Electrodeposition of thick chromium coatings from an environmentally acceptable chromium (III)-glycine complex

IF 1.2 4区 材料科学 Q4 ELECTROCHEMISTRY Transactions of The Institute of Metal Finishing Pub Date : 1999-01-01 DOI:10.1080/00202967.1999.11871269
M. El-Sharif, J. Mcdougall, C. Chisholm
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引用次数: 41

Abstract

SUMMARYHexavalent chromium process provides unique engineering coatings in terms of wear and corrosion resistance. However, this process is under pressure due to its environmentally unfriendly attributes. Recently significant advances have been made on the development of an electrolyte based on chromium(III)-glycine complex. A successful enhancement of both quality of deposits and the rate of deposition has been achieved using high speed and conventional techniques. A clear correlation has been established between the percentage chromium metal deposited and the formation of chromium (III)-glycine complexes leading to the identification of the species suitable for chromium deposition.
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从环境可接受的铬(III)-甘氨酸络合物中电沉积厚铬涂层
六价铬工艺在耐磨和耐腐蚀性方面提供了独特的工程涂层。然而,由于其不环保的特性,这一过程面临着压力。近年来,铬(III)-甘氨酸配合物电解质的研究取得了重大进展。利用高速和常规技术,成功地提高了沉积质量和沉积速度。在金属铬沉积的百分比和铬(III)-甘氨酸络合物的形成之间建立了明确的相关性,从而确定了适合铬沉积的物种。
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来源期刊
Transactions of The Institute of Metal Finishing
Transactions of The Institute of Metal Finishing 工程技术-材料科学:膜
CiteScore
3.40
自引率
10.50%
发文量
62
审稿时长
3 months
期刊介绍: Transactions of the Institute of Metal Finishing provides international peer-reviewed coverage of all aspects of surface finishing and surface engineering, from fundamental research to in-service applications. The coverage is principally concerned with the application of surface engineering and coating technologies to enhance the properties of engineering components and assemblies. These techniques include electroplating and electroless plating and their pre- and post-treatments, thus embracing all cleaning pickling and chemical conversion processes, and also complementary processes such as anodising. Increasingly, other processes are becoming important particularly regarding surface profile, texture, opacity, contact integrity, etc.
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