{"title":"Effect of pressure on the structure of multispin complexes","authors":"G. Romanenko, G. Letyagin, V. Ovcharenko","doi":"10.1070/RCR5028","DOIUrl":null,"url":null,"abstract":"Changes in the hydrostatic pressure may significantly affect the spin dynamics of magnetically active compounds. Hence, objects exhibiting spin transitions have attracted attention of researchers in different fields. Since these transitions are reversible and do not cause the chemical decomposition of the compounds, spin state conversions can be responsible for the functional activity of materials as data storage media, external stimulus sensors or actuators for certain solid-state processes. Moreover, multispin compounds can demonstrate specific structural dynamics that is not inherent in diamagnetic compounds, which is of independent interest. The review presents the analysis of recent data on the effect of hydrostatic pressure on the crystal structure and magnetic properties of metal complexes with organic diamagnetic and paramagnetic ligands, exhibiting spin transitions and valence tautomerism, organic paramagnets and single-molecule magnets. The bibliography includes 179 references.","PeriodicalId":21523,"journal":{"name":"Russian Chemical Reviews","volume":"91 1","pages":""},"PeriodicalIF":7.0000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Reviews","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1070/RCR5028","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 3
Abstract
Changes in the hydrostatic pressure may significantly affect the spin dynamics of magnetically active compounds. Hence, objects exhibiting spin transitions have attracted attention of researchers in different fields. Since these transitions are reversible and do not cause the chemical decomposition of the compounds, spin state conversions can be responsible for the functional activity of materials as data storage media, external stimulus sensors or actuators for certain solid-state processes. Moreover, multispin compounds can demonstrate specific structural dynamics that is not inherent in diamagnetic compounds, which is of independent interest. The review presents the analysis of recent data on the effect of hydrostatic pressure on the crystal structure and magnetic properties of metal complexes with organic diamagnetic and paramagnetic ligands, exhibiting spin transitions and valence tautomerism, organic paramagnets and single-molecule magnets. The bibliography includes 179 references.
期刊介绍：
Russian Chemical Reviews serves as a complete translation of the esteemed monthly review journal Uspekhi Khimii, which has been a prominent figure in Russian scientific journals since its establishment in 1932. It offers comprehensive access to the advancements made by chemists from Russia and other former Soviet Union countries.
Established in 1932, Russian Chemical Reviews is committed to publishing timely and significant review articles encompassing various facets of modern chemistry, including chemical physics, physical chemistry, computational and theoretical chemistry, catalysis, coordination chemistry, analytical chemistry, organic, organometallic, and organoelement chemistry, chemistry of macromolecules, applied chemistry, biochemistry, bio-organic chemistry, biomolecular chemistry, medicinal chemistry, materials chemistry, nanochemistry, nanostructures, and environmental chemistry.
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