THE EFFECTS OF FE-DOPING ON MECHANICAL PROPERTIES IN Bi1.6Pb0.4Sr2Ca2Cu3-XFeXOY SUPERCONDUCTOR

Suazlina Mat Ali, A. Hashim, S. A. Senawi, A. Kasim, W. Razali, R. Mohamed, F. A. Lothfy
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引用次数: 1

Abstract

Bi-2223 superconductors doped with Fe2O3 at Cu-site were prepared in bulk form using high purity oxide powders via solid state reaction technique with intermediate grinding. The series of Fe stoichiometric ratio (x = 0.00, 0.02, 0.04, 0.06, 0.08 and 0.10) are systematically added to Bi1.6Pb0.4Sr2Ca2Cu3-xFexOy system to study the effect of Fe doping on mechanical and superconducting system properties. Vickers hardness, electrical resistivity, X-ray diffraction and Field Emission Scanning Electron Microscopy have been carried out to assess the effects of Fe doping. These measurements indicate that the Fe doping decreased the critical temperature and deteriorated formation of high Tc phase, compared to undoped sample. Grain size of the samples were also reduced by increasing the amount of Fe and the mechanical properties were found to be escalate with the increasing of Fe concentration.
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fe掺杂对Bi1.6Pb0.4Sr2Ca2Cu3-XFeXOY超导体力学性能的影响
以高纯度氧化物粉末为原料,采用中间研磨固相反应法制备了Cu-site掺杂Fe2O3的Bi-2223超导体。系统地在Bi1.6Pb0.4Sr2Ca2Cu3-xFexOy体系中加入一系列化学计量比(x = 0.00, 0.02, 0.04, 0.06, 0.08和0.10)的Fe,研究Fe掺杂对体系力学性能和超导性能的影响。通过维氏硬度、电阻率、x射线衍射和场发射扫描电镜对铁掺杂的影响进行了评价。结果表明,与未掺杂样品相比,Fe的掺杂降低了样品的临界温度,促进了高Tc相的形成。随着Fe含量的增加,试样的晶粒尺寸减小,力学性能随Fe浓度的增加而升高。
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Malaysian Journal of Analytical Sciences
Malaysian Journal of Analytical Sciences Chemistry-Analytical Chemistry
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