Recent Advances in the Use of Dimethyl Sulfoxide as a Synthon in Organic Chemistry

IF 7.1 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Topics in Current Chemistry Pub Date : 2022-10-28 DOI:10.1007/s41061-022-00411-8
Hao Lu, Zhou Tong, Lifen Peng, Zhiqing Wang, Shuang-Feng Yin, Nobuaki Kambe, Renhua Qiu
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引用次数: 8

Abstract

Dimethyl sulfoxide (DMSO), as extremely important aprotic polar solvent and reaction medium, has attracted widespread attention from chemists in recent years due to its wide range of uses and the multiple functions it displays in various chemical processes. Especially in the past decade, dimethyl sulfoxide has become increasingly favored as a synthon in organic chemistry, resulting in great progress in this research field. In this context, this review provides a comprehensive summary of the literature on the recent progress in organic synthesis using dimethyl sulfoxide as a synthon, covering all the reports from 1 January 2016 to 11 May 2022. This type of reaction is mainly performed by transferring one or more units of dimethyl sulfoxide, such as oxygen (–O–, =O), methyl (–CH3), methylene (–CH2–), methylidene (=CH2), methine (=CH–), donor of formylation (–CHO), sulfur (–S–), methylthio (–SMe), methyl sulfoxide (–SOMe), donor of methyl thiomethylation (–CH2SMe), or donor of methyl sulfoxide methylation (–CH2SOMe), to the target molecules. At the same time, we hope that this review will stimulate future studies and promote developments in this area.

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二甲基亚砜合成物在有机化学中的应用进展
二甲基亚砜(DMSO)作为一种非常重要的非质子极性溶剂和反应介质,由于其广泛的用途和在各种化学过程中所表现出的多种功能,近年来引起了化学家们的广泛关注。特别是近十年来,二甲基亚砜作为一种合成物越来越受到有机化学领域的青睐,使该领域的研究取得了很大的进展。在此背景下,本文对2016年1月1日至2022年5月11日期间以二甲亚砜为合成物的有机合成的最新进展进行了文献综述。这类反应主要是通过将二甲基亚砜的一个或多个单位,如氧(- O -, =O)、甲基(- ch3)、亚甲基(- CH2 -)、亚甲基(=CH2)、甲基(=CH -)、甲酰化供体(- cho)、硫(- s -)、甲基硫(- sme)、甲基亚砜(- some)、甲基硫甲基化供体(- ch2sme)或甲基亚砜甲基化供体(- ch2some)转移到目标分子上进行的。同时,我们也希望本文的综述能够刺激未来的研究,促进这一领域的发展。图形抽象
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来源期刊
Topics in Current Chemistry
Topics in Current Chemistry Chemistry-General Chemistry
CiteScore
13.70
自引率
1.20%
发文量
48
期刊介绍: Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.
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