Micropore size analysis in hydrated cement paste by NMR

Arnaud Plassais , Marie-Pierre Pomiès , Nicolas Lequeux , Philippe Boch , Jean-Pierre Korb , Dominique Petit
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引用次数: 22

Abstract

We present a time evolution of 1H spin-lattice relaxation rates in the laboratory (1/T1) and in the rotating (1/T) frame of a synthetic cement paste. The typical results found for both rates allow us to follow the main hydration stages of the cement paste and the refinement of its microporosity. In particular the texturation of the porosity and the structuration of the surface of the material are evidenced on two model cement pastes. An interpretation in terms of fractal size distribution is considered as well as the effect of the curing temperature.

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水化水泥浆体微孔大小的核磁共振分析
我们在实验室(1/T1)和合成水泥浆的旋转(1/T1ρ)框架中给出了1H自旋晶格弛豫速率的时间演化。这两种速率的典型结果使我们能够跟踪水泥浆体的主要水化阶段及其微孔隙度的细化。特别地,孔隙度的纹理和材料表面的结构在两个模型水泥浆体上得到证实。考虑了分形尺寸分布的解释以及固化温度的影响。
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