Wan-Feng Lin, Mei-Feng Wu, Shun-Chen Dai, Wei-Li Dai, Jian-Ping Zou
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引用次数: 3
Abstract
The aqueous solution reaction of chelidamic acid (H3CAM), succinic acid, CdCl2·2.5H2O in the air at 50 °C, along with little of ammonia added dropwise, gave rise to colorless crystals {Cd2.5(CAM)(HCAM)(H2O)7·1.5H2O}n (1), which presents an interesting (4,6)-connected 3D structure. Notably, 1 is the third homonuclear 3D framework based on H3CAM ligand, which acts as two different μ4/μ5-bridges in 1 and was abbreviated to HCAM2 − and CAM3 −, respectively, in writing molecular formula of 1. Polymer 1 exhibits strong blue photoluminescence at room temperature.
期刊介绍：
Launched in January 1998, Inorganic Chemistry Communications is an international journal dedicated to the rapid publication of short communications in the major areas of inorganic, organometallic and supramolecular chemistry. Topics include synthetic and reaction chemistry, kinetics and mechanisms of reactions, bioinorganic chemistry, photochemistry and the use of metal and organometallic compounds in stoichiometric and catalytic synthesis or organic compounds.
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