Brillouin and Raman Scattering Study of Ethylene Glycol Aqueous Solutions

IF 0.5 Q4 MATHEMATICS, INTERDISCIPLINARY APPLICATIONS Complex Systems Pub Date : 2008-02-27 DOI:10.1063/1.2897819
Y. Seshimo, Y. Ike, S. Kojima
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引用次数: 2

Abstract

We studied the cluster structure of ethylene glycol aqueous solutions by Brillouin and Raman scattering. We measured the ultrasonic sound velocity of the sample by Brillouin scattering. From the concentration dependence of the sound velocity, we studied the cluster structure in the solution. We showed that the number of H2O molecule neighboring a EG molecule becomes a little higher with increasing temperature and the intermolecular interaction between EG and H2O molecules weakened with increasing temperature. In Raman scattering study, We studied the hydrogen bond in the solution using the OD stretching band. We revealed that the strength of the hydrogen bond is independent of the EG concentration.
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乙二醇水溶液的布里渊散射和拉曼散射研究
利用布里渊散射和拉曼散射研究了乙二醇水溶液的团簇结构。用布里渊散射法测量了样品的超声声速。从声速的浓度依赖性出发,研究了溶液中的团簇结构。结果表明,随着温度的升高,EG分子与H2O分子之间的相互作用逐渐减弱,而与EG分子相邻的H2O分子数量逐渐增加。在拉曼散射研究中,我们用OD拉伸带研究了溶液中的氢键。我们发现氢键的强度与EG的浓度无关。
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来源期刊
Complex Systems
Complex Systems MATHEMATICS, INTERDISCIPLINARY APPLICATIONS-
CiteScore
1.80
自引率
25.00%
发文量
18
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