Recent Advances in the Use of Dimethyl Sulfoxide as a Synthon in Organic Chemistry

IF 7.1 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Topics in Current Chemistry Pub Date : 2022-10-28 DOI:10.1007/s41061-022-00411-8
Hao Lu, Zhou Tong, Lifen Peng, Zhiqing Wang, Shuang-Feng Yin, Nobuaki Kambe, Renhua Qiu
{"title":"Recent Advances in the Use of Dimethyl Sulfoxide as a Synthon in Organic Chemistry","authors":"Hao Lu,&nbsp;Zhou Tong,&nbsp;Lifen Peng,&nbsp;Zhiqing Wang,&nbsp;Shuang-Feng Yin,&nbsp;Nobuaki Kambe,&nbsp;Renhua Qiu","doi":"10.1007/s41061-022-00411-8","DOIUrl":null,"url":null,"abstract":"<div><p>Dimethyl sulfoxide (DMSO), as extremely important aprotic polar solvent and reaction medium, has attracted widespread attention from chemists in recent years due to its wide range of uses and the multiple functions it displays in various chemical processes. Especially in the past decade, dimethyl sulfoxide has become increasingly favored as a synthon in organic chemistry, resulting in great progress in this research field. In this context, this review provides a comprehensive summary of the literature on the recent progress in organic synthesis using dimethyl sulfoxide as a synthon, covering all the reports from 1 January 2016 to 11 May 2022. This type of reaction is mainly performed by transferring one or more units of dimethyl sulfoxide, such as oxygen (–O–, =O), methyl (–CH<sub>3</sub>), methylene (–CH<sub>2</sub>–), methylidene (=CH<sub>2</sub>), methine (=CH–), donor of formylation (–CHO), sulfur (–S–), methylthio (–SMe), methyl sulfoxide (–SOMe), donor of methyl thiomethylation (–CH<sub>2</sub>SMe), or donor of methyl sulfoxide methylation (–CH<sub>2</sub>SOMe), to the target molecules. At the same time, we hope that this review will stimulate future studies and promote developments in this area.</p><h3>Graphical Abstract</h3>\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\n </div>","PeriodicalId":54344,"journal":{"name":"Topics in Current Chemistry","volume":null,"pages":null},"PeriodicalIF":7.1000,"publicationDate":"2022-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Topics in Current Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s41061-022-00411-8","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 8

Abstract

Dimethyl sulfoxide (DMSO), as extremely important aprotic polar solvent and reaction medium, has attracted widespread attention from chemists in recent years due to its wide range of uses and the multiple functions it displays in various chemical processes. Especially in the past decade, dimethyl sulfoxide has become increasingly favored as a synthon in organic chemistry, resulting in great progress in this research field. In this context, this review provides a comprehensive summary of the literature on the recent progress in organic synthesis using dimethyl sulfoxide as a synthon, covering all the reports from 1 January 2016 to 11 May 2022. This type of reaction is mainly performed by transferring one or more units of dimethyl sulfoxide, such as oxygen (–O–, =O), methyl (–CH3), methylene (–CH2–), methylidene (=CH2), methine (=CH–), donor of formylation (–CHO), sulfur (–S–), methylthio (–SMe), methyl sulfoxide (–SOMe), donor of methyl thiomethylation (–CH2SMe), or donor of methyl sulfoxide methylation (–CH2SOMe), to the target molecules. At the same time, we hope that this review will stimulate future studies and promote developments in this area.

Graphical Abstract

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
二甲基亚砜合成物在有机化学中的应用进展
二甲基亚砜(DMSO)作为一种非常重要的非质子极性溶剂和反应介质,由于其广泛的用途和在各种化学过程中所表现出的多种功能,近年来引起了化学家们的广泛关注。特别是近十年来,二甲基亚砜作为一种合成物越来越受到有机化学领域的青睐,使该领域的研究取得了很大的进展。在此背景下,本文对2016年1月1日至2022年5月11日期间以二甲亚砜为合成物的有机合成的最新进展进行了文献综述。这类反应主要是通过将二甲基亚砜的一个或多个单位,如氧(- O -, =O)、甲基(- ch3)、亚甲基(- CH2 -)、亚甲基(=CH2)、甲基(=CH -)、甲酰化供体(- cho)、硫(- s -)、甲基硫(- sme)、甲基亚砜(- some)、甲基硫甲基化供体(- ch2sme)或甲基亚砜甲基化供体(- ch2some)转移到目标分子上进行的。同时,我们也希望本文的综述能够刺激未来的研究,促进这一领域的发展。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Topics in Current Chemistry
Topics in Current Chemistry Chemistry-General Chemistry
CiteScore
13.70
自引率
1.20%
发文量
48
期刊介绍: Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.
期刊最新文献
Structure-Based Drug Design of RdRp Inhibitors against SARS-CoV-2 The Intramolecular Povarov Tool in the Construction of Fused Nitrogen-Containing Heterocycles Photothermal Catalytic CO2 Conversion: Beyond Catalysis and Photocatalysis Multicomponent Reactions Using C,N-Binucleophilic Nature of Aminopyrazoles: Construction of Pyrazole-Fused Heterocycles Laser-Induced Transfer of Functional Materials
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1