{"title":"Complex Impedance Spectroscopic Properties of BaVO Ceramics","authors":"P. Khatri, B. Behera, V. Srinivas, R. Choudhary","doi":"10.1155/2008/746256","DOIUrl":null,"url":null,"abstract":"The polycrystalline sample of Ba3V2O8 was prepared by a high-temperature solid-state reaction technique. The effect of temperature on impedance parameters was studied using an impedance analyzer in a wide frequency range (102-106 Hz). The real and imaginary parts of complex impedance trace semicircles in the complex plane. The temperature-dependent plots reveal the presence of both bulk and grain boundary effects above 125∘C. The bulk resistance of the material decreases with rise in temperature. This exhibits a typical negative temperature coefficient of resistance (NTCR) behavior of the material. The modulus analysis suggests a possible hopping mechanism for electrical transport processes of the material. The nature of variation of dc conductivity suggests the Arrhenius type of electrical conductivity.","PeriodicalId":7345,"journal":{"name":"Advances in Materials Science and Engineering","volume":"2008 1","pages":"1-5"},"PeriodicalIF":0.0000,"publicationDate":"2008-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2008/746256","citationCount":"25","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Materials Science and Engineering","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1155/2008/746256","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 25
Abstract
The polycrystalline sample of Ba3V2O8 was prepared by a high-temperature solid-state reaction technique. The effect of temperature on impedance parameters was studied using an impedance analyzer in a wide frequency range (102-106 Hz). The real and imaginary parts of complex impedance trace semicircles in the complex plane. The temperature-dependent plots reveal the presence of both bulk and grain boundary effects above 125∘C. The bulk resistance of the material decreases with rise in temperature. This exhibits a typical negative temperature coefficient of resistance (NTCR) behavior of the material. The modulus analysis suggests a possible hopping mechanism for electrical transport processes of the material. The nature of variation of dc conductivity suggests the Arrhenius type of electrical conductivity.
期刊介绍：
Advances in Materials Science and Engineering is a broad scope journal that publishes articles in all areas of materials science and engineering including, but not limited to:
-Chemistry and fundamental properties of matter
-Material synthesis, fabrication, manufacture, and processing
-Magnetic, electrical, thermal, and optical properties of materials
-Strength, durability, and mechanical behaviour of materials
-Consideration of materials in structural design, modelling, and engineering
-Green and renewable materials, and consideration of materials’ life cycles
-Materials in specialist applications (such as medicine, energy, aerospace, and nanotechnology)
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