Molybdenum oxide based sensors

IF 0.3 Q4 CHEMISTRY, MULTIDISCIPLINARY Chemical Bulletin of Kazakh National University Pub Date : 2021-06-30 DOI:10.15328/cb1164
N.Zh. Zhumasheva, Leyla Kudreeva, Diana Kosybayeva
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Abstract

In this review article were considered the works of electrochemical sensors modified with molybdenum oxide. The work of sensors based on molybdenum oxide was systematized, a comparison table was developed, the sensors were classified according to the purpose of use. Methods of molybdenum oxide synthesis used to modify the working electrode in electrochemical sensors were considered. The various methods have been used to synthesize molybdenum oxide, such as a thermal, hydrothermal, electrochemical, electric spark, pulsed laser method, acid condensation, electrophoretic precipitation, pulse potential precipitation. The main parameters of the molybdenum oxide modified sensors, such as the detection limit, linear range, response time, sensitivity, and other parameters were compared. As a result of studies, it was found that molybdenum oxide is selected as a modifying material in electrochemical sensors due to the unique physicochemical properties of molybdenum oxide, in particular because of mechanical strength, electrical conductivity, electro catalytic activity, crystallinity. The features of electrochemical biosensors coated with molybdenum oxide were described for the detection of important compounds in specific samples. Sensors based on molybdenum oxide have been used for detection of glucose, dopamine, ethanol, ascorbic acid, troponin-1, norepinephrine, procalcitonin, L-lactate, bromate, chlorate, E110, tartrazine, hydrochlorothiazide, human epidermal growth factor-2, lithium,sodium,potassium. This paper provides general summarized information about current aspects of research works related to electrochemical sensors based on molybdenum oxide.
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氧化钼基传感器
本文综述了氧化钼改性电化学传感器的研究进展。对基于氧化钼的传感器的工作进行了系统化,编制了比较表,并根据使用目的对传感器进行了分类。研究了用于修饰电化学传感器工作电极的氧化钼合成方法。合成氧化钼的方法多种多样,如热法、水热法、电化学法、电火花法、脉冲激光法、酸缩合法、电泳沉淀法、脉冲电位沉淀法等。比较了氧化钼修饰传感器的主要参数,如检出限、线性范围、响应时间、灵敏度等参数。通过研究发现,由于氧化钼具有独特的物理化学性质,特别是机械强度、电导率、电催化活性、结晶度等特点,因此在电化学传感器中选择氧化钼作为改性材料。介绍了氧化钼包覆的电化学生物传感器对特定样品中重要化合物的检测特性。基于氧化钼的传感器已被用于检测葡萄糖、多巴胺、乙醇、抗坏血酸、肌钙蛋白-1、去甲肾上腺素、降钙素原、l -乳酸、溴酸盐、氯酸盐、E110、酒黄、氢氯噻嗪、人表皮生长因子-2、锂、钠、钾。本文对基于氧化钼的电化学传感器的研究现状进行了综述。
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审稿时长
10 weeks
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