An overview of bismuth tungstate-based catalysts in various organic transformations

IF 1.6 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Transition Metal Chemistry Pub Date : 2023-06-27 DOI:10.1007/s11243-023-00535-w
Murugesan Shobika, Selvaraj Mohana Roopan
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Abstract

Bismuth tungstate (Bi2WO6) has received extensive research in a numerous area, including degradation, CO2 reduction, organic transformations, etc. Due to their wide range of applications, the discovery and development of effective, environmentally safe, gentle, and affordable techniques for the synthesis of bismuth tungstate are critical in organic transformations. There have been reports on variety of multicomponent reactions employing the heterogeneous catalysts Bi2O3, BiVO4, and as well Bi2WO6 nanoparticle. Among other materials, Bi2WO6 nanoparticles are perceived for their high reactivity at ambient temperature in an aquatic medium. The main objective of this study is to emphasize the mechanistic considerations, scope, benefits, and limits of recent catalytic improvements in the process of oxidation and other reactions. Consequently, the use of Bi2WO6 catalyst offers many advantages, including high yields, an ecologically friendly process, quick reaction times, and a straightforward work-up technique. It has been created to use a Bi2WO6 catalyst in an aqueous medium in a versatile, simple, one-pot, multi-component technique. This process offers easy-to-find, inexpensive reagents, quick reaction times, great yields, and high atom economy. In this review, we have elaborated how Bi2WO6 nanomaterials can be employed as effective and reusable catalysts for organic transformation.

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钨酸铋基催化剂在各种有机转化中的应用综述
钨酸铋(Bi2WO6)在许多领域得到了广泛的研究,包括降解、CO2还原、有机转化等。由于其广泛的应用范围,发现和发展有效、环保、温和和负担得起的合成钨酸铋的技术是有机转化的关键。采用非均相催化剂Bi2O3、BiVO4和纳米颗粒Bi2WO6进行多组分反应已有报道。在其他材料中,Bi2WO6纳米颗粒因其在水生介质中的环境温度下的高反应性而被认为。本研究的主要目的是强调最近在氧化和其他反应过程中催化改进的机理、范围、好处和局限性。因此,使用Bi2WO6催化剂具有许多优点,包括高产量、生态友好的过程、快速的反应时间和简单的处理技术。它是在水介质中使用Bi2WO6催化剂,以一种通用、简单、一锅、多组分的技术创建的。该工艺提供了容易找到、廉价的试剂、快速的反应时间、高收率和高原子经济性。在这篇综述中,我们阐述了如何将Bi2WO6纳米材料作为有机转化的有效和可重复使用的催化剂。图形抽象
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来源期刊
Transition Metal Chemistry
Transition Metal Chemistry 化学-无机化学与核化学
CiteScore
3.60
自引率
0.00%
发文量
32
审稿时长
1.3 months
期刊介绍: Transition Metal Chemistry is an international journal designed to deal with all aspects of the subject embodied in the title: the preparation of transition metal-based molecular compounds of all kinds (including complexes of the Group 12 elements), their structural, physical, kinetic, catalytic and biological properties, their use in chemical synthesis as well as their application in the widest context, their role in naturally occurring systems etc. Manuscripts submitted to the journal should be of broad appeal to the readership and for this reason, papers which are confined to more specialised studies such as the measurement of solution phase equilibria or thermal decomposition studies, or papers which include extensive material on f-block elements, or papers dealing with non-molecular materials, will not normally be considered for publication. Work describing new ligands or coordination geometries must provide sufficient evidence for the confident assignment of structural formulae; this will usually take the form of one or more X-ray crystal structures.
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