Comparison of the effectiveness of different types of extractants for recovery of iron from mineral wool waste

M. Huculak-Mączka, E. Klem, E. Ogonowska, A. Justyniarski, J. Hoffmann
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Abstract

The paper presents the results of iron extraction from wool waste. In studies as extractant was used: water, EDTA, acetic acid, formic acid, DTPA, ammonium lactate and calcium lactate. For analysis has been taken wool after one year cultivation of tomato and cucumber and wool after two years of mixed cultivation. The main aim of the analysis was to determine which extractant allows the greatest recovery of the iron from waste mineral wool. Current trends in the agriculture development and the fertilizer industry are aimed at maximizing the recovery of nutrients from waste for re-use. Demonstration of the effectiveness of the recycling of valuable trace elements contained in the mineral wool can make develop a method of wool utilization profitable. In addition, the high cost of fertilizer components makes a new type of medium containing nutrients obtained by extraction from mineral wool waste, can be an interesting option in the future. Implementation of this type of process is consistent with the objectives of Sustainable Development, as well as the environmental policy of the European Union. The proposed way to get iron from mineral waste wool consists of following steps: drying at 30 C for 24 hours, grinding to particles with a sieve size of 0.40 nm, extraction and phase separation. The studies included the effect of time, temperature and type of extractants on the efficiency of the process. The iron content in the samples was determined by spectrophotometric method based on the ferric ion complex of 2,2-pyridyl in a solution at pH of 3.1.
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不同萃取剂回收矿棉废铁的效果比较
本文介绍了从羊毛废料中提取铁的试验结果。研究中使用的萃取剂有:水、EDTA、乙酸、甲酸、DTPA、乳酸铵和乳酸钙。对番茄和黄瓜栽培1年后的羊毛和混作2年后的羊毛进行了分析。分析的主要目的是确定哪种萃取剂可以最大限度地从废矿棉中回收铁。目前农业发展和肥料工业的趋势旨在最大限度地从废物中回收营养物质进行再利用。论证了矿棉中有价微量元素回收利用的有效性,为开发一种有益的矿棉利用方法奠定了基础。此外,肥料成分的高成本使得从矿棉废料中提取含有营养物质的新型培养基在未来可能是一个有趣的选择。这类进程的实施符合可持续发展的目标,也符合欧洲联盟的环境政策。本文提出的从废羊毛中提取铁的方法包括:在30℃下干燥24小时,磨成0.40 nm粒度的颗粒,萃取和相分离。研究了萃取时间、萃取温度和萃取剂种类对萃取效率的影响。以2,2-吡啶的铁离子配合物为基础,在pH为3.1的溶液中分光光度法测定样品中的铁含量。
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