. The results of two negative binomial models, where the dependent variables are the count of SDWA health and SDWA monitoring and reporting violations between 2020 and 2024, show that workforce quality has a substantively large and statistically significant negative effect on SDWA violations across both types of violations. An additional analysis explores the interactive effect of workforce quality and median income and workforce quality and water source on utility performance.

We apologize for this error.

塞维茨,r.r. 2025。估计水务公司员工素质与水务公司绩效之间的关系AWWA水科学,第7期。5: e70032。https://doi.org/10.1002/aws2.70032.The摘要倒数第二句中的“合规”一词应改为“违规”。更正后的摘要如下。几十年来,劳动力质量一直是水务部门关注的主要问题。虽然以前的研究假设劳动力素质在水务公司绩效中起着重要作用,但迄今为止还没有研究对这种关系进行实证研究。本研究首次尝试量化劳动力质量与绩效之间的关系,使用的数据集包含德克萨斯州服务于500多名客户的水务公司、违反《安全饮用水法》(SDWA)的数据以及水务公司运营商类别。两个负二项模型的结果表明,在2020年至2024年期间,SDWA健康和SDWA监测和报告违规行为的数量是两个负二项模型的变量,劳动力质量对两种类型的SDWA违规行为都有相当大的、统计上显著的负面影响。另一项分析探讨了劳动力质量和收入中位数以及劳动力质量和水源对公用事业绩效的互动影响。我们为这个错误道歉。
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引用次数: 0
Indirect Electrochemical Regeneration of Manganese Oxide (MnOx) – Coated Media 锰氧化物(MnOx)涂层介质的间接电化学再生
IF 1.8 Pub Date : 2025-10-03 DOI: 10.1002/aws2.70038
Carrie Ellis, Joseph E. Goodwill

Manganese (Mn) in drinking water poses aesthetic, health, and operational concerns. One common removal method involves adsorbing soluble Mn(II) onto manganese (III/IV) oxide (MnOx)-coated media, but this approach typically relies on chemical reagents for surface regeneration. In systems lacking chemical storage, dosing, and containment capacity, this may be impractical. This study demonstrated an alternative regeneration technique using an electrochemical reactor for in situ oxidant production at conditions relevant to drinking water treatment. The reactor generated oxidants, likely free chlorine, and increased the pH of the applied water. Across batch-scale recirculating, intermittent regeneration, and single-pass continuous regeneration experiments, electrochemically regenerated MnOx-coated media produced ~90% removal of Mn(II), achieving a common treatment goal of 0.02 mg/L. Regeneration was also confirmed by analyzing the average oxidation state of the MnOx surface. Performance depended on several factors, such as raw water Mn, applied voltage, and alkalinity. Although modeling and Mn fractionation suggested limited homogenous oxidation of Mn(II), the formation of some colloidal MnOx may have confounded results in some experimental situations. These findings highlight a promising, reagent-free strategy for regenerating oxide-coated media, expanding its applicability for water treatment, especially in isolated systems and point-of-use applications.

饮用水中的锰(Mn)会引起审美、健康和操作方面的问题。一种常见的去除方法是将可溶性锰(II)吸附到锰(III/IV)氧化物(MnOx)涂层介质上,但这种方法通常依赖于化学试剂进行表面再生。在缺乏化学储存、剂量和遏制能力的系统中,这可能是不切实际的。这项研究展示了一种替代再生技术,使用电化学反应器在与饮用水处理相关的条件下进行原位氧化剂生产。反应器产生氧化剂,可能是游离氯,并增加了所施用水的pH值。在批量循环、间歇再生和单次连续再生实验中,电化学再生的mnox包覆介质的Mn(II)去除率达到90%,达到了0.02 mg/L的共同处理目标。通过分析MnOx表面的平均氧化态也证实了再生。性能取决于几个因素,如原水Mn、施加电压和碱度。尽管建模和Mn分异表明Mn(II)的均质氧化有限,但在某些实验情况下,一些胶体MnOx的形成可能会混淆结果。这些发现强调了一种有前途的、无试剂的氧化涂层介质再生策略,扩大了其在水处理中的适用性,特别是在隔离系统和使用点应用中。
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引用次数: 0
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