{"title":"AVALIAÇÃO DE COMPOSTOS ORGÂNICOS VOLÁTEIS AROMÁTICOS NA ATMOSFERA EM CAMPOS DOS GOYTACAZES E ITAPERUNA APLICANDO A ANÁLISE MULTIVARIADA DE DADOS","authors":"H. Vieira, A. Figueiredo, Murilo Souza, M. Canela","doi":"10.21577/0100-4042.20170952","DOIUrl":null,"url":null,"abstract":"EVALUATION OF AROMATIC VOLATILE ORGANIC COMPOUNDS IN THE ATMOSPHERE IN CAMPOS DOS GOYTACAZES AND ITAPERUNA APPLYING MULTIVARIATE DATA ANALYSIS. Volatile Organic Compounds (VOCs) are air pollutants emitted from different sources, mainly by industries and motor vehicles. The evaluation of the emission of these compounds into the atmosphere should be done systematically and with a varied class of compounds. The large number of data generated during the monitoring of these VOCs requires the use of multivariate data tools to interpret the results. In this sense, this work aimed to monitor 10 aromatic VOCs present in the atmosphere of the largest cities in the Norte Fluminense (Campos dos Goytacazes) and Noroeste Fluminense (Itaperuna) regions. The VOCs were actively sampled and analyzed by gas chromatography with mass spectrometry detection after thermal desorption. After treatment of analytical results, it was observed that in both cities there is influence of vehicular emissions. In the city of Itaperuna, due to the relief and lower dispersion of contaminants, there is a higher occurrence of photochemical reactions. The exploratory analysis of the data allowed identifying the variables that were more significant and correlating these variables with the main sources of emission of the compounds. This is the first study of VOCs evaluation in Campos dos Goytacazes and Itaperuna, demonstrating the relevance of this research for understanding the behavior of VOCs in these cities, which have different reliefs and high traffic of cars and trucks in the studied sites.","PeriodicalId":49641,"journal":{"name":"Quimica Nova","volume":null,"pages":null},"PeriodicalIF":0.5000,"publicationDate":"2023-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Quimica Nova","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.21577/0100-4042.20170952","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
EVALUATION OF AROMATIC VOLATILE ORGANIC COMPOUNDS IN THE ATMOSPHERE IN CAMPOS DOS GOYTACAZES AND ITAPERUNA APPLYING MULTIVARIATE DATA ANALYSIS. Volatile Organic Compounds (VOCs) are air pollutants emitted from different sources, mainly by industries and motor vehicles. The evaluation of the emission of these compounds into the atmosphere should be done systematically and with a varied class of compounds. The large number of data generated during the monitoring of these VOCs requires the use of multivariate data tools to interpret the results. In this sense, this work aimed to monitor 10 aromatic VOCs present in the atmosphere of the largest cities in the Norte Fluminense (Campos dos Goytacazes) and Noroeste Fluminense (Itaperuna) regions. The VOCs were actively sampled and analyzed by gas chromatography with mass spectrometry detection after thermal desorption. After treatment of analytical results, it was observed that in both cities there is influence of vehicular emissions. In the city of Itaperuna, due to the relief and lower dispersion of contaminants, there is a higher occurrence of photochemical reactions. The exploratory analysis of the data allowed identifying the variables that were more significant and correlating these variables with the main sources of emission of the compounds. This is the first study of VOCs evaluation in Campos dos Goytacazes and Itaperuna, demonstrating the relevance of this research for understanding the behavior of VOCs in these cities, which have different reliefs and high traffic of cars and trucks in the studied sites.
应用多元数据分析对CAMPOS DOS GOYTACAZES和ITAPERUNA大气中挥发性有机化合物的评价
应用多变量数据分析评价校园中大气中芳香族挥发性有机物的含量。挥发性有机化合物(VOCs)是来自不同来源的空气污染物,主要由工业和机动车辆排放。对这些化合物排放到大气中的评价应系统地、用不同种类的化合物进行。这些VOCs监测过程中产生的大量数据需要使用多变量数据工具来解释结果。从这个意义上说,这项工作旨在监测北弗鲁米嫩塞(Campos dos Goytacazes)和北弗鲁米嫩塞(Itaperuna)地区最大城市大气中存在的10种芳香性VOCs。对挥发性有机化合物进行主动取样,热解吸后采用气相色谱-质谱法进行分析。对分析结果进行处理后发现,两个城市均存在机动车尾气排放的影响。在伊塔佩鲁纳市,由于污染物的缓解和较低的分散,光化学反应的发生率较高。数据的探索性分析允许识别更重要的变量,并将这些变量与化合物的主要排放源相关联。这是首个对Campos dos Goytacazes和Itaperuna进行VOCs评价的研究,证明了本研究对了解这些城市VOCs行为的相关性,这些城市在研究地点有不同的缓解和高车流量的汽车和卡车。
期刊介绍:
Química Nova publishes in portuguese, spanish and english, original research articles, revisions, technical notes and articles about education in chemistry. All the manuscripts submitted to QN are evaluated by, at least, two reviewers (from Brazil and abroad) of recognized expertise in the field of chemistry involved in the manuscript. The Editorial Council can be eventually asked to review manuscripts. Editors are responsible for the final edition of QN.