REMOVAL OF URANIUM AND ASSOCIATED ELEMENTS FROM SINAI WELLS WATER USING THE DRIED AND CHEMICALLY MODIFIED ORANGE PEELS

A. Abdelhakim, E. Awad, I. Mohamed, E. El-Sheikh
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Abstract

It is well known that the natural cellulose has low ionic exchange properties, due to its characterization by a small number of carboxylic groups. Incorporation of different functional groups can promote its ionic exchange capacity. In this work, modification of orange peel by treating with sodium hydroxide and amination, phosphoration and sulfonation. The different ion exchanger has been used to increase the ion exchange capacity of such materials, by developing their swelling properties and decreasing their lignin content. A maximum uranium uptake of 726 mg/g was observed at the obtained optimum conditions using modified resin (ion exchange No. VII). The latter (0.841: 0.420) mm size orange peels were modified using a mixture of sulfonic and phosphoric acids. Ion exchange No. VII was used as the case study to remove uranium and associated elements from Sinai wells water. The main purpose of this work is to prepare different resins from the Egyptian plant waste. Orange peels were chosen because they are popular and widespread plant wastes in Egypt.
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使用干燥和化学修饰的橘子皮从西奈井水中去除铀和相关元素
众所周知,天然纤维素具有较低的离子交换性能,因为它的表征是由少量的羧基。不同官能团的掺入可以提高其离子交换能力。本文研究了用氢氧化钠和胺化、磷酸化、磺化对橙皮进行改性。不同的离子交换剂已被用于提高这类材料的离子交换能力,通过发展它们的膨胀性能和降低它们的木质素含量。在最佳条件下,改性树脂(离子交换No.)对铀的最大吸收率为726 mg/g。后一种(0.841:0.420)mm大小的橘子皮用磺酸和磷酸的混合物进行改性。离子交换号:以西奈井水中的铀及伴生元素为研究对象。本工作的主要目的是从埃及植物废料中制备不同的树脂。之所以选择橘子皮,是因为在埃及,橘子皮是一种普遍存在的植物废弃物。
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