Molecular composition of humic substances isolated from selected soils and cryconite of the Grønfjorden area, Spitsbergen

Abstract

: Humic acids, isolated from selected soils of Grønfjorden area (Spitsbergen) were investigated in terms of molecular composition and resistance of decomposition. The degree of soils organic matter stabilization has been assessed with the use of modern instrumental methods (nuclear magnetic resonance spectroscopy (CP/MAS 13 C-NMR). Analysis of the humic acids showed that aromatic compounds prevail in the organic matter formed in cryoconites, located on the glaciers surfaces. The predominance of aliphatic fragments is revealed in the soils in tidal zone that form on the coastal terrace. This could be caused by sedimentation of fresh organic matter exhibiting low decomposition stage due to the harsh climate and processes of hydrogenation in the humic acids, destruction of the C-C bonds and formation of chains with a high hydrogen content. These processes result in formation of aliphatic fragments in the humic acids. In general, soils of the studied region characterizes by low stabilized soil organic matter which is indicated by low aromaticity of the HAs.