Hydrothermally synthesized Mo/Zr-MOF photocatalyst for promoting the removal of Cr6+ under visible light

IF 1.8 4区 材料科学 Q4 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY Green Materials Pub Date : 2023-01-19 DOI:10.1680/jgrma.22.00074
Wenyu Ren, Yi Wang, Jin Wang, Ruixue Sun
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Abstract

The development of highly efficient photocatalysts for the degradation of organic dyes and heavy metal ions is necessary to control pollution in the environment and further human health. We report nMo/Zr-MOFs (n=1, 2, 3, and 4, nMZMs) synthesized by a simple hydrothermal method for efficient photocatalytic Cr6+ reduction for the first time. Among all the prepared samples, 2MZMs shows the highest photocatalytic performance with a degradation rate of 94.36% for methylene blue and 91.20% for Cr6+ under visible light irradiation for 120 min and 100 min respectively. The ESR experiments reveal that •O2 − and •OH play a major role. This finding proves great potential for the design and application of MOFs nanomaterials and might bring considerable application prospects for photocatalysis of organic pollutants and heavy metal ions in polluted water.
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水热合成Mo/Zr-MOF光催化剂促进可见光下Cr6+的去除
开发高效降解有机染料和重金属离子的光催化剂是控制环境污染和促进人类健康的必要条件。我们首次报道了用简单水热法合成的nMo/ zr - mfs (n= 1,2,3和4,nmzms)用于光催化Cr6+的高效还原。在所制备的样品中,2MZMs在可见光照射120 min和100 min时,对亚甲基蓝和Cr6+的降解率分别为94.36%和91.20%,表现出最高的光催化性能。ESR实验表明,•O2−和•OH起主要作用。这一发现为mof纳米材料的设计和应用提供了巨大的潜力,并可能在光催化污染水中有机污染物和重金属离子方面带来可观的应用前景。
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来源期刊
Green Materials
Green Materials Environmental Science-Pollution
CiteScore
3.50
自引率
15.80%
发文量
24
期刊介绍: The focus of Green Materials relates to polymers and materials, with an emphasis on reducing the use of hazardous substances in the design, manufacture and application of products.
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