{"title":"Enantioselective synthesis of a taxol C ring","authors":"Cong Ma, Stéphanie Schiltz, Joëlle Prunet","doi":"10.1135/CCCC2011039","DOIUrl":null,"url":null,"abstract":"An enantioselective synthesis of a C ring of taxol has been accomplished. The key step is an oxidative cleavage of a derivative of the Wieland-Miescher ketone. A first attempt of a Shapiro reaction modelling the coupling of the C ring with the A fragment of taxol was also successful. © 2011 Institute of Organic Chemistry and Biochemistry.","PeriodicalId":10674,"journal":{"name":"Collection of Czechoslovak Chemical Communications","volume":"76 1","pages":"1579-1594"},"PeriodicalIF":0.0000,"publicationDate":"2011-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1135/CCCC2011039","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Collection of Czechoslovak Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1135/CCCC2011039","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5
紫杉醇C环的对映选择性合成
完成了紫杉醇C环的对映选择性合成。关键步骤是氧化裂解一个衍生的威兰-米歇尔酮。第一次尝试夏皮罗反应模拟C环与紫杉醇A片段的耦合也取得了成功。©2011中国科学院有机化学与生物化学研究所。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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