{"title":"DEHYDRATION AND ALKYLATION REACTIONS BY THE USE OF PERCHLORATE SALTS","authors":"T. Mukaiyama, M. Kuwahara, T. Izawa, M. Ueki","doi":"10.1246/CL.1972.287","DOIUrl":null,"url":null,"abstract":"By the treatment of secondary and tertiary benzylic alcohols or tertiary aliphatic alcohols with AgClO4, in benzene at refluxing temperature for 20 to 420 min, olefins were obtained as dehydrated products in good yields. Further, a new procedure for generating tin perchlorate was devised, and the application of this reagent to alkylation reactions of aromatic compounds from alcohols or paraformaldehyde was investigated.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":"1 1","pages":"287-290"},"PeriodicalIF":1.1000,"publicationDate":"1972-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1246/CL.1972.287","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1246/CL.1972.287","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 5
Abstract
By the treatment of secondary and tertiary benzylic alcohols or tertiary aliphatic alcohols with AgClO4, in benzene at refluxing temperature for 20 to 420 min, olefins were obtained as dehydrated products in good yields. Further, a new procedure for generating tin perchlorate was devised, and the application of this reagent to alkylation reactions of aromatic compounds from alcohols or paraformaldehyde was investigated.
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